Transmetalation as a Route to Novel Styryllithium Reagents

Organic Letters

Volumn 5, Issue 19, 2003, Pages 3443-3445

  Rim, Chinwon ^a   Son, David Y ^a  

^a SOUTHERN METHODIST UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALKANE DERIVATIVE; CHLOROTRIMETHYLSILANE; DIMETHYL SULFATE; LITHIUM DERIVATIVE; METHYL IODIDE; REAGENT; STYRYLLITHIUM; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL BOND; CHEMICAL REACTION; TRANSMETALATION;

EID: 0345255683     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol035193k     Document Type: Article

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12. It should be noted that the existence of the discrete di-and trilithium reagents in solution was not proven (the reactions could in theory proceed in a stepwise fashion, for example), but at the very least these reagents are functional equivalents of the corresponding lithium compounds. We thank a reviewer for pointing this out.
13. Farina, V.; Krishnamurthy, V.; Scott, W. J. The Stille Reaction; Wiley: New York, 1998.
14. Negishi, E. I.; Liu, F. In Metal-Catalyzed Cross-Coupling Reactions; Diederich, F., Stang, P., Eds.; Wiley: New York, 1998; p 1.