Molecular Structure of RbSCN Complex with N-(4′-hydroxy-3′,5′-diisopropylbenzyl)-monoaza-15-crown-5 Ether: Two Structures in a Unit Cell

Supramolecular Chemistry

Volumn 13, Issue 4, 2001, Pages 539-543

  Habata, Yoichi ^a   Watanabe, Atsushi ^a   Akabori, Sadatoshi ^a  

^a TOHO UNIVERSITY   (Japan)

Author keywords

Alkali metal; Complex; Crown ether; Crystal structure; Polymer like

Indexed keywords

EID: 0347608299     PISSN: 10610278     EISSN: None     Source Type: Journal    
DOI: 10.1080/10610270108028300     Document Type: Article

References (11)

1. Gluzinski, P., Krajewski, J. W., Urbanczyk-Lipkowska, Z., Andreetti, G. D. and Bocelli, G. (1984). Acta Crystallogr., Sec. C., C40, 778; Shu, M. P., Shim, B. Y. and Yoon, T. S. (1994). Inorg. Chem., 33, 5509; Sibert, J. W., Lange, S. J., Williams, D. J., Barrett, A. G. M. and Hoffman, B. M. (1995). Inorg. Chem., 34, 2300; Olsher, U., Frolow, F., Weiming, J., Yu, Z., Knobeloch, J. M. and Bartsch, R. A. (1991). J. Am. Chem. Soc., 113, 6570.
2. Gluzinski, P., Krajewski, J. W., Urbanczyk-Lipkowska, Z., Andreetti, G. D. and Bocelli, G. (1984). Acta Crystallogr., Sec. C., C40, 778; Shu, M. P., Shim, B. Y. and Yoon, T. S. (1994). Inorg. Chem., 33, 5509; Sibert, J. W., Lange, S. J., Williams, D. J., Barrett, A. G. M. and Hoffman, B. M. (1995). Inorg. Chem., 34, 2300; Olsher, U., Frolow, F., Weiming, J., Yu, Z., Knobeloch, J. M. and Bartsch, R. A. (1991). J. Am. Chem. Soc., 113, 6570.
3. Gluzinski, P., Krajewski, J. W., Urbanczyk-Lipkowska, Z., Andreetti, G. D. and Bocelli, G. (1984). Acta Crystallogr., Sec. C., C40, 778; Shu, M. P., Shim, B. Y. and Yoon, T. S. (1994). Inorg. Chem., 33, 5509; Sibert, J. W., Lange, S. J., Williams, D. J., Barrett, A. G. M. and Hoffman, B. M. (1995). Inorg. Chem., 34, 2300; Olsher, U., Frolow, F., Weiming, J., Yu, Z., Knobeloch, J. M. and Bartsch, R. A. (1991). J. Am. Chem. Soc., 113, 6570.
4. Gluzinski, P., Krajewski, J. W., Urbanczyk-Lipkowska, Z., Andreetti, G. D. and Bocelli, G. (1984). Acta Crystallogr., Sec. C., C40, 778; Shu, M. P., Shim, B. Y. and Yoon, T. S. (1994). Inorg. Chem., 33, 5509; Sibert, J. W., Lange, S. J., Williams, D. J., Barrett, A. G. M. and Hoffman, B. M. (1995). Inorg. Chem., 34, 2300; Olsher, U., Frolow, F., Weiming, J., Yu, Z., Knobeloch, J. M. and Bartsch, R. A. (1991). J. Am. Chem. Soc., 113, 6570.
5. Habata, Y. and Akabori, S. (1996). J. Chem. Soc., Dalton Trans., 3871.
6. Reviews for the Mannich reaction. Bricke, F. F. (1949). Org. React., 5, 301; Tramontini, M. and Angiolini, L. (1990). Tetrahedron, 46, 1791; Trost, B. M., Fleming, I. and Heathcock, C. H. (1991). Comprehensive organic synthesis. Oxford: Pergamon Press, pp. 893-1109.
7. Reviews for the Mannich reaction. Bricke, F. F. (1949). Org. React., 5, 301; Tramontini, M. and Angiolini, L. (1990). Tetrahedron, 46, 1791; Trost, B. M., Fleming, I. and Heathcock, C. H. (1991). Comprehensive organic synthesis. Oxford: Pergamon Press, pp. 893-1109.
8. Reviews for the Mannich reaction. Bricke, F. F. (1949). Org. React., 5, 301; Tramontini, M. and Angiolini, L. (1990). Tetrahedron, 46, 1791; Trost, B. M., Fleming, I. and Heathcock, C. H. (1991). Comprehensive organic synthesis. Oxford: Pergamon Press, pp. 893-1109.
9. A review for the syntheses of armed-aza crown ethers using the Mannich reaction. Bordunov, A. V., Bradshaw, J. S., Pastushok, V. N. and Izatt, R. M. (1996). Synlett, 966 and references cited therein.
10. Compounds 2, 3 and their RbSCN complexes were synthesized according to the reported method. [2] Satisfactory spectroscopic and analytical data for compounds 2, 3, 2-RbSCN and 3-RbSCN have been obtained.
11. Crystal data for 2-RbSCN and 3-RbSCN. X-ray diffraction measurements were made on a Rigaku AFC5S four-circle diffractometer with graphite-monochromated Mo-Kα radiation (10.71069 Å) at 23°C and a 12kW rotating-anode generator.