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Volumn 68, Issue 24, 2003, Pages 9453-9455

Radical Azidonation of Aldehydes

Author keywords

[No Author keywords available]

Indexed keywords

RADICAL MECHANISM;

EID: 0345254934     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo035163v     Document Type: Article
Times cited : (89)

References (17)
  • 1
    • 0034641322 scopus 로고    scopus 로고
    • Recently Renaud's group has reported an elegant method for radical substitution with azide by adding alkyl radicals to ethanesulfonyl azide, see: (a) Ollivier, C.; Renaud, P. J. Am. Chem. Soc. 2000, 122, 6496-6497.
    • (2000) J. Am. Chem. Soc. , vol.122 , pp. 6496-6497
    • Ollivier, C.1    Renaud, P.2
  • 3
    • 0000988928 scopus 로고
    • Reactions that use PhIO/TMSN3 to introduce azide α to amines and enol ethers may involve radicals, see: Magnus, P.; Lacour, J.; Weber, W. J. Am. Chem. Soc. 1993, 115, 9347-9348.
    • (1993) J. Am. Chem. Soc. , vol.115 , pp. 9347-9348
    • Magnus, P.1    Lacour, J.2    Weber, W.3
  • 11
    • 0345622198 scopus 로고    scopus 로고
    • note
    • Solid iodine azide is explosive and should never be allowed to form. We always generate the reagent in solution and destroy the reagent with thiosulfate wash before workup. When adhering to this we have not encountered any problems even on prolonged reflux.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.