Effects of an Electron-Withdrawing Group on Thermal Decomposition of 4-Alkylidene-1-pyrazolines: A Novel Stereoselective Formation of Alkylidenecyclopropane Due to Participation of π-Electrons on the Methylene Carbon in Decomposition

Journal of Organic Chemistry

Volumn 68, Issue 25, 2003, Pages 9711-9722

  Hamaguchi, Masashi ^a   Nakaishi, Masahiro ^a   Nagai, Toshikazu ^a   Tamura, Hatsue ^a  

^a OSAKA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL BONDS; CONFORMATIONS; CRYSTAL STRUCTURE; ELECTRONS; PYROLYSIS; THERMAL EFFECTS;

PLANAR RING STRUCTURE;

NITROGEN COMPOUNDS;

ALKANE; ALKENE; ALKYL GROUP; AZO COMPOUND; CARBENE; CARBON; CARBOXYLIC ACID DERIVATIVE; CYCLOPROPANE DERIVATIVE; DIAZONIUM COMPOUND; NITROGEN; PYRAZOLINE DERIVATIVE;

ARTICLE; CHEMICAL STRUCTURE; CONFORMATION; CRYSTAL STRUCTURE; CYCLOADDITION; DECOMPOSITION; DISSOCIATION; ELECTRON; ISOMER; LOW TEMPERATURE; POLARIZATION; REACTION ANALYSIS; STEREOCHEMISTRY; STRUCTURE ANALYSIS; X RAY CRYSTALLOGRAPHY;

EID: 0345529027     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo035321i     Document Type: Article

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