Trace element diffusion and element partitioning between garnet and andesite melt using synchrotron X-ray fluorescence microanalysis (μ-SRXRF)

European Journal of Mineralogy

Volumn 15, Issue 5, 2003, Pages 883-892

  Koepke, Jürgen ^a   Falkenberg, Gerald ^b   Rickers, Karen ^b,c   Diedrich, Otto ^a  

^a LEIBNIZ UNIVERSITY HANNOVER   (Germany)

^b DESY   (Germany)

^c GFZ GERMAN RESEARCH CENTRE FOR GEOSCIENCES   (Germany)

Author keywords

Element partitioning; Garnet; In situ method; Synchrotron X ray fluorescence analysis; Trace element diffusion

Indexed keywords

DIFFUSION; FLUORESCENCE; GARNETS; IMAGE RESOLUTION; MICROANALYSIS; PHOSPHATE MINERALS; SYNCHROTRON RADIATION; SYNCHROTRONS; X RAYS;

DISTRIBUTION COEFFICIENT; ELEMENT DIFFUSION; ELEMENT PARTITIONING; IN-SITU METHODS; PISTON-CYLINDER APPARATUS; SYNCHROTRON RADIATION X-RAY FLUORESCENCE; SYNCHROTRON X-RAY FLUORESCENCES; TRACE ELEMENT PARTITIONING;

TRACE ELEMENTS;

ANDESITE; CRYSTAL CHEMISTRY; EXPERIMENTAL MINERALOGY; GARNET; GEOCHEMISTRY; PARTITIONING; SILICATE MELT; TRACE ELEMENT; X-RAY FLUORESCENCE;

EID: 0345099285     PISSN: 09351221     EISSN: None     Source Type: Journal    
DOI: 10.1127/0935-1221/2003/0015-0883     Document Type: Article

References (41)

1. Baker, D.R. (1990): Chemical interdiffusion of dacite and rhyolite: Anhydrous measurements at 1 atm and 10 kbar, application of transition state theory, and diffusion in zoned magma chambers. Contrib. Mineral. Petrol., 104, 407-423.
2. Bessette, D. (1999) Analyse und Quantifizierung geologischer Proben mit der Synchrotron-Röntgenfluoreszenz. PhD Thesis, University of Hamburg, 94 p.
3. Brearley, A. J., Bajt, S., Sutton, S. (1995): Distribution of moderately volatile trace elements in fine-grained chondrule rims in the unequilibrated CO3 Chondrite, ALH A 77307. Geochim. Cosmochim. Acta, 59, 4307-4316.
4. Bühn, B. & Rankin, A.H. (1999): Composition of natural, volatile-rich Na-Ca-REE-Sr carbonatitic fluids trapped in fluid inclusions. Geochim. Cosmochim. Acta, 63, 3781-3797.
5. Frantz, J., Mao, H., Zhang, Y., Wu, Y., Thompson, A. (1988): Analysis of fluid inclusions by X-ray fluorescence using synchrotron radiation. Chemical Geol., 69, 235-244.
6. Green, T.H., Sie, S.H., Ryan, C.G., Cousens, D.R. (1989): Proton microprobe-determined partitioning of Nb, Ta, Zr, Sr and Y between garnet, clinopyroxene and basaltic magma at high pressure and temperature. Chemical Geol., 74, 201-216.
7. Haller, M. & Knöchel, A. (1996): X-ray fluorescence analysis using synchrotron radiation (SYXRF). J. Trace Microprobe Techniques, 14, 461-488.
8. Haller, M., Knöchel, A., Radtke, M. (1995): New glass capillary optics for the SYXRF microprobe. Hasylab Annual Report, 2, 993-994.
9. Hansteen, T.H., Sachs, P.M., Lechtenberg, F. (2000): Synchrotron-XRF microprobe analysis of silicate reference standards using fundamental-parameter quantification. Eur. J. Mineral., 12, 25-31.
10. Janssens, K., Adams, F., Rindby, A. (2000): "Microscopic X-ray fluorescence analysis". Wiley, Chichester, 419 p.
11. Jenner, G.A., Foley, S.F., Jackson, S.E., Green, T.H., Fryer, B.J., Longerich, H.P. (1994): Determination of partitioning coefficients for trace elements in high pressure-temperature experimental run products by laser ablation microprobe-inductively coupled plasma-mass spectrometry (LAM-ICP-MS). Geochim. Cosmochim. Acta, 58, 5099-5103.
12. Jochum, K.P., Hofmann, A.W., Bessette, D., Stoll, B., Graup, G. (1998): SR-XRF microprobe trace element study on melt inclusions from Hawaiian basalts. Hasylab Annual Report, 2, 965-966.
13. Johannes, W. & Holtz, F. (1996): "Petrogenesis and experimental petrology of granitic rocks". Springer, Berlin, Heidelberg, 335 p.
14. Johannes, W. & Koepke, J. (2001): Uncomplete reaction of plagio-clase in experimental dehydration melting of amphibolite. Austral. J. Earth Sci., 48, 581-590.
15. Klein, M. (1995): Experimentelle Bestimmung von Kristall/ Schmelze-Verteilungskoeffizienten ausgewählter Spurenelemente für Klinopyroxen, Granate und Amphibole. PhD Thesis, University of Cologne, 182 p.
16. Klöck, W., Flynn, G.J., Sutton, S.R. (1994): Heating experiments simulating atmospheric entry of micrometeorites. Lunar Planet. Sci., XXV, 713-714.
17. Koepke, J. & Behrens, H. (2001): Trace element diffusion in andesitic melts: An application of synchrotron X-ray fluorescence analysis. Geochim. Cosmochim. Acta, 65, 1481-1498.
18. Koepke, J., Rocholl, A., Jantos, N. (1998): Trace element microanalysis of hydrous silicate melts: The influence of water on SIMS and synchrotron-XRF analysis. Terra Nova, Abstr. Suppl. 1, 10, 31.
19. Lowenstern, J.B., Mahood, G.A., Rivers, M.L., Sutton, S.R. (1991): Evidence for extreme partitioning of copper into a magmatic vapor phase. Science, 252, 1405-1409.
20. Mavrogenes, J.A., Bodnar, R.J., Anderson, A.J., Bait, S., Sutton, S. R., Rivers, M.L. (1995): Assessment of the uncertainties of quantitative elemental analysis of individual fluid inclusions using synchrotron X-ray fluorescence (SXRF). Geochim. Cosmochim. Acta, 59, 3987-3995.
21. Ménez, B., Philippot, P., Bonnin-Mosbah, M., Simionovici, A., Gilbert, F. (2002): Analysis of individual fluid inclusions using synchrotron X-ray fluorescence microprobe: progress towards calibration for trace elements. Geochim. Cosmochim. Acta, 66, 561-576.
22. Mungall, J.E., Dingwell, D.B., Chaussidon, M. (1999): Chemical diffusivities of 18 trace elements in granitoid melts. Geochim. Cosmochim. Acta, 63, 2599-2610.
23. Nakamura, E. & Kushiro, I. (1998): Trace element diffusion in jadeite and diopside melts at high pressures and its geochemical implication. Geochim. Cosmochim. Acta, 62, 3151-3160.
24. Nicholls, I.A. & Harris, K.L. (1980): Experimental rare earth element partitioning coefficients for garnet, clinopyroxene and amphibole coexisting with andesitic and basaltic liquids. Geochim. Cosmochim. Acta, 44, 287-308.
25. Philippot, P., Ménez, B., Drakopoulos, M., Simionovici, A., Snigirev, A., Snigireva, I. (2001): Mapping trace metal (Cu, Zn, As) distribution in a single fluid inclusion using third generation synchrotron light source. Chemical Geol., 173, 151-158.
26. Rankin, A.H., Ramsey, M.H., Coles, B., Van Langevelde, F., Thomas, C.R. (1992): The composition of hypersaline, iron-rich granitic fluids based on laser ICP and synchrotron-XRF microprobe analysis of individual fluid inclusions in topaz, Mole Granit, Eastern Australia. Geochim. Cosmochim. Acta, 56, 67-79.
27. Rickers, K., Thomas, R., Heinrich, W. (2001): Element distribution in immiscible pegmatite melts and coexisting fluids determined by synchrotron radiation XRF. Ber. Dt. Mineralog. Ges., Beih. z. Eur. J. Mineral., 13, No. 1, 54.
28. Rocholl, A., Jantos, N., Koepke, J. (1997): The influence of water on secondary ion yields in SIMS analysis. Terra Nova, Abstr. Suppl. 1, 9, 452.
29. Rocholl, A., Koepke, J., Wiedenbeck, M. (2001): Systematic errors in SIMS analysis of hydrous phases: the role of water. Ber. Dt. Mineralog. Ges., Beih. z. Eur. J. Mineral.,, 13, No. 1, 155.
30. Smith, J.V. & Rivers, M.L. (1995): Synchrotron X-ray microanalysis. in "Microprobe techniques in the Earth sciences", P. J. Potts, J. F. W. Bowles, S. J. B. Reed, M. R. Cave, eds. Chapman & Hall, London, 163-233.
31. Somogyi, M., Drakopoulos, M., Vincze, L., Vekemans, B., Camerani, C., Janssens, K., Snigirev, A., Adams, F. (2001): ID18F: a new micro-x-ray fluorescence end-station at the European Synchrotron Radiation Facility (ESRF): preliminary results. X-Ray Spectrom., 30, 242-252.
32. Sutton, S.R., Bertsch, P.M., Newville, M., Rivers, M., Lanzirotti, A., Eng, P. (2002): Microfluorescence and microtomography analyses of heterogeneous earth and environmental materials. in "Applications of synchrotron radiation in low-temperature geochemistry and environmental science", P. Fenter, M. Rivers, N. Sturchio, S.R. Sutton, eds. Reviews in Mineralogy and Geochemistry, 49, Mineral. Soc. Am., Washington, DC, United States, 429-483.
33. Tegge-Schüring, A., Koepke, J., Johannes, W. (1998): Synthetische Monazite als SEE-Quelle in Schmelzexperimenten zur Bestimmung von Verteilungskoeffizienten. Terra Nostra, 98/3, 184-185.
34. Tegge-Schüring, A., Koepke, J., Behrens, H., Hahn, M., Falkenberg, G., Wiedenbeck, M. (2001): Measurements of trace element diffusivities: comparison between SYXRF and SIMS. Ber. Dt. Mineralog. Ges., Beih. z. Eur. J. Mineral., 13, No. 1, 185.
35. Török, S., Sindor, C., Xhoffer, C. (1994): X-ray microprobe studies of Hungarian background and urban aerosols. Adv. X-ray Anal., 35, 67-75.
36. Van Espen, P.J., Nullens, H., Adams, F. (1977): A computer analysis of X-ray fluorescence spectra. Nucl. Instr. Meth., 142, 269-273.
37. Vanko, D.A., Sutton, S.R., Rivers, M.L., Bodnar, R.J. (1993): Major-element ratios in synthetic fluid inclusions by synchrotron X-ray fluorescence microprobe. Chemical Geol., 109, 125-134.
38. Vanko, D.A., Bonnin-Mosbah, M., Philippot, P., Roedder, E., Sutton, S.R. (2001): Fluid inclusions in quartz from oceanic hydrothermal specimens and the Bingham, Utha porphyry-Cu deposit: a study with PIXE and SXRF. Chemical Geol., 173, 227-238.
39. Vincze, L., Janssens, K., Adams, F. (1993): A general Monte Carlo simulation of energy dispersive X-Ray fluorescence spectrometers - Part I. Spectrochim. Acta, 48B, 553-573.
40. Vincze, L., Janssens, K., Adams, F. (1995): A general Monte Carlo simulation of energy dispersive X-Ray fluorescence spectrometers - Part II. Polarized radiation of homogeneous samples. Spectrochim. Acta, 50B, 127-135.
41. Wiedenbeck, M., Rocholl, A., Koepke, J. (2001): Water - a source of systematic error in quantitative SIMS analyses of hydrous glasses. Abstract 3604, LPI Contribution No. 1088, Lunar and Planetary Science Institute, Houston.