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Volumn 76, Issue 11, 2003, Pages 2075-2089

Photochemical Transformations of Quintet m-Phenylenedinitrenes

Author keywords

[No Author keywords available]

Indexed keywords

ADDITION REACTIONS; CHEMICAL BONDS; FOURIER TRANSFORM INFRARED SPECTROSCOPY; PHASE TRANSITIONS; PHOTOCHEMICAL REACTIONS; REACTION KINETICS;

EID: 0345528023     PISSN: 00092673     EISSN: None     Source Type: Journal    
DOI: 10.1246/bcsj.76.2075     Document Type: Article
Times cited : (48)

References (50)
  • 2
    • 0004056023 scopus 로고    scopus 로고
    • ed by K. Itoh and M. Kinoshita, Kodansha-Godon and Breach, Tokyo
    • b) "Molecular Magnetism: New Magnetic Materials," ed by K. Itoh and M. Kinoshita, Kodansha-Godon and Breach, Tokyo (2000).
    • (2000) Molecular Magnetism: New Magnetic Materials
  • 36
    • 0344456937 scopus 로고    scopus 로고
    • note
    • For 5a and 6a, the data for only one isomer was shown in Table for simplicity. Although other isomers might be formed, at this stage of the reaction, the spectra are consisting of a mixture of many products and hence it is practically impossible to assign all the absorptions.
  • 37
    • 0344025801 scopus 로고
    • ed by D. Klopmann, Georg Thieme Verlag, Stuttgart
    • J. Backes, "Methoden der Organischen Chemie, Houben-Weyl," ed by D. Klopmann, Georg Thieme Verlag, Stuttgart (1992), Bd. E16C, S. 366-369.
    • (1992) Methoden der Organischen Chemie, Houben-Weyl , vol.E16C , pp. 366-369
    • Backes, J.1
  • 38
    • 0344456938 scopus 로고    scopus 로고
    • note
    • For products formed as a result of ring opening reaction, e.g., 9 to 13, all possible isomers were calculated, but only isomers whose theoretical IR bands match best the experimental IR bands are recorded in Table.
  • 39
    • 0344025805 scopus 로고    scopus 로고
    • note
    • For 2c, due to the presence of two methyl groups at orthoposition with respect to azide groups, the azide groups are forced to come out of the plane of phenyl ring. Therefore, there are too many conformers to calculate. Similarly, 3c has many possible conformers but here in order to roughly estimate the ratio of 3c to 4c upon irradiation of 2c, two isomers, E- and Z-3c where methyl groups are fixed are calculated and reported in Table.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.