A Better Understanding of the Self-Structuration of Bridged Silsesquioxanes

Angewandte Chemie - International Edition

Volumn 43, Issue 2, 2003, Pages 203-206

  Moreau, Joël J E ^a   Pichon, Benoît P ^a   Wong Chi Man, Michel ^a   Bied, Catherine ^a   Pritzkow, Hans ^b   Bantignies, Jean Louis ^c   Dieudonné, Philippe ^c   Sauvajol, Jean Louis ^c  

^a Laboratoire de Chimie Macromoleculaire UMR 5076   (France)

^b UNIVERSITY OF HEIDELBERG   (Germany)

^c CNRS   (France)

Author keywords

Hydrogen bonds; Nanostructures; Organic inorganic hybrid composites; Self assembly; Silsesquioxanes

Indexed keywords

CRYSTALLINE MATERIALS; HYDROGEN BONDS; HYDROLYSIS; MOLECULAR STRUCTURE;

MOLECULAR PRECURSOR;

SILICA;

BRIDGED COMPOUND; INORGANIC COMPOUND; ORGANIC COMPOUND; SILSESQUIOXANE DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CRYSTAL STRUCTURE; HYDROGEN BOND; HYDROLYSIS; MOLECULAR INTERACTION; NANOPARTICLE; PRECURSOR;

EID: 0347753821     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200352485     Document Type: Article

References (25)

1. C. Sanchez, F. Ribot, New J. Chem. 1994, 18, 1007-1047.
2. D. Avnir, Acc. Chem. Res. 1995, 28, 328-334.
3. a) Organic/inorganic Hybrid Materials, MRS Symp. Vol. 628 (Eds.: R. M. Laine, C. Sanchez, C. J. Brinker, E. Giannelis), 2000;
4. b) Organic/inorganic Hybrid Materials, MRS Symp. Vol. 726 (Eds.: R. M. Laine, C. Sanchez, C. J. Brinker, E. Giannelis), 2002.
5. K. J. Shea, D. A. Loy, O. W. Webster, J. Am. Chem. Soc. 1992, 114, 6700-6710.
6. R. J. P. Corriu, J. J. E. Moreau, P. Thépot, M. Wong Chi Man, Chem. Mater. 1992, 4, 1217-1224.
7. U. Schubert, New J. Chem. 1994, 18, 1049-1058.
8. A. Adima, J. J. E. Moreau, M. Wong Chi Man, Chirality 2000,12, 411-420.
9. J.-C. Broudic, O. Conocar, J. J. E. Moreau, D. Meyer, M. Wong Chi Man, J. Mater. Chem. 1999, 9, 2283-2285.
10. B. Lebeau, S. Brasselet, J. Zyss, C. Sanchez, Chem. Mater. 1997, 9, 1012-1021.
11. C. T. Kresge, M. E. Leonowicz, W. J. Roth, J. C. Vartulli, J. S. Beck, Nature 1992, 359, 710-712.
12. a) S. Inagaki, S. Guan, T. Ohsuna, O. Terasaki, Nature 2002, 416, 304-307;
13. b) B. J. Melde, B. T. Holland, C. F. Blanford, A. Stein, Chem. Mater. 1999, 11, 3302-3308;
14. c) T. Asefa, M. J. MacLachlan, N. Coombs, G. A. Ozin, Nature 1999, 402, 867-871;
15. d) A. Sayari, S. Hamoudi, Y. Yang, I. L. Moudrakovski, J. R. Ripmeester, Chem. Mater. 2000, 12, 3857-3863;
16. e) Y. Lu, H. Fan, N. Doke, D. A. Loy, R. A. Assink, D. A. LaVan, C. J. Brinker, J. Am. Chem. Soc. 2000, 122, 5258-5261.
17. B. Boury, R. J. P. Corriu, Chem. Commun. 2002, 795-802.
18. a) J. J. E. Moreau, L. Vellutini, M. Wong Chi Man, C. Bied, J. Am. Chem. Soc. 2001, 123, 1509-1510;
19. b) J. J. E. Moreau, L. Vellutini, M. Wong Chi Man, C. Bied, Chem. Eur. J. 2003, 9, 1594-1999;
20. c) J. J. E. Moreau, L. Vellutini, M. Wong Chi Man, C. Bied, J.-L. Bantignies, P. Dieudonné, J.-L. Sauvajol, J. Am. Chem. Soc. 2001, 123, 7957-7958.
21. a) N. Liu, K. Yu, B. Smarsly, D. R. Dunphy, Y.-B. Jiang, C. J. Brinker, J. Am. Chem. Soc. 2002, 124, 14540-14541;
22. b) N. Liu, D. R. Dunphy, M. A. Rodriguez, S. Singer, C. J. Brinker, Chem. Commun. 2003, 1144-1145.
23. H. Muramatsu, R. J. P. Corriu, B. Boury, J. Am. Chem. Soc. 2003, 125, 854-855.
24. 2 (SHELXTL NT 5.1, Bruker-AXS 1998), 405 parameters, R1 = 0.085, wR2 = 0.187, with disorder of some of the ethoxy groups. CCDC-215379 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/conts/retrieving.html (or from the Cambridge Crystallographic Data Centre, 12, Union Road, Cambridge CB21EZ, UK; fax: (+44)1223-336-033; or deposit@ ccdc.cam.ac.uk).
25. G. Careri, U. Buontempo, F. Galluzzi, A. C. Scott, E. Gratton, E. Shyamsunder, Phys. Rev. B 1984, 30, 4689-4702.