Structural characterization of products from fuel-rich combustion: An approach based on size exclusion chromatography

Combustion Science and Technology

Volumn 174, Issue 11-12, 2002, Pages 345-359

  Apicella, B ^a   Ciajolo, A ^a   Suelves, I ^b   Morgan, T J ^c   Herod, A A ^c   Kandiyoti, R ^c  

^a CNR   (Italy)

^b INSTITUTO DE CARBOQUÍMICA   (Spain)

^c IMPERIAL COLLEGE LONDON   (United Kingdom)

Author keywords

Size exclusion chromatography; Soot

Indexed keywords

CHLORINE COMPOUNDS; ETHYLENE; FLAME RESEARCH; LIGHT ABSORPTION; LIGHT SCATTERING; MOLECULAR STRUCTURE; MOLECULAR WEIGHT; PARTICLES (PARTICULATE MATTER); SIZE EXCLUSION CHROMATOGRAPHY; SOLUBILITY; SOOT; STRUCTURE (COMPOSITION);

DICHLOROMETHANE; POLYCYCLIC AROMATIC HYDROCARBON; PREMIXED LAMINAR FLAME; STRUCTURAL CHARACTERIZATION;

COMBUSTION;

EID: 0347541145     PISSN: 00102202     EISSN: None     Source Type: Journal    
DOI: 10.1080/713712962     Document Type: Article

References (30)

1. Apicella, B. (2000) Chemical and Spectroscopic Properties of Condensed Species in Rich Combustion Processes. Ph.D. Dissertation, Department of Chemical Engineering, University of Naples, Italy.
2. Begon, V., Megaritis, A., Lazaro, M.-J., Herod, A.A., Dugwell, D.R., and Kandiyoti, R. (1998) Changes in sample reactivity and catalyst deactivation during early stages of the hydrocracking of a coal extract. Fuel, 77, 1261-1272.
3. Ciajolo, A., Apicella, B., Barbella, R., and Tregrossi, A. (2000) Correlations of the spectroscopic properties with the chemical composition of flame-formed aromatic mixtures. Comb. Sci. Technol., 153, 19-32.
4. Ciajolo, A., Barbella, R., Tregrossi, A., and Bonfanti, L. (1998) Spectroscopic and compositional signatures of PAH-loaded mixtures in the soot inception region of a premixed ethylene flame. Proc. Combust. Instit., 27, 1481-1487.
5. Ciajolo, A., D'Anna, A., and Barbella, R. (1994) PAH and high molecular weight species formed in a premixed methane flame. Combust. Sci. Technol., 100, 271-281.
6. Ciajolo, A., D'Anna, A., Barbella, R., Tregrossi, A., and Violi, A. (1996) The effect of temperature on soot inception in premixed ethylene flame. Proc. Combust. Instit., 26, 2327-2333.
7. Ciajolo, A., Ragucci, R., Apicella, B., Barbella, R., de Joannon, M., and Tregrossi, A. (2001) Fluorescence spectroscopy of aromatic species produced in rich premixed ethylene flames. Chemosphere, 42, 835-841.
8. Deelchand, J.P., Naqvi, Z., Dubau, C., Shearman, J., Lazaro, M.-J., Herod, A.A., Read, H., and Kandiyoti, R. (1999) Planar chromatographic separation of petroleum residues and coal-derived liquids. J. Chromatogr. A, 380, 397-414.
9. Dockery, D.W. and Pope, C.A., III (1994) Acute respiratory effects of particulate air pollution. Annu. Rev. Public Health, 15, 107-132.
10. Domin, M., Herod, A.A., Kandiyoti, R., Larsen, J.W., Lazaro, M.-J., Li, S., and Rahimi, P. (1999) A comparative study of bitumen molecular weight distributions. Energy Fuels, 3, 552-557.
11. Freudenthal, R.I. and Jones, P.W. (1976) Polynuclear Aromatic Hydrocarbons: Chemistry, Metabolism and Carcinogenesis, Vol. I, Raven, New York.
12. Gelboin, H.V. and Ts'o, P.O.P. (1978) P.H. and Cancer, Academic Press, New York.
13. Haynes, B.S. and Wagner, H. Gg. (1981) Soot formation. Prog. Energy Combust. Sci., 7, 229-273.
14. Herod, A.A., Islas, C., Lazaro, M.-J., Dubau, C., Carter, J.F., and Kandiyoti, R. (1999) Correlation of pyrolysis-gas chromatography mass spectra and nuclear magnetic resonance spectra of pitch fractions separated by planar chromatography. Rapid Commun. Mass Spectrom., 13, 201-210.
15. Herod, A.A. and Kandiyoti, R. (1995) Detection of high-molecular-mass materials in coal-derived liquids by independent techniques. Fuel, 74, 784-786.
16. Herod, A.A., Lazaro, M.-J., Domin, M., Islas, C.A., and Kandiyoti, R. (2000) Molecular mass distributions and structural characterisation of coal derived liquids. Fuel, 79, 323-337.
17. Herod, A.A., Lazaro, M.-J., Rahman, M., Domin, M., Cocksedge, M.J., and Kandiyoti, R. (1997) Matrix-assisted laser desorption/ionization time-of-flight mass spectrometry of kerogen extracts: Effect of interactions between sample structure and matrix. Rapid Commun. Mass Spectrom., 11, 1627-1634.
18. Herod, A.A., Lazaro, M.-J., Shearman, J., Card, J., Jones, A.R., and Kandiyoti, R. (1999) Observation of high-mass liquids in the condensate from the pyrolysis of coals in a methane flame. Fuel, 78, 861-863.
19. Herod, A.A., Lazaro, M.J., Suelves, I., Dubau, C., Richaud, R., Shearman, J., Card, J., Jones, A.R., and Kandiyoti, R. (2000) Size-exclusion chromatography of soot and coal-derived materials with 1-methyl-2-pyrrolidinone as eluent: Observations on high molecular mass material. Energy Fuels, 14, 1009-1020.
20. Herod, A.A., Zang, S.F., Johnson, B.R., Bartle, K.D., and Kandiyoti, R. (1996) Solubility limitations in the determination of molecular mass distributions of coal liquefaction and hydrocracking products: 1-Methyl-2-pyrrolidinone as mobile phase in size exclusion chromatography. Energy Fuels, 10, 743-750.
21. Islas, C.A., Suelves, I., Carter, J.F., Herod, A.A., and Kandiyoti, R. (2000) Pyrolysis-gas chromatography/mass spectrometry of a coal extract and its fractions separated by planar chromatography: Correlation of structural features with molecular mass. Rapid Commun. Mass Spectrom., 14, 1766-1782.
22. Islas, C.A., Suelves, I., Carter, J.F., Herod, A.A., and Kandiyoti, R. (2001) Structural characterization of Baltic amber and its solvent extracts by several mass spectrometric methods. Rapid Commun. Mass Spectrom., 15, 845-856.
23. Johnson, B.R., Bartle, K.D., Herod, A.A., and Kandiyoti, R.J. (1997) N-Methyl-2-pyrrolidinone as a mobile phase in the size-exclusion chromatography of coal derivatives. J. Chromatogr., A, 758, 65-74.
24. Lazaro, M.J., Domin, M., Herod, A.A., and Kandiyoti, R. (1999) Fractionation of a wood tar by planar chromatography for the characterisation of large molecular mass materials. J. Chromatogr., A, 840, 107-115.
25. Lazaro, M.J., Islas, C.A., Herod, A.A., and Kandiyoti, R. (1999) Calibration of size exclusion chromatography in 1-methyl-2-pyrrolidinone for coal-derived liquids by using standards and mass spectrometry. Energy Fuels, 13, 1212-1222.
26. Li, C., Wu, F., Cai, H., and Kandiyoti, R. (1994) UV-fluorescence spectroscopy of coal pyrolysis tars. Energy Fuels, 8, 1039-1048.
27. Pipatmanomai, S., Islas, C.A., Suelves, I., Herod, A.A., and Kandiyoti, R. (2001) Pyrolysis of Baltic amber in a wire mesh pyrolyser: Structural comparisons with amber-extracts in NMP. J. Anal. Appl. Pyrolysis, 58, 299-313.
28. Richaud, R., Lazaro, M.-J., Lachas, H., Miller, B.B., Herod, A.A., Dugwell, D.R., and Kandiyoti, R. (2000) Identification of organically associated trace elements in wood and coal by ICP-mass spectrometry. Rapid Commun. Mass Spectrom., 14, 317-328.
29. Suelves, I., Islas, C.A., Herod, A.A., and Kandiyoti, R. (2001) Comparison of fractionation methods for the structural characterisation of petroleum residues. Energy Fuels, 15, 429-437.
30. Tompkins, E.E. and Long, R. (1970) The flux of polycyclic aromatic hydrocarbons and insoluble material in premixed acetylene-oxygen flames. Proc. Combust. Instit., 13, 625-634.