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Volumn 9, Issue 1, 1998, Pages 29-33

The ephemeral 10β-OH trifluoromethanesulfonates of 7-Epi paclitaxel analogs - A new example for anchimeric assistance

Author keywords

Anchimeric assistance; Neighboring group participatioa; Rearrange

Indexed keywords


EID: 0347371460     PISSN: 10018417     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article
Times cited : (1)

References (34)
  • 14
  • 15
    • 0029036346 scopus 로고    scopus 로고
    • (a) S. Py, J. W. Pan, and F. Khoung-Huu, Tetrahedron Aube, G. I. Georg, and L. Jayasinghe, J. Org. Chem. 1995, 60, 2918-2921. 1994, 50, 6881-6890.
    • (1995) J. Org. Chem. , vol.60 , pp. 2918-2921
    • Aube1    Georg, G.I.2    Jayasinghe, L.3
  • 16
    • 0029036346 scopus 로고    scopus 로고
    • (a) S. Py, J. W. Pan, and F. Khoung-Huu, Tetrahedron Aube, G. I. Georg, and L. Jayasinghe, J. Org. Chem. 1995, 60, 2918-2921. 1994, 50, 6881-6890.
    • (1994) J. Org. Chem. , vol.50 , pp. 6881-6890
  • 26
    • 3142577417 scopus 로고    scopus 로고
    • note
    • 10(11),12(18) dienone is thermodynamically stable due to its conjuagated cis-diene substructure which is confirmed by its IR.
  • 28
    • 3142531074 scopus 로고    scopus 로고
    • note
    • (15b) to ensure correct structure determination.
  • 30
    • 3142529019 scopus 로고    scopus 로고
    • note
    • (a) The 10-acetyl products of compound 6, 8 and 10 are prepared from 10-deacetylbaccatin III, paclitaxel and 7-epi-10-deacetylpaclitaxel respectively by common silylation and acylation. Selective hydrolysis of 10-OAc in these compounds were performed with hydrazine monohydrate in 95% ethanol.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.