Synthesis of an amino-functionalized model of the Fe-only hydrogenase active site

Chemistry - A European Journal

Volumn 9, Issue 2, 2003, Pages 557-560

  Salyi, Szabolcs ^a   Kritikos, Mikael ^a   Åkermark, Björn ^a   Sun, Licheng ^a  

^a STOCKHOLM UNIVERSITY   (Sweden)

Author keywords

Bioinorganic chemistry; Biomimetic synthesis; Iron carbonyl sulfides; Iron only hydrogenase

Indexed keywords

ELECTRONS; IRON; PROTEINS; SYNTHESIS (CHEMICAL); X RAY CRYSTALLOGRAPHY;

SUPRAMOLECULAR SYSTEMS;

SUPRAMOLECULAR CHEMISTRY;

AMINO ACID DERIVATIVE; HYDROGENASE; IRON;

ARTICLE; CHEMICAL STRUCTURE; ELECTRON TRANSPORT; ENZYME ACTIVE SITE; MOLECULAR MODEL; OXIDATION REDUCTION REACTION; SUPRAMOLECULAR CHEMISTRY; SYNTHESIS; X RAY CRYSTALLOGRAPHY;

AMINES; BINDING SITES; HYDROGENASE; IRON; MODELS, MOLECULAR; MOLECULAR MIMICRY; MOLECULAR STRUCTURE; OXIDATION-REDUCTION;

EID: 0346668229     PISSN: 09476539     EISSN: None     Source Type: Journal    
DOI: 10.1002/chem.200390058     Document Type: Article

References (34)

1. L. Florin, A. Tsokoglou, T. Happe, J. Biol. Chem. 2001, 276, 6125.
2. Y. Nicolet, B. J. Lemon, J. C. Fontecilla-Camps, J. W. Peters, Trends Biochem. Sci. 2000, 25, 138.
3. M. Y. Darensbourg, E. J. Lyon, J. J. Smee, Coord. Chem. Rev. 2000, 206-207, 533.
4. M. W. W. Adams, Biochim. Biophys. Acta 1990, 1020, 115.
5. A. E. Pryzbyla, J. Robbins. N. Menon, H. D. Peck. FEBS Microbiol. Rev. 1992, 88, 109.
6. R. Cammack, Nature 1999, 397, 214.
7. J. W. Peters, Curr. Opin. Struct. Biol. 1999, 9, 670.
8. J. W. Peters, W. N. Lanzilotta, B. J. Lemon, L. C. Seefeldt, Science 1998, 282, 1853.
9. Y. Nicolet, C. Piras, P. Legrand, E. C. Hatchikian, J. C. Fontecilla-Camps, Structure 1999, 7, 13.
10. Z.-P. Liu, P. Hu, J. Am. Chem. Soc. 2002, 124. 5175.
11. Y. Nicolet, A. L. de Lacey, X. Vernéde, V. Fernandez, E. C. Hatchikian, J. C. Fontecilla-Camps, J. Am. Chem. Soc. 2001, 123, 1596.
12. H. Li, T. B. Rauchfuss, J. Am. Chem. Soc. 2002, 124, 726.
13. J. D. Lawrence, H. Li, T. B. Rauchfuss, M. Bénard, M.-M. Rohmer, Angew. Chem. 2001, 113, 1818; Angew. Chem. Int. Ed. 2001, 40, 1768.
14. J. D. Lawrence, H. Li, T. B. Rauchfuss, M. Bénard, M.-M. Rohmer, Angew. Chem. 2001, 113, 1818; Angew. Chem. Int. Ed. 2001, 40, 1768.
15. F. Gloaguen, J. D. Lawrence, M. Schmidt, S. R. Wilson, T. B. Rauchfuss, J. Am. Chem. Soc. 2001, 123, 12518.
16. X. Zhao, I. P. Georgakaki, M. L. Miller, J. C. Yarbrough, M. Y. Darensbourg, J. Am. Chem, Soc. 2001, 123, 9710.
17. F. Gloaguen, J. D. Lawrence, T. B. Rauchfuss, J. Am. Chem. Soc. 2001, 123, 9476.
18. L. Sun, L. Hammarström, B. Åkermark, S. Styring. Chem. Soc. Rev. 2001, 30, 36.
19. A. Winter, L. Zsolnai. G. Huttner, Naturforsch, 1982, 37b, 1430.
20. A. Bhati, R. J. Hamilton, D. A. Steven, J. Chem. Soc. Perkin Trans. 2 1983, 1553.
21. S. Boyes, A. T. Hewson, J. Chem. Soc. Perkin Trans. I 2000, 2759.
22. L. M. Jr. Ellis, E. Emmet Reid, J. Am. Chem. Soc. 1932, 54, 1674.
23. B. C. Cossar, J. O. Fournier, D. L. Fields, D. D. Reynolds, J. Org. Chem. 1962, 27, 93.
24. C. Djerassi, M. Gorman, F. X. Markley, E. B. Odlenberg, J. Am. Chem. Soc. 1955, 77, 568.
25. P. A. Bobbio, J. Org. Chem. 1961, 26, 3023.
26. K. E. Yelm, Tetrahedron Lett. 1999, 40, 1101.
27. J. R. Hwu, S. Hakimelahi, K-L. Lu, S-C. Tsay, Tetrahedron 1999, 55, 8039.
28. P. Florio, R. J. Thomson, M. von Itzstein, Carbohydr. Res. 2000, 328, 445.
29. D. Crich, H. Li, J. Org. Chem. 2000, 65, 801.
30. N. Sakai, Y. Ohfune, J. Am. Chem. Soc. 1992, 114, 998.
31. C. Alvarez-Toledano, J. Enriquez, R. A. Toscano, M. Martínez-García, E. Cortés-Cortés, Y. M. Osornio, O. García-Mellado, R. Gutiérrez-Pérez, J. Organomet. Chem. 1999, 577, 38.
32. STOE, X-SHAPE revision 1.09, Crystal Optimisation for Numerical Absorption Correction, Darmstadt (Germany), 1997.
33. G. M. Sheldrick, Acta Crystallogr. 1994, A46, 467.
34. G. M. Sheldrick, SHELX97, Computer Program for the Refinement of Crystal Structures, Release 97-2, (Ed.: G. M. Sheldrick), University of Göttingen, Göttingen (Germany), 1997.