Synthesis, crystal structure, and gas adsorption property of microporous solid by assembly of 1-D coordination polymer with a zigzag skeleton

Inorganic Chemistry Communications

Volumn 7, Issue 1, 2004, Pages 125-127

  Takamizawa, Satoshi ^a   Nakata, Ei Ichi ^a   Saito, Teruo ^a  

^a Yokohama City University   (Japan)

Author keywords

Crystal structure; Dinuclear Rh complex; Gas adsorption; Microporous solid; One dimensional polymer

Indexed keywords

COORDINATION COMPOUND; POLYMER; RHENIUM COMPLEX;

ADSORPTION; ARTICLE; CHEMICAL BOND; CRYSTAL STRUCTURE; GAS; POROSITY; SURFACE PROPERTY; X RAY DIFFRACTION;

EID: 0346730884     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2003.10.028     Document Type: Article

References (13)

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7. 2: C, 52.70; H, 3.19; N, 3.41. Found: C, 51.81; H, 3.15; N, 3.30%.
8. 2 = 1.081. The structure was solved using the Patterson method (DIRDIF94PATTY) and refined by full-matrix least squares methods (SHELXL97) using the teXsan software package. Crystallographic data (excluding structure factors) for the structure reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-209257. Copies of the data can be obtained free of charge on application to CCDC, 12 Union Road, Cambridge CB2 1EZ, UK (fax: +44-1223-336-033; e-mail: deposit@ccdc.cam.ac.uk).
9. The cavity size was estimated from the atomic distance crossing the cavity less the van der Waals diameter of 3.0 Å.
10. 2 adsorption curve using the ASWin program package.
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