Template Synthesis and Single-Molecule Magnetism Properties of a Complex with Spin S = 16 and a [Mn8O8]8+ Saddle-Like Core

Journal of the American Chemical Society

Volumn 125, Issue 50, 2003, Pages 15274-15275

  Tasiopoulos, Anastasios J ^a   Wernsdorfer, Wolfgang ^b   Moulton, Brian ^c   Zaworotko, Michael J ^c   Christou, George ^a  

^a University of Florida ^*  (United States)

^b LABORATOIRE DE CRISTALLOGRAPHIE   (France)

^c UNIVERSITY OF SOUTH FLORIDA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CERIUM; MANGANESE DERIVATIVE; OXYGEN DERIVATIVE; POLYMER;

ACCELERATION; ANISOTROPY; ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; CRYSTALLIZATION; HYDROGEN BOND; MAGNET; MAGNETISM; MOLECULAR INTERACTION; PARAMETER; QUANTUM MECHANICS; STRUCTURE ANALYSIS; SYNTHESIS; TECHNIQUE;

EID: 0347480558     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja0385134     Document Type: Article

References (18)

1. Christou, G.; Gatteschi, D.; Hendrickson, D. N.; Sessoli, R. MRS Bull. 2000, 25, 66.
2. (a) Sessoli, R.; Tsai, H.-L.; Schake, A. R.; Wang, S.; Vincent, J. B.; Folting, K.; Gatteschi, D.; Christou, G.; Hendrickson, D. N. J. Am. Chem. Soc. 1993, 115, 1804.
3. (b) Sessoli, R.; Gatteschi, D.; Caneschi, A.; Novak, M. A. Nature 1993, 365, 141.
4. (a) Brechin, E. K.; Boskovic, C.; Wemsdorfer, W.; Yoo, J.; Yamaguchi, A. ; Sanudo, E. C.; Concolino, T. R.; Rheingold, A. L.; Ishimoto, H.; Hendrickson, D. N.; Christou, G. J. Am. Chem. Soc. 2002, 124, 9710.
5. (b) Brockman, J. T.; Abboud, K. A.; Hendrickson, D. N.; Christou, G. Polyhedron 2003, 22, 1765.
6. (a) Brechin, E. K.; Soler, M.; Davidson, J.; Hendrickson, D. N.; Parsons, S.; Christou, G. Chem. Commun. 2002, 2252.
7. (b) Soler, M.; Wemsdorfer, W.; Abboud, K. A.; Huffman, J. C.; Davidson, E. R.; Hendrickson, D. N.; Christou, G. J. Am. Chem. Soc. 2003, 125, 3576.
8. Goodwin, J. C.; Sessoli, R.; Gatteschi, D.; Wemsdorfer, W.; Powell, A. K.; Heath, S. L. J. Chem. Soc., Dalton Trans. 2000, 1835.
9. Tasiopoulos, A. J.; O'Brien, T. A.; Abboud, K. A.; Christou, G. unpublished.
10. Dolbecq, A.; Secheresse, F. Adv. Inorg. Chem. 2002, 53, 1.
11. Tasiopoulos, A. J.; Harden, N. C.; Abboud, K. A.; Christou, G. Polyhedron 2003, 22, 133.
12. 2O: C 18.47 (18.49), H 3.36 (3.32).
13. -3, T = 100 K. Final R1 = 8.99 and wR2 = 21.63%. The crystal was a small, thin plate; an absorption correction was applied.
14. 10c ions of 1 gave oxidation state values of 2.84-3.03 and 3.73-3.96, respectively.
15. (b) Liu, W.; Thorp, H. H. Inorg. Chem. 1993, 32, 4102.
16. (c) Roulhac, P. L.; Palenik, G. J. Inorg. Chem. 2003, 42, 118.
17. Wernsdorfer, W.; Orozco Bonet, E.; Hasselbach, K.; Benoit, A.; Mailly, D.; Kubo, O.; Nakano, H.; Barbara, B. Phys. Rev. Lett. 1997, 79, 4014.
18. Larionova, J.; Gross, M.; Pilkington, M.; Andres, H.; Stoeckli-Evans, H. ; Gudel, H.; Decurtins, S. Angew. Chem., Int. Ed. 2000, 39, 1605.