Novel Reversible Ionic-to-Covalent Transition in a Highly Conducting TTF Derivative

Journal of the American Chemical Society

Volumn 125, Issue 52, 2003, Pages 16206-16207

  Shen, Clifton Kwang Fu ^a   Duong, Hieu M ^a   Sonmez, Gursel ^a   Wudl, Fred ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

TETRATHIAFULVALENE DERIVATIVE;

ARTICLE; CHEMICAL ANALYSIS; CHEMICAL MODIFICATION; CHEMICAL STRUCTURE; CONDUCTANCE; COVALENT BOND; MOLECULAR DYNAMICS;

EID: 0346434115     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja037621n     Document Type: Article

References (14)

1. (a) Collet, E.; Lemée-Cailleau M.-H.; Cointe M. B.-L.; Cailleau H.; Wulff, M.; Luty, T.; Koshihara, S.-Y.; Meyer, M.; Toupet, L.; Rabiller, P.; Techert, S. Science 2003, 300, 612.
2. (b) Cointe, M. L.; Lemée-Cailleau, M. H.; Cailleau, H.; Toudic B. ; Toupet, L.; Heger, G.; Moussa, F.; Schweiss, P.; Kraft, K. H.; Karl, N. Phys. Rev. B 1995, 51(6), 3374.
3. (c) Horiuchi, S.; Kumai, R. J. Am. Chem. Soc. 1998, 120, 7379.
4. (d) Aoki, S.; Nakayama, T.; Miura, A. Synth. Met. 1995, 70, 1243.
5. (a) Sawyer, D. T.; Sobkowiak, A.; Roberts, J. L., Jr. Electrochemistry for Chemists; Wiley: New York, 1995; Chapter 12.
6. (b) Lomprey, J. R.; Guarr, T. F.; Baumann, K. L. U.S. Patent 6,433, 914, 2002.
7. 2: 1.029 (f) R indices (all data): R1 = 0.0268, wR2 = 0.058.
8. Wudl, F.; Smith, G. M.; Hufnagel, E. J. J. Chem. Soc., Chem. Commun. 1970, 1453.
9. (a) Wudl, F.; Wobschall, D.; Hunfnagel, E. J. J. Am. Chem. Soc. 1972, 94, 670.
10. (b) Torrance, J. B.; Mayerle, J. J.; Lee, V. Y.; Bechgaard, K. J. Am. Chem. Soc. 1979, 101, 4748.
11. (c) Mitani, T.; Kaneko, Y.; Tanuma, S.; Tokura, Y.; Koda, T.; Saito, G. Phys. Rev. B 1987, 35(1), 427.
12. All g values of ESR spectra reported here have been calibrated by DPPH (diphenylpicrihydrazyl).
13. There appears to be a hint of antiferromagnetic ordering between 300 and 230 K which will be examined by SQUID magnetometry.
14. See Figure 3 in Supporting Information.