Generating zintl anions: Homoatomic polyanions of group 15 elements by oxidative coupling of smaller anions or direct reduction of the elements in liquid ammonia

Phosphorus, Sulfur and Silicon and Related Elements

Volumn 124, Issue , 1997, Pages 339-346

  Korber, Nikolaus ^a  

^a UNIVERSITY OF BONN   (Germany)

Author keywords

Expanded metals; Homoatomic polyanions; Zintl ions

Indexed keywords

EID: 0345812211     PISSN: 10426507     EISSN: None     Source Type: Journal    
DOI: 10.1080/10426509708545639     Document Type: Article

References (24)

1. H.-G. von Schnering, W. Hönle, Chem. Rev., 1988, 243.
2. J. D. Corbett, Chem. Rev., 1985, 383.
3. a) E. Zintl, J. Goubeau, W. Dullenkopf, Z. phys. Chem. Abt. A , 154, 1 (1931);
4. b) E. Zintl, W. Dullenkopf, Z. phys. Chem. Abt. B , 16, 183 (1932).
5. a) M. Baudler, K. Glinka, Chem. Rev., 1993, 1623;
6. b) M. Baudler, K. Glinka, Chem. Rev., 1994, 1273;
7. G. Fritz, K. D. Hoppe, W. Hönle, D. Weber, C. Mujica, V. Manriquez, H.G. von Schnering, J. Organomet. Chem., 249, 63 (1983);
8. C. Mucija, D. Weber, H.G. von Schnering, Z. Naturforsch., 41b, 991 (1986).
9. a) G. Fritz, H. W. Schneider, W. Hönle, H. G. von Schnering, Z. anorg. allg. Chem., 584, 21 (1990);
10. b) S. Charles, B. W. Eichhorn, S. G. Bott, J. Am. Chem. Soc., 115, 5837 (1993);
11. S. Charles, J. C. Fettinger, B. W. Eichhorn, J. Am. Chem. Soc., 117, 5303 (1995);
12. B.W. Eichhorn, R.C. Haushalter, J.C. Huffman, Angew. Chem., 101, 1081 (1989).
13. a) N. Korber, H.-G. von Schnering, Chem. Ber., 129, 155 (1996);
14. b) N. Korber, J. Daniels, J. Chem. Soc. Dalton Trans. 1996, 1653;
15. N. Korber, J. Daniels, Polyhedron, 15, 2681 (1996);
16. N. Korber, J. Daniels, Acta Crystallogr. C, 52, 2454 (1996).
17. [7) a) N. Korber, H.-G. von Schnering, J. Chem. Soc. Chem. Commun., 1995, 1713;
18. b) N. Korber, J. Daniels, H.-G. von Schnering, Angew. Chem., 108, 1186 (1996); ibid. Int. Ed., 35, 1107.
19. b) N. Korber, J. Daniels, H.-G. von Schnering, Angew. Chem., 108, 1186 (1996); ibid. Int. Ed., 35, 1107.
20. N. Korber, J. Daniels, Z. anorg. allg. Chem., 622, 1833 (1996).
21. N. Korber, F. Richter, Chem. Commun., 1996, 2023.
22. R. C. Haushalter, B. W. Eichhorn, A. L. Rheingold, S. J. Geib, J. Chem. Soc., Chem. Commun., 1988, 1027.
23. V. G. Young and W. S. Glaunsinger, J. Am. Chem. Soc., 111, 9260 (1989).
24. N. Korber, F. Richter, Angew. Chem., in the press.