Molecularly Imprinted Polymer Membranes with Photoregulated Template Binding

Chemistry of Materials

Volumn 15, Issue 25, 2003, Pages 4703-4704

  Minoura, Norihiko ^a   Idei, Kazuto ^c   Rachkov, Alexandre ^a,b   Uzawa, Hirotaka ^a   Matsuda, Kiyomi ^c  

^a NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY AIST   (Japan)

^b JAPAN SCIENCE AND TECHNOLOGY AGENCY   (Japan)

^c NIHON UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ADSORPTION; DESORPTION; IRRADIATION; SYNTHESIS (CHEMICAL);

VISIBLE LIGHT IRRADIATION;

POLYMERIC MEMBRANES;

AZOBENZENE; COPOLYMER; DANSYL CHLORIDE; ETHYLENE GLYCOL DIMETHACRYLATE; MEROCYANINE; POLYMER; PYRAN DERIVATIVE; SPIRO COMPOUND;

ARTICLE; CATALYST; CHROMATOGRAPHY; DIPOLE; INFRARED SPECTROSCOPY; ISOMERISM; MEMBRANE; MOLECULAR IMPRINTING; MOLECULAR RECOGNITION; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; POLYMERIZATION; SENSOR; SOLID PHASE EXTRACTION; ULTRAVIOLET IRRADIATION;

EID: 0346750766     PISSN: 08974756     EISSN: None     Source Type: Journal    
DOI: 10.1021/cm0305608     Document Type: Article

References (24)

1. Haupt, K.; Mosbach, K. Chem. Rev. 2000, 100, 2495.
2. Andersson, L. I. J. Chromatogr., B 2000, 745, 3.
3. Sellergren, B. Angew. Chem., Int. Ed. 2000, 39, 1031.
4. Nicholls, I. A.; Andersson, H. S. In Molecularly Imprinted Polymers: Man-Made Mimics of Antibodies and Their Applications in Analytical Chemistry; Sellergren, B., Ed.; Elsevier: Amsterdam, 2001; Chapter 3.
5. Wulff, G. Chem. Rev. 2002, 102, 1.
6. Mathew-Krotz, J.; Shea, K. J. Am. Chem. Soc. 1996, 118, 8154.
7. Marx-Tibbon, S.; Willner, I. J. Chem. Soc., Chem. Commun. 1994, 1261.
8. Piletsky, S. A.; Panasyuk, T. L.; Piletskaya, E. V.; Nicholls, I. A.; Ulbricht, M. J. Membr. Sci. 1999, 157, 263.
9. Duffy, D. J.; Das, K.; Hsu, S. L.; Penelle, J.; Rotello, V. M.; Stidham, H. D. J. Am. Chem. Soc. 2002, 124, 8290.
10. Sueishi, Y.; Oncho, M.; Nishimura, N. Bull. Chem. Soc. Jpn. 1985, 58, 2608.
11. Keum, S.-R.; Hur, M.-S.; Kazmaier, P. M.; Buncel, E. Can. J. Chem. 1991, 69, 1940.
12. Sakuragi, M.; Aoki, K.; Tamaki, T.; Ichimura, K. Bull. Chem. Soc. Jpn. 1990, 63, 74.
13. Xie, S.; Natansohn, A.; Rochon, P. Chem. Mater. 1993, 5, 403.
14. Sellergren, B. Trends Anal. Sci. 1999, 16, 310.
15. Rachkov, A.; Minoura, N.; Shimizu, T. Opt. Mater. 2002, 21, 307.
16. cis-CH=CH-CONHR, J = 1.2 and 10.0 Hz).
17. 2 gas, it was incubated at 35 °C, in the presence of 2,2′-azobis (4-methoxy-2,4-dimethylvaleronitrile) as a free-radical initiator. The membranes were formed between two glass plates, and their thickness was set by spacers and was about 80 μm.
18. Photoisomerization was carried out by irradiation with a 500-W mercury lamp. The UV light was isolated with a UV-D35 filter. Visible light was obtained with a Y-43 filter. A TND-30% filter was used to reduce the intensity of irradiation. Absorption spectra were obtained at 25 °C in a V-530 UV-visible spectrophotometer. A piece (9 × 25 mm) of PhAAAn-containing membrane was inserted into a screw-capped quartz cell (optical path length 1 cm) containing 3 mL of acetonitrile. The membranes are stiff enough to stand inside the cell. For photoisomerization and its monitoring, the beams of both the irradiation from the mercury lamp and in the spectrophotometer were perpendicular to the plane of the tested membrane.
19. Chen, R. F.; Kernohan, J. C. J. Biol. Chem. 1967, 242, 5813.
20. Jain, A.; Huang, S. G.; Whitesides, G. M. J. Am. Chem. Soc. 1994, 116, 5057.
21. Schneider, H.-J.; Güttes, D.; Schneider, U. J. Am. Chem. Soc. 1988, 110, 6449.
22. A quartz cell having four transparent sides was used. To monitor the concentration of DA (at 251 nm), the light beam of the spectrophotometer was parallel to the plane of the tested membrane. For photoisomerization of PhAAAn within the tested membranes, the beam of irradiation from the mercury lamp was perpendicular to the plane of the tested membrane.
23. Jin, T.; Ali, A. H.; Yazawa, T. Chem. Commun. 2001, 99.
24. Murata, K.; Aoki, M.; Nishi, T.; Ikeda, A.; Shinkai, S. J. Chem. Soc., Chem. Commun. 1991, 1715.