Growth-step-selective incorporation of boron on the calcite surface

Geochimica et Cosmochimica Acta

Volumn 62, Issue 17, 1998, Pages 2915-2922

  Hemming, N Gary ^a   Reeder, Richard J ^b   Hart, Stanley R ^c  

^a Department of Earth and Environmental Sciences   (United States)

^b STONY BROOK UNIVERSITY   (United States)

^c WOODS HOLE OCEANOGRAPHIC INSTITUTION   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ADSORPTION; BORON; CALCITE; SURFACE LAYER;

EID: 0345279913     PISSN: 00167037     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0016-7037(98)00214-2     Document Type: Article

References (35)

1. + in calcites and aragonites. Geochim. Cosmochim. Acta. 49:1985;713-725.
2. Dromgoole E.L., Walter L.M. Iron and manganese incorporation into calcite Effects of growth kinetics, temperature and solution chemistry . Chem. Geol. 81:1990;311-336.
3. Gaillardet J., Allègre C.J. Boron isotopic composition of corals Seawater or diagenesis record? Earth Planet. Sci. Lett. 136:1995;665-676.
4. Goldberg S., Forster H.S. Boron sorption on calcareous soils and reference calcites. Soil Sci. 152:1991;304-310.
5. Gratz A.J., Hillner P.E., Hansma P.K. Step dynamics and spiral growth on calcite. Geochim. Cosmochim. Acta. 57:1993;491-495.
6. Gruzensky P.M. Growth of calcite crystals. Peiser H.S. Crystal Growth. 1967;365-367 Pergamon Press.
7. Hart S.R., Cohen A.L. An ion probe study of annual cycles of Sr/Ca and other trace elements in corals. Geochim. Cosmochim. Acta. 60:1996;3075-3084.
8. Hemming N.G., Hanson G.N. Boron isotopic composition and concentration in modern marine carbonates. Geochim. Cosmochim. Acta. 56:1992;537-543.
9. Hemming N.G., Reeder R.J., Hanson G.N. Mineral-fluid partitioning and isotopic fractionation of boron in synthetic calcium carbonate. Geochim. Cosmochim. Acta. 59:1995;371-379.
10. Hoffmann R. Solids and Surfaces A Chemist's View of Bonding in Extended Structures . 1988;VCH Publ.
11. 3 {10 1 4}-water interface. Surf. Sci. 373:1997;275-287.
12. Lamble G. M., Reeder R. J., and Northrup P. A. (1997) Characterization of heavy metal incorporation in calcite by XAFS spectroscopy. J. Phys. IV, 7, C2, 793-797.
13. Lorens R.B. Strontium, cadmium, manganese, and cobalt distribution in calcite as a function of calcite precipitation rate. Geochim. Cosmochim. Acta. 45:1981;553-561.
14. MacInnis I.N., Brantley S.L. The role of dislocations and surface morphology in calcite dissolution. Geochim. Cosmochim. Acta. 56:1992;1113-1126.
15. Morse J.W., Bender M.L. Partition coefficients in calcite Examination of factors influencing the validity of experimental results and their application to natural systems . Chem. Geol. 82:1990;265-277.
16. Mucci A., Morse J.W. Chemistry of low-temperature abiotic calcites Experimental studies on coprecipitation, stability and fractionation . Aquat. Sci. 3:1990;217-254.
17. Paquette J., Reeder R.J. New type of compositional zoning in calcites Insights into crystal-growth mechanisms . Geology. 18:1990;1244-1247.
18. Paquette J., Reeder R.J. Relationship between surface structure, growth mechanism, and trace element incorporation in calcite. Geochim. Cosmochim. Acta. 59:1995;735-749.
19. Pingitore N.E. Jr, Meitzner G., Love K.M. Identification of sulfate in natural carbonates by X-ray absorption spectroscopy. Geochim. Cosmochim. Acta. 59:1995;2477-2483.
20. Rakovan J., Reeder R.J. Intracrystalline rare earth element distributions in apatite Surface structural influences on incorporation during growth . Geochim. Cosmochim. Acta. 60:1996;4435-4445.
21. Reeder R.J. Interaction of divalent cobalt, zinc, cadmium, and barium with the calcite surface during layer growth. Geochim. Cosmochim. Acta. 60:1996;1543-1552.
22. Reeder R. J. and Rakovan J. (1998) Surface structural controls on trace element incorporation during growth. In Growth, Dissolution and Pattern-formation in Geosystems (ed. B. Jamtveit and P. Meakin) Kluwer. (in press).
23. 2- substitution in calcite An XAFS study . Geochim. Cosmochim. Acta. 58:1994;5639-5646.
24. 2+ in calcite. Amer. Mineral (submitted).
25. Sanyal A., Hemming N.G., Hanson G.N., Broecker W.S. Evidence for a higher pH in the glacial ocean from boron isotopes in foraminifera. Nature. 373:1995;234-236.
26. Sanyal A., Hemming N.G., Broecker W.S., Lea D.W., Spero H.J., Hanson G.N. Oceanic pH control on the boron isotopic composition of foraminifera Evidence from culture experiments . Paleoceanography. 11:1996;513-517.
27. Sanyal A., Hemming N.G., Broecker W.S. Changes in pH in the eastern equatorial Pacific across stage 5-6 boundary based on boron isotopes in foraminifera. Global Bio-Geochem. Cycles. 11:1997;125-133.
28. 11B MAS NMR study . Amer. Mineral. 79:1994;818-825.
29. Spivack A.J., You C.-F., Smith H.J. Foraminiferal boron isotope ratios as a proxy for surface ocean pH over the past 21 Myr. Nature. 363:1993;149-151.
30. 2- in synthetic calcite single crystals. Geochim. Cosmochim. Acta. 58:1994;2087-2098.
31. Stipp S.L., Eggleston C.M., Nielsen B.S. Calcite surface structure observed at microtopographic and molecular scales with atomic force microscopy (AFM). Geochim. Cosmochim. Acta. 58:1994;3023-3033.
32. Su C., Suarez D.L. Coordination of adsorbed boron A FTIR spectroscopic study . Environ. Sci. Tech. 29:1995;302-311.
33. Su C., Suarez D.L. Boron sorption and release by allophane. Soil Sci. Soc. Amer. J. 61:1997;69-77.
34. Sunagawa I. Surface microtopography of crystal faces. Sunagawa I. Morphology of Crystals, Part A. 1987;321-365 Terra Scientific.
35. Vengosh A., Kolodny Y., Starinsky A., Chivas A.R., McColloch M.T. Coprecipitation and isotopic fractionation of boron in modern biogenic carbonates. Geochim. Cosmochim. Acta. 55:1991;2901-2910.