Liquid-liquid extraction of isovaleric acid using alamine 308/diluent and conventional solvent systems: Effect of diluent and acid structure

Solvent Extraction and Ion Exchange

Volumn 21, Issue 6, 2003, Pages 853-879

  Senol, Aynur ^a  

^a ISTANBUL UNIVERSITY   (Turkey)

Author keywords

Alamine 308; Isovaleric acid; Liquid liquid extraction equilibria; Modeling

Indexed keywords

AMINES; EXTRACTION; ORGANIC SOLVENTS; PHASE EQUILIBRIA; WATER;

COMPLEX SOLVATION;

ORGANIC ACIDS;

AMINE; CHLOROFORM; LIQUID-LIQUID EQUILIBRIUM; LIQUID-LIQUID SEPARATION; MATHEMATICAL MODELING; SOLVENT EXTRACTION;

EID: 0346256535     PISSN: 07366299     EISSN: None     Source Type: Journal    
DOI: 10.1081/SEI-120025929     Document Type: Article

References (21)

1. Kertes, A.S.; King, C.J. Extraction chemistry of fermentation product carboxylic acids. J. Biotechnol. Bioeng. 1986, 28, 269-282.
2. Tamada, J.A.; Kertes, A.S.; King, C.J. Extraction of carboxylic acids with amine extractants. I. Equilibria and law of mass action modeling. Ind. Eng. Chem. Res. 1990, 29, 1319-1326.
3. Tamada, J.A.; King, C.J. Extraction of carboxylic acids with amine extractants. 2. Chemical interaction and interpretation of data. Ind. Eng. Chem. Res. 1990, 29, 1327-1333.
4. Yang, S.T.; White, S.A.; Hsu, S.T. Extraction of carboxylic acids with tertiary and quaternary amines. Effect of pH. Ind. Eng. Chem. Res. 1991, 30, 1335-1342.
5. Bizek, V.; Horácek, J.; Koušovovǎ, M. Amine extraction of citric acid. effect of diluent. Chem. Eng. Sci. 1993, 48, 1447-1457.
6. Poposka, F.A.; Nikolovski, K.; Tomovska, R. Equilibrium and mathematical models of extraction of citric acid with isodecanol/n-paraffins solutions of trioctylamine. J. Chem. Eng. Jpn 1997, 30, 777-785.
7. Heyberger, A.; Procházka, J.; Volaufova, E. Extraction of citric acid with tertiary amines-third phase formation. Chem. Eng. Sci. 1998, 53, 515-521.
8. Malmary, G.; Faizal, M.; Albet, J.; Molinier, J. Liquid-liquid equilibria of acetic, formic, and oxalic acids between water and tributyl phosphate + dodecane. J. Chem. Eng. Data. 1997, 42, 985-987.
9. Reinsel, M.A.; Borkowski, J.J.; Sears, J.T. Partition coefficients for acetic, propionic, and butyric acids in a crude oil/water system. J. Chem. Eng. Data. 1994, 39, 513-516.
10. Senol, A. Extraction equilibria of formic, levulinic and acetic acids using (alamine 336/diluent) and conventional solvent systems. Modeling considerations. J. Chem. Eng. Jpn 1999, 32, 717-731.
11. Kirsch, T.; Maurer, G. Distribution of oxalic acid between water and organic solutions of tri-n-octylamine. Ind. Eng. Chem. Res. 1996, 35, 1722-1735.
12. Kamlet, M.J.; Doherty, R.M.; Abraham, M.H.; Marcus, Y.; Taft, R.W. Linear solvation energy relationships. 46. An improved equation for correlation and prediction of octanol/water partition coefficients of organic nonelectrolytes (including strong hydrogen bond donor solutes). J. Phys. Chem. 1988, 92, 5244-5255.
13. Marcus, Y. Linear solvation energy relationships. Correlation and prediction of the distribution of organic solutes between water and immiscible organic solvents. J. Phys. Chem. 1991, 95, 8886-8891.
14. Gmehling, J.; Li, J.; Schiller, M. A. Modified UNIFAC model 2. Present parameter matrix and results for different thermodynamic properties. Ind. Eng. Chem. Res. 1993, 32, 178-193.
15. Bauer, U.; Marr, R.; Ruckl, W.; Siebenhofer, M. Reactive extraction of citric acid from aqueous fermentation broth. Ber. Bunsen-Ges. Phys. Chem. 1989, 93, 980-984.
16. Riddick, J.A.; Bunger, W.B.; Sakano, T.K. Organic Solvents. Physical Properties and Methods of Purification, 4th Ed.; Wiley-Interscience: New York, 1986.
17. Himmelblau, D.M. Basic Principles and Calculations in Chemical Engineering, 5th Ed.; Prentice-Hall, Inc.: N.J., 1989.
18. Senol, A. Vapor-liquid equilibria of the systems ethyl ethanoate/2- methyl-2-butanol, 2-methyl-1-propanol/3-methyl-1-butanol, and cyclohexanol/benzyl alcohol at 101.32 kPa. J. Chem. Eng. Data. 1998, 43, 763-769.
19. Barton, A.F.M. Solubility parameters. Chem. Rev. 1975, 75, 731-753.
20. Taylor, R.; Kooijman, H. Composition derivatives of activity coefficient models (for the estimation of thermodynamic factors in diffusion). Chem. Eng. Comm. 1991, 102, 87-106.
21. Mori, H.; Oda, A.; Ito, C.; Aragaki, T.; Liu, F.Z. Thermodynamic factors derived from group contribution activity coefficient models. J. Chem. Eng. Jpn. 1996, 29, 396-398.