Enthalpy of mixing and excess volume of binary metallic melts of eutectic systems

Powder Metallurgy and Metal Ceramics

Volumn 42, Issue 5-6, 2003, Pages 278-284

  Nizhenko, V I ^a  

^a FRANTSEVICH INSTITUTE FOR PROBLEMS OF MATERIALS SCIENCE   (Ukraine)

Author keywords

Enthalpy of mixing; Eutectic system; Excess volume; Melt

Indexed keywords

COVALENT BONDS; ELECTRONEGATIVITY FACTORS;

BINARY ALLOYS; CHEMICAL BONDS; ENTHALPY; MIXING; MIXTURES; PHASE DIAGRAMS; PHASE EQUILIBRIA;

EUTECTICS;

EID: 0347269022     PISSN: 10681302     EISSN: None     Source Type: Journal    
DOI: 10.1023/A:1025771629603     Document Type: Article

References (46)

1. I.T. Sryvalin, O. A. Esin, N. A. Vatolin, et al., "Thermodynamics of liquid metallic alloys," in: Physical Chemistry of Metallurgical Melts [in Russian], Institute of Metallurgy, Urals Branch, Academy of Sciences of USSR, Sverdlovsk (1969), No. 18, pp. 3-44.
2. T. G. Kryshtab, V. A. Lenichenko, E. I. Khar'kov, and S. V. Shvets, "Interrelationship between heats of mixing and changes in molar volumes in formation of liquid binary alloys," Ukr. Fiz. Zhurn., 18, No. 4, 681-683 (1973).
3. D. R. Wilson, Structure of Liquid Metals and Alloys [Russian translation], Metallurgiya, Moscow (1972).
4. R. Hultgren, R. L. Orr, P. D. Anderson, and K. K. Kelley, Selected Values of Thermodynamic Properties of Metals and Alloys, Wiley, New York/London (1963).
5. B. Djemili, L. Martin-Garin, R. Martin-Garin, and P. Desre, "Densities of indium, cadmium, and Cd - In alloys in the liquid state," J. Less-Common Met., 78, No. 2, 189-195 (1981).
6. V. I. Nizhenko and Yu. I. Smirnov, "Temperature dependence of the density and surface tension of melts in the aluminum - tin system," Rasplavy, No. 1, 3-8 (1995).
7. V. I. Nizhenko and L. I. Floka, "Surface properties and density of melts in the cobalt - gold system," in: Surface Properties of Melts [in Russian], Nauk. Dumka, Kiev (1982), pp. 127-133.
8. 8. V. V. Berezutskii, V. N. Eremenko, and G. M. Lukashenko, "Some thermodynamic properties of gold - cobalt melts," Izv. Akad. Nauk SSSR, Metally, No. 2, 54-56 (1975).
9. V. I. Kononenko, S. P. Yatsenko, and A. L. Sukhman, "Surface properties of indium - gallium and indium - tin alloys," Zhurn. Fiz. Khim., 46, No. 6, 1589-1590 (1972).
10. B. Predel and A. Emam, "Excess volume of liquid alloys in the indium - bismuth, indium - lead, indium zinc, and lead - zinc systems," Thermochim. Acta, 7, No. 1, 1-12 (1973).
11. A. E. Schwaneke, W. L. Falke, and V. R. Mille, "Surface tension and density of liquid tin - lead alloys," J. Chem. Eng. Data, 23, No. 4, 298-301 (1978).
12. S. I. Popel', V. N. Kozhurkov, and T. V. Zakharova, "Density and surface tension of lead - tin melts and their adhesion to iron," Zashchita Metallov, 7, No. 4, 428-426 (1971).
13. P. E. Berthou and R. Tougas, "The density of liquid tin - thallium alloys," J. Less-Common Met., 16, No. 4, 465-467 (1968).
14. B. Predel and A. Emam, "Excess volume of liquid alloys in the Bi - Sn, Sn - Tl, Pb - Sn, Bi - Tl, Hg - In, Hg - Tl, and Pb - Tl," Mater. Sci. Eng., 4, No. 5, 287-296 (1969).
15. Abowitz and R. B. Gordon, "Compressibility of mercury alloys," Trans. Metallurg. Soc. AIME, 227, No. 1, 51-59 (1963).
16. D. V. Khantadze and N. I. Topuridze, "Taking into account geometric nonequivalence in calculating excess volume and surface tension of melts," in: The Physics of Surface Phenomena in Melts, Izdat. Checheno-Ingush. Univ., Groznyi (1978), Pt. 2, pp. 11-16.
17. N. I. Topuridze, Density and Surface Tension of Binary Metallic Melts with Weakly Interacting Components, PhD Thesis [in Russian], Tbilisi (1978).
18. F. Sauerwald, "The densities of molten alloys with segregation tendencies," Adv. Phys., 16, No. 63, 545-550 (1967).
19. L. Martin-Garin, M. Gomez, P. Bedon, and P. Desre, "Densities of silver, germanium, and Ag - Ge alloys in the liquid state," J. Less-Common Met., 45, No. 1, 65-76 (1975).
20. M. Gomez, L. Martin-Garin, H. Ebert, et al., "Densities of molten copper and molten bismuth - copper alloys," Z. Metallk., 67, No. 2, 131-134 (1976).
21. M. Huijben, H. Klaucke, J. Hennerhot, and W. van der Lugt, "Density of liquid sodium - cesium alloys," Scr. Met., 9, No. 6, 653-656 (1975).
22. D. V. Khantadze and T. A. Tsuladze, "Density of sodium - rubidium and sodium - cesium melts," Zhurn. Fiz. Khim., 53, No. 3, 754-755 (1979).
23. N. I. Topuridze and D. V. Khantadze, "Taking into account the geometric factor when calculating the excess volume of a solution," Zhurn. Fiz. Khim., 52, No. 1, 81-84 (1978).
24. D. V. Khantadze and N. I. Topuridze, "Mechanism for compaction of two-component bulk media, modeled by spherical particles," Inzh.-Fiz. Zhurn., 33, No. 1, 120-125 (1977).
25. R. A. Tsuladze, D. V. Khantadze, and N. I. Topuridze, "Density and surface tension of binary alloys of germanium with tin, lead, and indium," in: Surface Properties of Melts [in Russian], Nauk. Dumka, Kiev (1982), pp. 140-143.
26. T. A. Tsuladze, Effect of Size Nonequivalence of Particles on the Density and Surface Tension of Binary Metallic Melts with Physicochemically Different Components, PhD Thesis [in Russian], Tbilisi (1985).
27. N. A. Vatolin and É. D. Pastukhov, Diffraction Studies of the Structure of High-Temperature Melts [in Russian], Nauka, Moscow (1980).
28. Yu. G. Poltavtsev, Structure of Semiconductor Melts [in Russian], Metallurgiya, Moscow (1984).
29. V. A. Shovskii, V. P. Kazimirov, S. P. Yaltanski, et al., "The structure of liquid germanium," Izv. Akad. Nauk SSSR. Metally, No. 6, 63-65 (1983).
30. G. I. Batalin, E. A. Beloborodova, and V. P. Kazimirov, Thermodynamics and Structure of Aluminum-Based Liquid Alloys [in Russian], Metallurgiya, Moscow (1983).
31. E. Gebhardt and K. Detering, "Properties of metallic melts. XVI. Internal friction of eutectic aluminum alloys," Z. Metallk., 50, No. 7, 379-385 (1959).
32. C. E. Birchenall, A. J. Harrison, and N. Balart, "Determination of density changes during melting by x-ray absorption," Met. Trans., A11, No. 7, 1213-1218 (1980).
33. P. S. Popel', E. L. Demina, E. A. Arkhangel'skii, and B. A. Baum, "Irreversible changes in the density of Al - Si melts at high temperatures," Teplofizika Vysokikh Temperatur, 25, No. 3, 487-491 (1987).
34. V.I. Nizhenko and L. I. Floka, "Density of melts in the aluminum -silicon system," Rasplavy, No. 6, 72-74 (1992).
35. E. L. Demina, "Microstratification region of eutectic melts," in: Abstracts, Third All-Union Scientific Conference on Structure Formation Patterns in Eutectic Alloys (March 1986) [in Russian], Dnepropetrovsk (1986), pp. 139-142.
36. G. I. Batalin and E. A. Beloborodova, "Thermodynamic properties of liquid alloys of aluminum with germanium," Zhurn. Fiz. Khim., 42, No. 3, 781-784 (1968).
37. B. Predel and D. W. Stein, "Thermodynamic study of germanium - aluminum and germanium - gallium systems," Z. Metallik., 62, No. 6, 499-502 (1971).
38. G. I. Batalin, E. A. Beloborodova, V. A. Stukalo, and S. S. Trofimova, "Study of thermodynamic properties of binary liquid alloys in the Ge - Ga system," Ukr. Khim. Zhurn., 38, No. 2, 1231-1233 (1972).
39. G. P. Khilya and P. S. Martsenyuk, "Density and surface tension of melts in the gallium - germanium system," Adgeziya Rasplavov i Paika Materialov, No. 19, 20-23 (1987).
40. Yu. V. Naidich, V. M. Perevertailo, and L. P. Obushchak, "Surface properties of gold - germanium and gold silicon melts," in: Physical Chemistry of the Surface of Melts, Metsniereba, Tbilisi (1977), pp. 113-121.
41. E. A. Beloborodova and G. I. Batalin, "Some characteristic patterns in the thermodynamic properties of germanium-based binary liquid alloys," Ukr. Khim. Zhurn., 43, No. 1, 34-38 (1977).
42. A. I. Vol and I. K. Kagan, Structure and Properties of Binary Metallic Systems [in Russian], Nauka, Moscow (1976), Vol. 3.
43. V. A. Evseev, L. V. Kozhitov, and V. V. Lipatov, "Heats of melting of alloys in the Sn - Si - Sb system," in: Abstracts, Second All-Union Conference on Thermodynamics and Semiconductor Materials Science [in Russian], Institute of Electronics Technology, Moscow (1983), pp. 95-96.
44. V. S. Sudavtsova, "Thermodynamic properties of Si - (Ge, Sn) binary alloys," in: Abstracts, Fourth All-Union Conference on Thermodynamics and Materials Science of Semiconductors [in Russian], Institute of Electronics Technology, Moscow (1989), Pt. 1, pp. 209-210.
45. A. L. Sukhman, S. P. Yatsenko, and V. I. Kononenko, "Density and surface characteristics of Ga - Al and Ga - Sn alloys," Izv. Akad. Nauk SSSR. Metally, No. 3, 56-57 (1972).
46. Kh. I. Ibragimov and A. G. Nal'giev, "Surface properties of melts in the gallium - tin system," The Physical Chemistry of Interfaces between Contacting Phases [in Russian], Nauk. Dumka, Kiev (1976), pp. 85-90.