-
1
-
-
0009633602
-
-
Luchinat, C.; Steuernagel, S.; Turano, P. Inorg. Chem. 1990, 29, 4351.
-
(1990)
Inorg. Chem.
, vol.29
, pp. 4351
-
-
Luchinat, C.1
Steuernagel, S.2
Turano, P.3
-
3
-
-
0025025643
-
-
Crans, D. C.; Rithner, C. D.; Thiesen, L. A. J. Am. Chem. Soc. 1990, 112, 2901.
-
(1990)
J. Am. Chem. Soc.
, vol.112
, pp. 2901
-
-
Crans, D.C.1
Rithner, C.D.2
Thiesen, L.A.3
-
6
-
-
0028672868
-
-
James, T. L., Oppenheimer, N. J., Eds.; Academic Press: New York
-
Banci, L.; Bertini, I.; Luchinat, C. In Methods in Enzymology; James, T. L., Oppenheimer, N. J., Eds.; Academic Press: New York, 1994; vol 239, pp. 485-514.
-
(1994)
Methods in Enzymology
, vol.239
, pp. 485-514
-
-
Banci, L.1
Bertini, I.2
Luchinat, C.3
-
8
-
-
0001215890
-
-
Bertini, I.; Turano, P.; Vila, A. Chem. Revs. 1993, 93, 2833.
-
(1993)
Chem. Revs.
, vol.93
, pp. 2833
-
-
Bertini, I.1
Turano, P.2
Vila, A.3
-
10
-
-
0346530294
-
-
Actually, A/gβ (in gauss or mT) for EPR and A/h (in MHz) for NMR spectra
-
Actually, A/gβ (in gauss or mT) for EPR and A/h (in MHz) for NMR spectra.
-
-
-
-
11
-
-
0009002918
-
-
Beringer, R.; Heald, M. A. Phys. Rev. 1954, 95, 1474. Kusch, P. Phys. Rev. 1955, 100, 1188.
-
(1954)
Phys. Rev.
, vol.95
, pp. 1474
-
-
Beringer, R.1
Heald, M.A.2
-
12
-
-
0007352613
-
-
Beringer, R.; Heald, M. A. Phys. Rev. 1954, 95, 1474. Kusch, P. Phys. Rev. 1955, 100, 1188.
-
(1955)
Phys. Rev.
, vol.100
, pp. 1188
-
-
Kusch, P.1
-
13
-
-
0345899382
-
-
note
-
Note thai this "fast chemical exchange" of the electron spin on the NMR time scale is the opposite of the "slow chemical exchange" of the electron spin on the EPR time scale that gives rise to the two hyperfine lines discussed in the preceding paragraph and shown in Figure 2. In spite of the difference in time scales between EPR and NMR spectroscpy, this "fast" vs. "slow" electron spin relaxation rate is responsible for the rule of thumb that if you see the EPR spectrum of the complex at room temperature, you will not see the NMR spectrum of the same complex at room temperature. However, rules of thumb are meant to be broken, or at least bent, as is the case with certain monomeric, tetrahedral Cu(II) complexes.
-
-
-
-
14
-
-
0347790754
-
-
note
-
Downfield or upfield in the jargon that has developed over the years.
-
-
-
-
15
-
-
0009380833
-
-
La Mar, G. N.; Horrocks, W. D.; Holm, R. H., Eds.; Academic Press: New York
-
Jesson, J. P. In NMR of Paramagnetic Molecules; La Mar, G. N.; Horrocks, W. D.; Holm, R. H., Eds.; Academic Press: New York, 1973; pp. 1-53.
-
(1973)
NMR of Paramagnetic Molecules
, pp. 1-53
-
-
Jesson, J.P.1
-
17
-
-
0002159556
-
-
Dolphin, D., Ed.; Academic Press: New York
-
La Mar, G. N.; Walker, F. A. In The Porphyrins; Dolphin, D., Ed.; Academic Press: New York, 1979; Vol. IV; pp. 57-61.
-
(1979)
The Porphyrins
, vol.4
, pp. 57-61
-
-
La Mar, G.N.1
Walker, F.A.2
-
21
-
-
0347790752
-
-
Manuscript in preparation
-
Banci, L.; Bertini, I.; Luchinat, C.; Pierattelli, R.; Walker, F. A. Manuscript in preparation.
-
-
-
Banci, L.1
Bertini, I.2
Luchinat, C.3
Pierattelli, R.4
Walker, F.A.5
-
23
-
-
0001933508
-
-
La Mar, G. N.; Eaton, G. R.; Holm, R. H.; Walker, F. A. J. Am. Chem. Soc. 1973, 95, 63.
-
(1973)
J. Am. Chem. Soc.
, vol.95
, pp. 63
-
-
La Mar, G.N.1
Eaton, G.R.2
Holm, R.H.3
Walker, F.A.4
-
24
-
-
0001091347
-
-
Pawlik, M. J.; Miller, P. K.; Sullivan, E. P.; Levstik, M. A.; Almond, D. A.; Strauss, S. H. J. Am. Chem. Soc. 1988, 110, 3007.
-
(1988)
J. Am. Chem. Soc.
, vol.110
, pp. 3007
-
-
Pawlik, M.J.1
Miller, P.K.2
Sullivan, E.P.3
Levstik, M.A.4
Almond, D.A.5
Strauss, S.H.6
-
28
-
-
85088238087
-
-
note
-
yy (25), if necessary.
-
-
-
-
30
-
-
0347160664
-
-
Reference 20 and references therein
-
Reference 20 and references therein.
-
-
-
-
32
-
-
0345899379
-
-
Reference 32, pp. 549-552
-
Reference 32, pp. 549-552.
-
-
-
-
34
-
-
0002494112
-
-
Ed. 2; Drago, R. S., Ed.; Saunders: Mexico, Chapter 12
-
Bertini, I.; Luchinat, C. In Physical Methods for Chemists, Ed. 2; Drago, R. S., Ed.; Saunders: Mexico, 1992; Chapter 12.
-
(1992)
Physical Methods for Chemists
-
-
Bertini, I.1
Luchinat, C.2
-
35
-
-
0345899378
-
-
Reference 32, p. 519
-
Reference 32, p. 519.
-
-
-
-
36
-
-
0346530289
-
-
Reference 32, p. 527
-
Reference 32, p. 527.
-
-
-
-
37
-
-
0029993350
-
-
Kalverda, A.; Salgado, J.; Dennison, C.; Canters, G. W. Biochemistry 1996, 35, 3085.
-
(1996)
Biochemistry
, vol.35
, pp. 3085
-
-
Kalverda, A.1
Salgado, J.2
Dennison, C.3
Canters, G.W.4
-
38
-
-
0001653866
-
-
Peters, J. A.; Huskens, J.; Raber, D. J. Progr. NMR Spectrosc. 1996, 28, 283-350.
-
(1996)
Progr. NMR Spectrosc.
, vol.28
, pp. 283-350
-
-
Peters, J.A.1
Huskens, J.2
Raber, D.J.3
-
40
-
-
0347160661
-
-
note
-
The protons that have been detected near the Cu(U) center of amicyanin are those that have a hyperfine coupling constant less than 4.2 MHz and are at a distance of >4 Å from the copper. (35)
-
-
-
-
43
-
-
0346530288
-
Applications of Nuclear Magnetic Resonance to Paramagnetic Species
-
Dekker: New York
-
Sigel, H.; Sigel, A., Eds. Metal Ions in Biological Systems; Dekker: New York, 1989; Vol. 21, "Applications of Nuclear Magnetic Resonance to Paramagnetic Species."
-
(1989)
Metal Ions in Biological Systems
, vol.21
-
-
Sigel, H.1
Sigel, A.2
-
45
-
-
0347790749
-
-
Reference 40, p. 22
-
Reference 40, p. 22.
-
-
-
-
49
-
-
0000784948
-
-
Basu, P.; Shokhirev, N. V.; Enemark, J. H.; Walker, F. A. J. Am. Chem. Soc. 1995, 117, 9042.
-
(1995)
J. Am. Chem. Soc.
, vol.117
, pp. 9042
-
-
Basu, P.1
Shokhirev, N.V.2
Enemark, J.H.3
Walker, F.A.4
-
50
-
-
85088243916
-
-
note
-
g, etc. (42)
-
-
-
-
51
-
-
0001650818
-
-
Brink, J. M.; Rose, R. A.; Holz, R. C. Inorg. Chem. 1996, 55, 2878.
-
(1996)
Inorg. Chem.
, vol.55
, pp. 2878
-
-
Brink, J.M.1
Rose, R.A.2
Holz, R.C.3
-
52
-
-
0030892780
-
-
Murthy, N. N.; Karlin, K. D.; Bertini, I.; Luchinat, C. J. Am. Chem. Soc. 1997, 119, 2156.
-
(1997)
J. Am. Chem. Soc.
, vol.119
, pp. 2156
-
-
Murthy, N.N.1
Karlin, K.D.2
Bertini, I.3
Luchinat, C.4
-
53
-
-
0025320199
-
-
Dugad, L. B.; La Mar, G. N.; Unger, S. W. J. Am. Chem. Soc. 1990, 112, 1386.
-
(1990)
J. Am. Chem. Soc.
, vol.112
, pp. 1386
-
-
Dugad, L.B.1
La Mar, G.N.2
Unger, S.W.3
-
54
-
-
0000070293
-
Magnetochemistry - Advances in Theory and Experimentation
-
Lippard, S. J., Ed.; Wiley-Interscience: New York
-
O'Connor, C. J. "Magnetochemistry - Advances in Theory and Experimentation;" In Progress in Inorganic Chemistry; Lippard, S. J., Ed.; Wiley-Interscience: New York, 1982; Vol. 29, pp. 203-283.
-
(1982)
Progress in Inorganic Chemistry
, vol.29
, pp. 203-283
-
-
O'Connor, C.J.1
-
56
-
-
0345899375
-
-
Available upon E-mail request to nikolai@u.arizona.edu
-
Available upon E-mail request to nikolai@u.arizona.edu.
-
-
-
-
57
-
-
0000626708
-
-
Tan, H.; Simonis, U.; Shokhirev, N. V.; Walker, F. A. J. Am. Chem. Soc. 1994, 116, 5784.
-
(1994)
J. Am. Chem. Soc.
, vol.116
, pp. 5784
-
-
Tan, H.1
Simonis, U.2
Shokhirev, N.V.3
Walker, F.A.4
-
58
-
-
0003338279
-
-
Isaac, M. F.; Lin, Q.; Simonis, U.; Suffian, D. J.; Wilson, D. L.; Walker, F. A. Inorg. Chem. 1993, 32, 4030.
-
(1993)
Inorg. Chem.
, vol.32
, pp. 4030
-
-
Isaac, M.F.1
Lin, Q.2
Simonis, U.3
Suffian, D.J.4
Wilson, D.L.5
Walker, F.A.6
-
59
-
-
0347160657
-
-
note
-
In the case of solvent molecules that remain in the crystals, it is often necessary to pump on the sample extensively on a high vacuum line, and also to evaporate the sample from the deuterated solvent to be used, or preferably both.
-
-
-
-
60
-
-
0347160659
-
-
Reference 4, p. 38
-
Reference 4, p. 38.
-
-
-
-
61
-
-
85088251685
-
-
note
-
1. (59)
-
-
-
-
65
-
-
0345899374
-
-
Reference 59, p. 37
-
Reference 59, p. 37.
-
-
-
-
67
-
-
0001750480
-
-
Unger, S. W.; LeComte, J. T. J.; La Mar, G. N. J. Magn. Reson 1985, 64, 521.
-
(1985)
J. Magn. Reson
, vol.64
, pp. 521
-
-
Unger, S.W.1
LeComte, J.T.J.2
La Mar, G.N.3
-
68
-
-
0007618487
-
-
Yu, C.; Unger, S. W.; La Mar, G. N. J. Magn. Reson. 1986, 67, 346.
-
(1986)
J. Magn. Reson.
, vol.67
, pp. 346
-
-
Yu, C.1
Unger, S.W.2
La Mar, G.N.3
-
73
-
-
0011491177
-
-
Bothner-By, A. A.; Stephens, R. L.; Lee, J.; Warren, C. D.; Jeanloz, R. W. J. Am. Chem. Soc. 1984, 106, 811.
-
(1984)
J. Am. Chem. Soc.
, vol.106
, pp. 811
-
-
Bothner-By, A.A.1
Stephens, R.L.2
Lee, J.3
Warren, C.D.4
Jeanloz, R.W.5
-
74
-
-
0039965711
-
-
Summers, M. P.; Marzilli, L. G.; Bax, A. J. Am. Chem. Soc. 1986, 108, 4285.
-
(1986)
J. Am. Chem. Soc.
, vol.108
, pp. 4285
-
-
Summers, M.P.1
Marzilli, L.G.2
Bax, A.3
-
76
-
-
0345899369
-
-
Unpublished data
-
Ogura, H. Unpublished data.
-
-
-
Ogura, H.1
-
77
-
-
0001565088
-
-
Shokhirev, N. V.; Shokhireva, T. Kh.; Polam, J. R.; Watson, C. T.; Raffii, K.; Simonis, U.; Walker, F. A. J. Phys. Chem. A 1997, 101, 2778.
-
(1997)
J. Phys. Chem. A
, vol.101
, pp. 2778
-
-
Shokhirev, N.V.1
Shokhireva, T.Kh.2
Polam, J.R.3
Watson, C.T.4
Raffii, K.5
Simonis, U.6
Walker, F.A.7
-
78
-
-
0001137433
-
-
Walker, F. A.; Simonis, U. J. Am. Chem. Soc. 1991, 113, 8652; 1992, 114, 1929.
-
(1991)
J. Am. Chem. Soc.
, vol.113
, pp. 8652
-
-
Walker, F.A.1
Simonis, U.2
-
79
-
-
0347538306
-
-
Walker, F. A.; Simonis, U. J. Am. Chem. Soc. 1991, 113, 8652; 1992, 114, 1929.
-
(1992)
J. Am. Chem. Soc.
, vol.114
, pp. 1929
-
-
-
80
-
-
0027962802
-
-
Chen, Z.; de Ropp, J. S.; Hernandez, G.; La Mar, G. N. J. Am. Chem. Soc. 1994, 116, 8772.
-
(1994)
J. Am. Chem. Soc.
, vol.116
, pp. 8772
-
-
Chen, Z.1
De Ropp, J.S.2
Hernandez, G.3
La Mar, G.N.4
-
84
-
-
0000050826
-
-
Keating, K. A.; de Ropp, J. S.; La Mar, G. N.; Balch, A. L.; Shiau, F.-Y.; Smith, K. M. Inorg. Chem. 1991, 30, 3258.
-
(1991)
Inorg. Chem.
, vol.30
, pp. 3258
-
-
Keating, K.A.1
De Ropp, J.S.2
La Mar, G.N.3
Balch, A.L.4
Shiau, F.-Y.5
Smith, K.M.6
-
85
-
-
0039054173
-
-
Holz, R. C.; Evdokimov, G. A.; Gobena, F. T. Inorg. Chem. 1996, 35, 3808.
-
(1996)
Inorg. Chem.
, vol.35
, pp. 3808
-
-
Holz, R.C.1
Evdokimov, G.A.2
Gobena, F.T.3
-
86
-
-
0030892780
-
-
Murthy, N. N.; Karlin, K. D.; Bertini, I.; Luchinat, C. J. Am. Chem. Soc. 1997, 119, 2156.
-
(1997)
J. Am. Chem. Soc.
, vol.119
, pp. 2156
-
-
Murthy, N.N.1
Karlin, K.D.2
Bertini, I.3
Luchinat, C.4
-
88
-
-
0000759407
-
-
Bertini, I.; Luchinat, C.; Tarchi, D. Chem. Phys. Lett. 1993, 203, 445.
-
(1993)
Chem. Phys. Lett.
, vol.203
, pp. 445
-
-
Bertini, I.1
Luchinat, C.2
Tarchi, D.3
-
89
-
-
0000709283
-
-
Qin, J.; Delaglio, F.; La Mar, G. N.; Bax, A. J. Magn. Reson., Series B 1993, 102, 332.
-
(1993)
J. Magn. Reson., Series B
, vol.102
, pp. 332
-
-
Qin, J.1
Delaglio, F.2
La Mar, G.N.3
Bax, A.4
-
91
-
-
0345899362
-
-
Reference 66, Figure 6.21, p. 335
-
Reference 66, Figure 6.21, p. 335.
-
-
-
-
93
-
-
0001681462
-
-
Bertini, I.; Coutsolelos, A.; Dikiy, A.; Luchinat, C.; Spyroulias, G. A.; Troganis, A. Inorg. Chem. 1996, 35, 6308.
-
(1996)
Inorg. Chem.
, vol.35
, pp. 6308
-
-
Bertini, I.1
Coutsolelos, A.2
Dikiy, A.3
Luchinat, C.4
Spyroulias, G.A.5
Troganis, A.6
-
94
-
-
0030929706
-
-
Lehmann, T. E.; Ming, L.-J.; Rosen, M. E.; Que, L., Jr. Biochemistry 1997, 36, 2807.
-
(1997)
Biochemistry
, vol.36
, pp. 2807
-
-
Lehmann, T.E.1
Ming, L.-J.2
Rosen, M.E.3
Que L., Jr.4
-
96
-
-
0347160652
-
-
Personal communication
-
Simonis, U. Personal communication.
-
-
-
Simonis, U.1
-
101
-
-
0001178589
-
-
Kruppa, A. I.; Taraban, M. B.; Leshina, T. V.; Natarajan, E.; Grissom, C. B. Inorg. Chem. 1997, 36, 758.
-
(1997)
Inorg. Chem.
, vol.36
, pp. 758
-
-
Kruppa, A.I.1
Taraban, M.B.2
Leshina, T.V.3
Natarajan, E.4
Grissom, C.B.5
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