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Volumn 689, Issue 2, 2004, Pages 438-443

Regioselectivity in the rhodium catalysed 1,4-hydrosilylation of isoprene. Aspects on reaction conditions and ligands

Author keywords

Catalysis; Hydrosilylation; Isoprene; Ligands; Regioselectivity; Rhodium complexes

Indexed keywords

CARBONYL DERIVATIVE; ISOPRENE; LIGAND; RHODIUM; RHODIUM COMPLEX; SOLVENT;

EID: 0347022480     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jorganchem.2003.09.054     Document Type: Article
Times cited : (14)

References (38)
  • 21
    • 0347248807 scopus 로고    scopus 로고
    • We checked the stability of the products by heating the pure isolated mixture of I and II at 80 °C for 15 h in the presence of the catalyst. No decomposition was observed and the I:II ratio was not changed
    • We checked the stability of the products by heating the pure isolated mixture of I and II at 80 °C for 15 h in the presence of the catalyst. No decomposition was observed and the I:II ratio was not changed
  • 25
    • 0346619072 scopus 로고    scopus 로고
    • CO by backdonation into π* of CO
    • CO by backdonation into π* of CO
  • 26
    • 0347879382 scopus 로고    scopus 로고
    • Due to the built-in limitations in Tolmans approach, and the fact that the used ligands have different electronic properties, this is not meant to be a strict comparison regarding size
    • Due to the built-in limitations in Tolmans approach, and the fact that the used ligands have different electronic properties, this is not meant to be a strict comparison regarding size
  • 29
    • 0000206268 scopus 로고
    • It has also been reported that thiocarbonyl complexes have a larger electron buffering effect than the corresponding carbonyl analogues. See
    • It has also been reported that thiocarbonyl complexes have a larger electron buffering effect than the corresponding carbonyl analogues. See: Lichtenberger D. Fenske R.F. Inorg. Chem. 15 1976 2015
    • (1976) Inorg. Chem. , vol.15 , pp. 2015
    • Lichtenberger, D.1    Fenske, R.F.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.