Small cage d10 metallacarboranes: Crystal structure of the mercury bridged carborane, μ,μ′-[2-(Si(CH3) 3)-3-(CH3)-2,3-C2B4H 5]2Hg

Inorganic Chemistry Communications

Volumn 7, Issue 1, 2004, Pages 111-113

  Yang, Jimin ^a   Zheng, Chong ^b   Maguire, John A ^a   Hosmane, Narayan S ^b  

^a SOUTHERN METHODIST UNIVERSITY   (United States)

^b NORTHERN ILLINOIS UNIVERSITY   (United States)

Author keywords

Bridged complex; Crystal structure; d10 Carborane; Mercuracarborane; Metallacarborane; Nido carborane cage

Indexed keywords

CARBORANE DERIVATIVE; MERCURY;

ARTICLE; CHEMICAL REACTION; CRYSTAL STRUCTURE; STRUCTURE ANALYSIS; X RAY DIFFRACTION;

EID: 0346100328     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2003.10.013     Document Type: Article

References (17)

1. V.I. Bregadze, V.Ts. Kampel, N.N. Godovikov, J. Organomet. Chem. 112 (1976) 249.
2. (a) V.I. Bregadze, V.Ts. Kampel, A.Ya. Usiatinskii, N.N. Godovikov, J. Organomet. Chem. 154 (1978) Cl;
3. (b) V.I. Bregadze, V.Ts. Kampel, N.N. Godovikov, J. Organomet. Chem. 157 (1978) Cl;
4. (c) G.Z. Suleimanov, V.I. Bregadze, N.A. Koval'chuk, I.P. Beletskaya, J. Organomet. Chem. 235 (1982) C17.
5. T.J. Wedge, M.F. Hawthorne, Coord. Che. Rev. 240 (2003) 111.
6. H. Lee, D. Martin, M.F. Hawthorne, Tetrahedron Lett. 40 (1999) 7651.
7. (a) H.W. Colquhoun, T.J. Greenhough, M.G.H. Wallbridge, Chem. Commun. (1977) 737;
8. (b) H.W. Colquhoun, T.J. Greenhough, M.G.H. Wallbridge, J. Chem. Soc. Dalton (1979) 737.
9. (a) K.F. Shaw, B.D. Reid, A.J. Welch, J. Organomet. Chem. 482 (1994) 207;
10. (b) F. Teixidor, J.A. Ayllón, C. Viñas, R. Kivekäs, Sillanpää, J. Organomet. Chem. 483 (1994) 153.
11. N.S. Hosmane, R.N. Grimes, Inorg. Chem. 18 (1979) 2886.
12. D.C. Finster, R.N. Grimes, Inorg. Chem. 20 (1981) 863.
13. N.S. Hosmane, J.A. Maguire, in: G.A. Olah, K. Wade, R.E. Williams (Eds.), Electronic Deficient Boron and Carbon Clusters, Wiley, New York, 1991, Chapter. 9, p. 215.
14. N.S. Hosmane, A.K. Saxena, R.D. Barreto, H. Zhang, J.A. Maguire, L. Jia, Y. Wang, A.R. Oki, K.V. Grover, S.J. Whitten, K. Dawson, M.A. Tolle, U. Siriwardane, T. Demissie, J.S. Fagner, Organometallics 12 (1993) 3001.
15. 2) δ 6.0 (br, basal 3BH), -43.5 (br apical BH).
16. 2, = 0.1659, and GOF = 1.085.
17. 2, = 0.1659, and GOF = 1.085.