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note
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3+-reduced samples to air, which causes a complete loss of the Ni(I) signal in the L-edge spectrum, also resulted in increased intensity in the region near 853.0 eV. as well as in the high energy shoulder region around 854.4 eV, apparently due to generation of a more ionic high-spin Ni(II) form. However, air oxidation is an unlikely explanation for these samples, which display substantial quantities of Ni-(I). Since the high-spin Ni(II) component in these samples exhibited slightly shifted centroids and slightly different splitting, a change in magnetic behavior might have resulted as well.
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