Conformational Studies by Dynamic NMR. 97.1 Structure, Conformation, Stereodynamics and Enantioseparation of Aryl Substituted Norbornanes

Journal of Organic Chemistry

Volumn 69, Issue 2, 2004, Pages 345-351

  Casarini, Daniele ^a   Grilli, Stefano ^b   Lunazzi, Lodovico ^b   Mazzanti, Andrea ^b  

^a UNIVERSITY OF BASILICATA   (Italy)

^b UNIVERSITY OF BOLOGNA   (Italy)

Author keywords

[No Author keywords available]

Indexed keywords

CONFORMATIONS; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY; MOLECULAR STRUCTURE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; STEREOCHEMISTRY; X RAY DIFFRACTION ANALYSIS;

MOLECULAR MECHANICS;

BORON COMPOUNDS;

NORBORNANE DERIVATIVE;

ARTICLE; CALCULATION; CARBON NUCLEAR MAGNETIC RESONANCE; CHEMICAL STRUCTURE; CIRCULAR DICHROISM; CONFORMATION; ENANTIOSELECTIVITY; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY; MOLECULAR MECHANICS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; SEPARATION TECHNIQUE; STEREOCHEMISTRY; STRUCTURE ANALYSIS; TEMPERATURE DEPENDENCE; X RAY DIFFRACTION;

EID: 0345871941     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo035411n     Document Type: Article

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32. -1.
33. -1, for the phenyl-C7, p-anisyl-C7, and phenyl-C1 rotation, respectively). These observations thus support the existence of a correlated motion.
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47. -1 value for the interconversion barrier.
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53. 1c.8
54. 2 solution at about -17 °C.
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