Influence of layer charge on the hydroxyl stretching of trioctahedral clay minerals: A vibrational study of synthetic Na- and K-saponites

American Mineralogist

Volumn 88, Issue 11-12 PART 1, 2003, Pages 1801-1808

  Pelletier, Manuel ^a   Michot, Laurent J ^a   Humbert, Bernard ^b   Barrès, Odile ^a   D'Espinose de la Caillerie, Jean Baptiste ^c   Robert, Jean Louis ^d  

^a Faculté des Sciences et Technologies   (France)

^b Laboratoire de Chimie Physique et Microbiologie pour l'Environnement   (France)

^c CNRS   (France)

^d UNIVERSITÉ D'ORLÉANS   (France)

Author keywords

[No Author keywords available]

Indexed keywords

HYDRATION; POPULATION STATISTICS; POSITIVE IONS; SPECTROSCOPIC ANALYSIS;

COMPENSATING CATIONS; HYDROXYL STRETCHING; INTERLAYER CATION; LINEAR RELATIONSHIPS; OCTAHEDRAL LAYERS; RAMAN SPECTROSCOPIC STUDY; STATISTICAL MODELING; TETRAHEDRAL SUBSTITUTION;

SODIUM COMPOUNDS;

CATION; CLAY MINERAL; CRYSTAL CHEMISTRY; HYDROXYL RADICAL; INFRARED SPECTROSCOPY; RAMAN SPECTROSCOPY; SAPONITE;

EID: 0346640377     PISSN: 0003004X     EISSN: None     Source Type: Journal    
DOI: 10.2138/am-2003-11-1221     Document Type: Article

References (35)

1. 2+ de saponites à piliers aluminiques, 248 p. Thèses de doctoral de l'université Paris VI. Université Paris VI. France.
2. Besson, G. and Drits, V.A. (1997a) Refined relationships between chemical composition of dioctahedral fine-grained micaceous minerals and their infrared spectra within the OH stretching region. Part I: identification of the OH-streching bands. Clays and Clay Minerals, 45, 158-169.
3. Besson, G. and Drits, V.A. (1997b) Refined relationships between chemical composition of dioctahedral fine-grained micaceous minerals and their infrared spectra within the OH stretching region. Part II: the main factors affecting OH vibrations and quantitative analysis. Clays and Clay Minerals, 45, 170-183.
4. Besson, G., Drits, V.A., Daynyak, L.G., and Smoliar, B.B. (1987) Analysis of cation distribution in dioctahedral micaceous minerals on the basis of IR spectroscopy data. Clay Minerals, 22, 465-478.
5. Chang, F.-R.C., Skipper, N.T., and Sposito, G. (1995) Computer simulation of interlayer molecular structure in sodium montmorillonite hydrates. Langmuir, 11, 2734-3741.
6. De la Calle, C. and Suquet, H. (1988) Vermiculite. In S.W. Bailey, Ed., Hydrous Phyllosilicates, 19, 455-496. Reviews in Mineralogy, Mineralogical Society of America, Washington, D.C.
7. Decarreau, A., Granby, O., and Petit, S. (1992) The actual distribution of octahedral cations in 2:1 clay minerals: results from clay synthesis. Applied Clay Sciences, 7, 147-167.
8. Farmer, V.C. (1974) The Infrared Spectra of Minerals. In V.C. Farmer, Ed., The layer silicates, Chapter 15, p. 331-363. Mineralogical Society, London.
9. Farmer, V.C. and Russell, J.D. (1967) Infrared absorption spectrometry in clay studies. In S.W. Bailey, Ed., Clays and Clay Minerals Proceedings of the fifteenth conference, Pittsburgh, Pennsylvania, p. 121-142. Pergamon Press, Oxford.
10. Fraser, A.R. and Russell, J.D. (1994) Infrared methods. In M.J. Wilson, Ed., Clay mineralogy: spectroscopic and chemical determinative methods, Chapter 2, p. 11-67. Chapman & Hall, London.
11. Hamilton, D.L. and Henderson, C.M.B. (1968) The preparation of silicate compositions by a gelling method. Mineralogy Magazine, 36, 832-838.
12. Komadel, P., Madejova, J., and Stucki, J.W. (1999) Partial stabilization of Fe(II) in reduced ferruginous smectite by Li fixation. Clays and Clay Minerals, 47, 458-465.
13. Lambert, J.F., Chevalier, S., Franck, R., Suquet, H., and Barthomeuf, D. (1994) Al-pillared saponites. Journal of Chemical Society Faraday Transaction, 90, 675-682.
14. Madejova, J. (2002) FTIR techniques in clay mineral studies. Vibrational Spectroscopy, 944, 1-10.
15. Madejova, J., Komadel, P., and Cicel, B. (1994) Infrared study of octahedral site populations in smectites. Clay Minerals, 29, 319-326.
16. Michot, L. and Viliéras, F. (2002) Assessment of surface energetic heterogeneity of synthetic Na-saponites. The role of layer charge. Clay Minerals, 37, 39-57.
17. Ohtaki, H. and Radnai, T. (1993) Structure and dynamics of hydrated ions. Chemical Reviews, 93, 1157-1204.
18. Papin, A., Sergent, J., and Robert, J.L. (1997) Intersite OH-F distribution in a Al-rich synthetic saponite. European Journal of Mineralogy, 9, 501-508.
19. Pelletier, M., Michot, L.J., Barrès, O., Humbert, B., Petit, S., and Robert, J.-I. (1999) Influence of KBr conditioning on the infrared hydroxyl-stretching region of saponite. Clay Minerals, 34, 439-445.
20. Petit, S., Robert, J-L., Decarreau, A., Besson, G., Grauby, O., and Martin, F. (1995) Contribution of spectroscopic methods to 2:1 clay caracterization. Bulletin des centres de recherches Exploration-Production Elf Aquitaine, 19, 119-147.
21. Prost, R. (1975) Étude de l'hydratation des argiles : interactions eau-minérale et mécanisme de la rétention de l'eau. II. Étude d'une smectite (Hectorite). Annales Agronomiques, 26, 463-535.
22. Remy, J.C. and Orsini, L. (1976) Utilisation du chlorure de cobaltihexamine pour la détermination simultanée de la capacité d'échange et des bases échangeables des sols. Science du sol, 4, 269-275.
23. 2O: a single model for trioctahedral and dioctahedral micas. American Journal of Science, 288-A, 196-212.
24. Robert, J.L., Beny, J.M., Beny, C., and Volfinger M. (1989) Characterization of lepidolites by raman and infrared spectrometries. 1. Relationships between OH-streching wavenumbers and composition. Canadian Mineralogist, 27, 225-235.
25. Robert, J.L., Beny, J.M., Della Ventura, G., and Hardy, M. (1993) Fluorine in micas: crystal-chemical control of the OH-F distribution between trioctahedral and dioctahedral sites. European Journal of Mineralogy, 5, 7-18.
26. Slonimskaya, M.V., Besson, G., Dainyak, L.G., Tchoubar, C., and Drits, V.A. (1986) Interpretation of the IR spectra of celadonites and glauconites in the region of OH-stretching frequencies. Clay Minerals, 21, 377-388.
27. Stubican, V. and Roy, R. (1961) Isomorphous substitution and infrared spectra of the layer lattice silicates. American Mineralogist, 46, 32-51.
28. Suquet, H., Prost, R., and Pezerat, H. (1977) Étude par spectroscopie infrarouge de l'eau adsorbéc par la saponite-calcium. Clay Minerals, 12, 113-126.
29. Suquet, H., Prost, R., and Pezerat, H. (1982) Etude par spectroscopie Infrarouge et diffraction X des interactions eau-cation-feuillet dans les phases à 14.6, 12.2 et 10.1 Å d'une saponite-Li de synthèse. Clay Minerals, 17, 231-241.
30. Vantelon, D., Pelletier M., Michot, L.J., Barres, O., and Thomas, F. (2001) Fe, Mg and Al distribution in the octahedral layer of montmorillonites. An infrared study in the OH-bending region. Clay Minerals, 36, 369-379.
31. Vedder, W. (1964) Correlations between infrared spectrum and chemical composition of mica. American Mineralogist, 49, 736-768.
32. Velde, B. (1983) Infrared OH-stretch bands in potassic micas, tales and saponites: influence of electronic configuration and site of charge compensation. American Mineralogist, 68, 1169-1173.
33. Xu, W., Johnston, C.T., Parker, P., and Agnew, S.F. (2000) Infrared study of water sorption on Na-, Li-, Ca-, and Mg-exchanged (SWy-1 and SAz-1) montmorillonite.
34. th International Clay Conference, p. 257-260. The Clay Mineral Society. Bloomington, Indiana.
35. Yvon, J., Marion, P., Michot, L., Villieras, F., Wagner, F.E., and Friedl, J. (1991) Development of mineralogy applications in mineral processing. European Journal of Mineralogy, 3, 667-676.