Stereoselectivity and chemoselectivity in Ziegler-Natta polymerization of conjugated dienes. 2. Mechanism for 1,2 syndiotactic polymerization of diene monomers with high energy s-cis η4 coordination

Polymer

Volumn 45, Issue 2, 2004, Pages 467-485

  Costabile, Chiara ^a   Milano, Giuseppe ^a   Cavallo, Luigi ^a   Longo, Pasquale ^a   Guerra, Gaetano ^a   Zambelli, Adolfo ^a  

^a UNIVERSITY OF SALERNO   (Italy)

Author keywords

Ziegler Natta diene polymerizations

Indexed keywords

ETHYLENE; MONOMERS; POLYMERIZATION; PROBABILITY DENSITY FUNCTION; STEREOCHEMISTRY;

CHEMOSELECTIVITY; STEREOSELECTIVITY;

ORGANIC POLYMERS;

1,3 BUTADIENE; 4 METHYLPENTADIENE; ALKADIENE; MONOMER; PENTADIENE; UNCLASSIFIED DRUG;

ANALYTIC METHOD; ARTICLE; CHEMICAL ANALYSIS; CHEMOSELECTIVITY; CHIRALITY; CONJUGATION; DENSITY FUNCTIONAL THEORY; ENERGY; POLYMERIZATION; REACTION ANALYSIS; STEREOCHEMISTRY; ZIEGLER NATTA POLYMERIZATION;

POLYMERIZATION;

EID: 0346492932     PISSN: 00323861     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.polymer.2003.10.084     Document Type: Article

References (59)

1. Porri L, Natta G, Gallazzi MC. Chim Ind (Milan) 1964;46:428-9.
2. Natta G, Porri L, Carbonaro A, Greco A. Makromol Chem 1964;71:207-11.
3. Wilke G, Bogdanovich B, Hardt P, Heimbach P, Keim W, Kromer M, Oberkirch W, Tanaka K, Steinrucke E, Walter D, Zimmermann H. Angew Chem Int Ed Engl 1966;5:151-64.
4. Marconi W. In: Ketley AD, editor. The stereochemistry of macromolecules, vol. 1. New York: Dekker; 1967. p. 239.
5. Natta G, Porri L. Polymer chemistry of synthetic elastomers. In: Kennedy JP, Tornquist E, editors. Wiley-Interscience; 1969. p. 597. Part II.
6. Teyssie P, Dawans F. In: Saltman WM, editor. The stereo rubbers. New York: Wiley; 1977. p. 79.
7. Porri L. In: Ciardelli F, Giusti P, editors. Structural order in polymers. Oxford, UK: Pergamon Press; 1981. p. 51.
8. Porri L, Giarrusso A. In: Eastmond GC, Ledwith A, Russo S, Sigwalt P, editors. Comprehensive polymer science, 4. Oxford, UK: Pergamon Press; 1989. p. 53. Part II.
9. Porri L, Giarrusso A, Ricci G. Prog Polym Sci 1991;16:405-41.
10. Taube R, Windisch H, Maiwald S. Macromol Symp 1995;89:393-409.
11. Costabile C, Milano G, Cavallo L, Guerra G. Macromolecules 2001;23:7952-60.
12. Guerra G, Cavallo L, Corradini P, Fusco R. Macromolecules 1997;30:677-84.
13. Erker G, Berg K, Krüger C, Müller G, Angermund K, Benn R, Schroth G. Angew Chem Int Ed Engl 1984;96:445-6.
14. Longo P, Oliva P, Proto A, Zambelli A. Gazz Chim Ital 1996;126:377-82.
15. Oliva L, Longo P, Grassi A, Ammendola P, Pellecchia C. Makromol Chem Rapid Commun 1990;11:519-24.
16. Ricci G, Porri L, Giarrusso A. Macromol Symp 1995;89:383-92.
17. Ricci G, Italia S, Porri L. Macromolecules 1994;27:868-9.
18. Longo P, Proto A, Zambelli A. Macromol Chem Phys 1995;196:3015-29.
19. Longo P, Guerra G, Grisi F, Pizzuti S, Zambelli A. Macromol Chem Phys 1998;199:149-54.
20. Longo P, Proto A, Oliva P, Zambelli A. Macromolecules 1996;29:5500-1.
21. Longo P, Grisi F, Proto A. Macromol Rapid Commun 1997;18:183-90.
22. Natta G, Giannini U, Pino P, Cassata A. Chim Ind (Milan) 1965;47:524-5.
23. Taube R, Wache S, Sieler J. J Organomet Chem 1993;459:335-47.
24. Ciajolo R, Jama MA, Tuzi A, Vitagliano A. J Organomet Chem 1985;295:233-8.
25. Allegra G, Lo Giudice F, Natta G, Giannini U, Fagherazzi G, Pino P. Chem Commun 1967;24:1263-5.
26. Hanson KR. J Am Chem Soc 1966;88:2731-42.
27. Corradini P, Guerra G, Jama MA, Zhi G, Tuzi A. Polym Commun 1985;26:175-8.
28. Baerends EJ, Ellis DE, Ros P. Chem Phys 1973;2:41-51.
29. Baerends EJ, Ros P. Chem Phys 1973;2:52-9.
30. Vosko SH, Wilk L, Nusair M. Can J Phys 1980;58:1200-11.
31. Becke AD. Phys Rev B 1986;34:7406.
32. Perdew JP. Phys Rev 1988;38:3098.
33. (a) Lohrenz JCW, Woo TK, Ziegler T. J Am Chem Soc 1995;117:12793-800.
34. (b) Deng L, Woo TK, Cavallo L, Margl PM, Ziegler T. J Am Chem Soc 1997;119:6177-86.
35. (c) Cavallo L, Guerra G, Corradini P. J Am Chem Soc 1998;120:2428-36.
36. (d) Margl PM, Deng L, Ziegler T. J Am Chem Soc 1998;120:5517-25.
37. (e) Guerra G, Longo P, Corradini P, Cavallo L. J Am Chem Soc 1999;121:8651-2.
38. (f) Milano G, Guerra G, Pellecchia C, Cavallo L. Organometallics 2000;19:1343-9.
39. (g) Longo P, Grisi F, Guerra G, Cavallo L. Macromolecules 2000;33:4647-59.
40. (a) Minieri G, Corradini P, Zambelli A, Guerra G, Cavallo L. Macromolecules 2001;34:2459-68.
41. (b) Minieri G, Corradini P, Zambelli A, Guerra G, Cavallo L. Macromolecules 2001;34:5379-85.
42. Tobisch S, Bögel H, Taube R. Organometallics 1996;15:3563-71.
43. Tobisch S, Bogel H, Taube R. Organometallics 1998;17:1177-96.
44. Tobisch S, Taube R. Organometallics 1999;18:5204-18.
45. (a) Tobisch S, Taube R. Organometallics 1999;18:3045-60.
46. (b) Tobisch S. Acc Chem Res 2002;96-104.
47. Jensen VR, Borve KJ. J Comput Chem 1991;19:94.
48. Rix FC, Brookhart M, White PS. J Am Chem Soc 1996;118:4746-64.
49. (a) Margl PM, Deng L, Ziegler T. Organometallics 1998;17:933-46.
50. (b) Musaev DG, Froese RDJ, Svensson M, Morokuma K. J Am Chem Soc 1997;119:367-74.
51. Zambelli A, Tosi C. Fortschritte der Hochpolymeren-Forschung 1974:15:31-60.
52. Guerra G, Cavallo L, Moscardi G, Vacatello M, Corradini P. J Am Chem Soc 1994;116:2988-95.
53. Cavallo L, Guerra G, Vacatello M, Corradini P. Macromolecules 1991;24:1784-90.
54. Corradini P, Cavallo L, Guerra G. In: Scheirs J, Kaminsky W, editors. Metallocene based polyolefins, properties and technology, vol. 2. Chichester: Wiley; 2000. p. 3.
55. (a) Venditto V, Guerra G, Corradini P, Fusco R. Polymer 1990;31:530-7.
56. (b) Milano G, Fiorello G, Guerra G, Cavallo L. Macromol Chem Phys 2002;203:1564-72.
57. (a) Zambelli A, Tosi C. Adv Polym Sci 1974;31.
58. (b) Resconi L, Abis L, Franciscono G. Macromolecules 1992;25:6814-7.
59. (c) Erker G, Fritze C. Angew Chem Int Ed Engl 1992;31:199-202.