Group 11 Metal Ions in Poly (donor atom) Environments: X-ray Crystal and Molecular Structure of [M((R,S)-1,2-(5-R-thio-2-CH=N)2-c-Hx)2](O3SCF3) (M = Ag(I), R = Me, thio = Thiophene, c-Hx = Cyclohexane) and Silver(I) and Copper(I) Coordination Properties in Solution (1H, 109Ag, and 15N NMR)

Inorganic Chemistry

Volumn 24, Issue 9, 1985, Pages 1367-1375

  Van Stein, Gerard C ^a   Koten, Gerard Van ^a   Vrieze, Kees ^a   Spek, Anthony L ^b   Klop, Enno A ^b   Brevard, Christian ^c  

^a UNIVERSITY OF AMSTERDAM   (Netherlands)

^b UTRECHT UNIVERSITY   (Netherlands)

^c Bruker Spectrospin ^*  (France)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0347784816     PISSN: 00201669     EISSN: 1520510X     Source Type: Journal    
DOI: 10.1021/ic00203a021     Document Type: Article

References (20)

1. Sorrell, T. N.; Malachowski, M. R. Inorg. Chem. 1983, 22, 1883. Pasquali, M.; Marini, G.; Floriani, C.; Gaetani-Manfredotti, A.; Guastini, C. Inorg. Chem. 1980, 19, 2525. Casella, L.; Ibers, J. A. Inorg. Chem. 1981, 20, 2438. Karlin, K. D.; Gultneh, Y.; Hutchinson, J. P.; Zubieta, J. J. Am. Chem. Soc. 1982, 104, 5240. Rietmeijer, F. J.; Birker, P. J. M. W. L.; Gorter, S.; Reedijk, J. J. Chem. Soc., Dalton Trans. 1982, 1191. Dagdigian, J. V.; McKee, V.; Reed, C. A. Inorg. Chem. 1982, 21, 1332.
2. Van Stein, G. C.; Van Koten, G.; Vrieze, K.; Brevard, C.; Spek, A. L. J. Am. Chem. Soc. 1984, 106, 4486.
3. Van Stein, G. C.; Van Koten, G.; De Bok, B.; Taylor, L. C.; Vrieze, K.; Brevard, C. Inorg. Chim. Acta 1984, 89, 29.
4. 2: Marker, A.; Gunther, M. J. J. Magn. Reson. 1982, 47, 118 and references cited there in.
5. -1respectively: Kidd, R. G.; Goodfellow, R. J. “NMR and the Periodic Table”; Harris, R. K., Mann, B. E., Eds.; Academic Press: New York, 1978; p 258.
6. Brevard, C.; Van Stein, G.C.; Van Koten, G.J. Am. Chem. Soc. 1981, 103, 6746.
7. Van Stein, G. C.; Van Koten, G.; Vrieze, K.; Brevard, C. Inorg. Chem. 1984, 23, 4269. (8) Van Stein, G. C.; Van Koten, G.; Blank, F.; Taylor, L. C.; Vrieze, K.; Spek, A. L.; Duisenberg, A. J. M.; Schreurs, A. M. M.; Kojić-Prodić, B.; Brevard, C. Inorg. Chim. Acta 1985, 98, 107.
8. Part of this study has been published as a preliminary communication: Van Stein, G. C.; Van Koten, G.; Spek, A. L.; Duisenberg, A. J. M.; Klop, E. A. Inorg. Chim. Acta 1983, 78, L61. Van Stein, G. C.; Van Koten, G.; Spek, A. L.; Klop, E. A. Inorg. Chim. Acta 1983, 79, 205.
9. Salomon, R. G.; Kochi, J. K. J. Am. Chem. Soc. 1973, 95, 1889.
10. Saito, R.; Kidani, Y. Chem. Lett. 1976, 123. (12) van der Ploeg, A. F. M. J.; van Koten, G.; Spek, A. L. Inorg. Chem. 1979, 18, 1052.
11. Cromer, D. T.; Liberman, D. J. Chem. Phys. 1970, 53, 1891. (15) Ilias-A DG-Eclipse/S 230 minicomputer crystallographic program package derived from G. Sheldrick's Shelx-76.
12. Cromer D.T.; Liberman, D. J. Chem. Phys. 1970, 53, 1891. !!(15) ilias-a DG-Eclipse/S 230 minicomputer crystallographic program package derived from G. Sheldrick's shelx-76.
13. Spek, A. L. In “Computational Crystallography”; Sayre, D., Ed.; Clarendon Press: Oxford, 1982. (17) For the abbreviations A and A denoting the stereochemical configuration of the metal center: Ernst, R. E.; O’Connor, M. J.; Holm, R. H. J. Am. Chem. Soc. 1967, 89, 6104.
14. A positive δ corresponds to a higher resonance frequency (“deshielding”) with respect to the reference frequency. (19) Eichhorn, G. L.; Bailar, J. C., Jr. J. Am. Chem. Soc. 1953, 75, 2905. Eichhorn, G. L.; Trachtenberg, I. M. J. Am. Chem. Soc. 1954, 76, 5183.
15. Beckingsale, P. G.; Morcom, A. T.; Rickard, C. E. F.; Waters, T. N. J. Chem. Soc., Dalton Trans. 1977, 2135. (21) Ho, R. K. Y.; Livingstone, S. E. Aust. J. Chem. 1965, 18, 659.
16. Schilstra, M. J.; Birker, P. J. M. W. L.; Verschoor, G. L.; Reedijk, J. Inorg. Chem. 1982, 21, 2637. Brubaker, G. R.; Brown, J. N.; Yoo, M. K.; Kinsey, R. A.; Kutchan, T. M.; Mottel, E. A. Inorg. Chem. 1979, 18, 299.
17. (24) Keijsper, J.; Van der Poel, H.; Polm, L. H.; Van Koten, G.; Vrieze, K.; Seignette, P. F. A. B.; Varenhorst, R.; Stam, C. H. Polyhedron 1983, 2, 1111.
18. Van Koten, G.; Vrieze, K. Reel. Trav. Chim. Pays-Bas 1981, 100, 129. (26) Sorrell, T. N.; Jameson, D. L. J. Am. Chem. Soc. 1982, 104, 2053. Hendriks, H. M. J.; Birker, P. J. M. W. L.; van Rijn, J.; Verschoor, G. C.; Reedijk, J. J. Am. Chem. Soc. 1982, 104, 3607.
19. Spek, A. L.; Duisenberg, A. J. M.; Klop, E. A.; Van Stein, G. C.; Van Koten, G. Acta Crystallogr., Sect. C: Cryst. Struct. Commun., in press.
20. IUPAC. “Nomenclature of Organic Chemistry”; Pergamon Press: Oxford, 1979; p 484.