Emission Energy Correlates with Inverse of Gold-Gold Distance for Various [Au(SCN)2]- Salts

Journal of the American Chemical Society

Volumn 126, Issue 1, 2004, Pages 12-13

  Coker, Nathan L ^a   Krause Bauer, Jeanette A ^a   Elder, R C ^a  

^a UNIVERSITY OF CINCINNATI   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BIS(THIOCYANATO)AURATE; CARBON; DIMER; GOLD; INORGANIC SALT; NITROGEN; SULFUR; UNCLASSIFIED DRUG;

ARTICLE; ATOM; CHEMICAL BOND; CHEMICAL STRUCTURE; CRYSTAL STRUCTURE; ENERGY; LUMINESCENCE; SOLID STATE; STRUCTURE ANALYSIS; ULTRAVIOLET SPECTROSCOPY; X RAY CRYSTALLOGRAPHY;

EID: 0347760142     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja037012f     Document Type: Article

References (10)

1. Rawashdeh-Omary, M. A.; Omary, M. A.; Patterson, H. H.; Fackler, J. P., Jr. J. Am. Chem. Soc. 2001, 123, 11237-11247.
2. Lee, Y.-A.; McGrath, J. E.; Lachicotte, R. J.; Eisenberg, R. J. Am. Chem. Soc. 2002, 124, 10662-10663.
3. Forward, J. M.; Bohmann, D.; Fackler, J. P., Jr.; Staples, R. J. Inorg. Chem. 1995, 34, 6330-6336.
4. van Zyl. W. E.; López-de-Luzuriaga, J. M.; Mohamed, A. A.; Staples, R. J.; Fackler, J. P., Jr. Inorg. Chem. 2002, 41, 4579-4589.
5. LeBlanc, J. D. Thiol Complexes of Gold(1): Structure and Chemistry of the Gold Based Antiarthritis Drugs. Ph.D. Dissertation. McMaster University, Hamilton, Canada, 1996.
6. min/max = 2.63/28.29°, 1854 [I > 2σ(I)] unique observed reflections were used to refine 148 variable parameters and gave a final R factor of 0.0519.
7. + are 320, 320, 320, 320, 360, 325, and 360 nm, respectively.
8. 2 = 0.8464).
9. + datum there appears to be a clear linear relationship between the inverse of metal center distances and the emission energies for the compounds studied.
10. Arvapally, R. K.; Coker, N. L.; Hettiarachchi, S. R.; Elder, R. C.; Patterson, H. H.; Omary, M. A. Abstracts of Papers. 225th National Meeting of the American Chemical Society, New Orleans, LA. March 23-27, 2003; American Chemical Society: Washington, DC. 2003; INOR-570.