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-1 or less.
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0345940523
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1 suggest that its origin involves the totally symmetric breathing mode of the heterocyclic ring.
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-1 increases in intensity, relative to the rest of the stretching contour, with rising temperature. This results from H-bond breakage. See Ref. (18).
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27
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0347200944
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Dore, J. C.; Teixeira, J.; Eds.; Kluwer Academic: Dordrecht
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0347200945
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note
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2O, see Ref. 4, refer to the polarization geometry, X(ZX)Y. This polarization gives a Raman spectrum which refers solely to the anisotropy of thepolarizability.
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30
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36549096182
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0345939592
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note
-
2O is 1.38. The ratio of the corresponding experimental vibiational frequencies is about 1.37 ± 0.03. This ratio is difficult to determine because of the extreme breadth of the stretching contours.
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36
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33748526213
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