New general synthetic methods involving π-allylpalladium complexes as intermediates and neutral reaction conditions

Tetrahedron

Volumn 42, Issue 16, 1986, Pages 4361-4401

  Tsuji, Jiro ^a  

^a TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0346602829     PISSN: 00404020     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4020(01)87277-X     Document Type: Article

References (127)

1. Organic Syntheses by Means of Noble Metal Compounds. Part 23. Reactions of π-Allylpalladium Chloride Complexes with Nucleophiles
2. Palladium-catalyzed Exchange of Allylic Groups of Ethers and Esters with Active Hydrogen Compounds. II.
3. Catalytic reactions via π-allylpalladium complexes
4. Transition metal templates for selectivity in organic synthesis
5. Bimetallic catalytic systems containing Ti, Zr, Ni, and Pd. Their applications to selective organic syntheses
6. Palladium in some selective oxidation reactions
7. The Allyloxycarbonyl (Aloc) Moiety?Conversion of an Unsuitable into a Valuable Amino Protecting Group for Peptide Synthesis
8. The cinnamyloxycarbonyl group as a new amino-protecting group.
9. Pd(O) Promoted Transformation of 1,1-Dialkoxycarbonyl-2-(1,3-butadienyl)cyclopropanes into 2-Ethenyl-3-cyclopentenes
10. Direct .ALPHA.-allylation of ketones with O-allylisourea catalyzed by palladium(0).
11. Ketone enolates as nucleophiles in palladium-catalysed allylic alkylation
12. Palladium-catalyzed allylation of ketones and aldehydes with allylic carbonates via silyl enol ethers under neutral conditions.
13. 1-Alkenylation on .ALPHA.-position of ketone: Palladium-catalyzed reaction of tin enolates and 1-bromo-1-alkenes.
14. 236. Addition of ??-unsaturated alcohols to the active methylene group. Part II. The action of ethyl acetoacetate on cinnamyl alcohol and phenylvinylcarbinol
15. 89. Addition of ??-unsaturated alcohols to the active methylene group. Part III. Scope and mechanism of the reaction
16. Synthesis of .GAMMA.,.DELTA.-unsaturated ketones by the intramolecular decarboxylative allylation of allyl .BETA.-keto carboxylates and alkenyl allyl carbonates catalyzed by molybdenum, nickel, and rhodium complexes.
17. Synthesis of digitoxigenin from 3?-acetoxyandrost-5-en-17-one involving palladium induced rearrangement of an allylic epoxide
18. Transfer of asymmetry by the palladium-catalyzed alkylation of chiral allylic sulfinates.
19. Asymmetric catalytic allylic alkylation
20. Stereocontrolled trans and cis nucleophilic attack by acetate on .pi.-allylpalladium complexes. Applications to stereoselective palladium-catalyzed 1,4-diacetoxylation of cyclic 1,3-dienes
21. Complete retention of chirality in the palladium catalyzed cyclization of methyl (R)-3-oxo-7-(methoxycarbonyloxy)-8-nonenoate.
22. Triphenylphosphanpalladium-katalysierte Abspaltung von Allylgruppen mit Ameisensäure
23. A convenient method for the preparation of 1-olefins by the palladium catalyzed hydrogenolysis of allylic acetates and allylic phenyl ethers with ammonium formate
24. Regioselective synthesis of 1-olefins by palladium-catalyzed hydrogenolysis of terminal allylic compounds with ammonium formate.
25. Enone formation from allyl .BETA.-keto esters, alkenyl allyl carbonates, silyl enol ethers, and enol acetates by the phosphine-free palladium catalyst.
26. Novel Synthetic Method for 2-Methyl-2-cyclopentenone from Diallyl Adipate by Two-Pot Reactions
27. 2-Methyl-2-cyclopenten-1-one from 2-Methylcyclopentane-1,3-dione
28. 315. The carbonylation of allylic chlorides