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The direct iodination of azulene-1-azoarenes failed and only a complex with iodine was obtained. Therefore, the iodinated compounds were obtained by the reaction with ICl or by the substitution of HgCl group with iodine, see A. C. Razus, L. Birzan, S. A. Razus, and V. Horga, Rev. Roum. Chim., 44, 235 (1999) and L. Birzan, Ph. D. Dissertation, Bucharest, 2000.
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Ph. D. Dissertation, Bucharest
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The direct iodination of azulene-1-azoarenes failed and only a complex with iodine was obtained. Therefore, the iodinated compounds were obtained by the reaction with ICl or by the substitution of HgCl group with iodine, see A. C. Razus, L. Birzan, S. A. Razus, and V. Horga, Rev. Roum. Chim., 44, 235 (1999) and L. Birzan, Ph. D. Dissertation, Bucharest, 2000.
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note
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At the dilution of the acidic solution a green color appears proving the probable formation of the 5-nitroso derivatives in a reversible amino nitrosation. The green spot observed by thin layer chromatography of the reaction mixture indicated also the generation of a little amount of nitroso derivative which polymerizes at solvent vaporization.
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