The solubility of calcite in seawater solution of different magnesium concentrations at 25°C and 1 atm total pressure: a laboratory re-examination

Mer

Volumn 36, Issue 1, 1998, Pages 9-22

  Rushdi, Ahmed I ^a,d   Chen, Chen Tung Arthur ^b   Suess, Erwin ^c  

^a OREGON STATE UNIVERSITY   (United States)

^b NATIONAL SUN YAT SEN UNIVERSITY   (Taiwan)

^c GEOMAR HELMHOLTZ CENTRE FOR OCEAN RESEARCH KIEL   (Germany)

^d SANA A UNIVERSITY   (Yemen)

Author keywords

[No Author keywords available]

Indexed keywords

CALCITE; MAGNESIUM; SEAWATER; SOLUBILITY;

EID: 0345020383     PISSN: 05031540     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article

References (64)

1. ANDERSON, L.G. and D. DYRSSEN (1987): Formation of chemogenic calcite in superanoxic seawater-Framvaren Southern Norway. Mar. Chem. 20, 361 -376.
2. ANDERSON, D.H. and R.J. ROBINSON (1946): Rapid electrometric determination of alkalinity of seawater. Industrial and Engineering Chemistry. 18, 767-769.
3. BATHURST, R.G.C. (1964): The replacement of aragonite by calcite in molluscan shell wall. In Approaches to Paleoecology. IMBRIE , J. and N.D. NEWELL (Eds), John Wiley and Sons., New York, p357-367.
4. BATHURST, R.G. (1974): Carbonate sediments and their diagnosis. Development in Sedimentolgy 12. 2nd Ed. Elsevier Publishing Company N.Y. 658pp.
5. BERNER, R.A. (1966): Chemical diagenesis of some modern carbonate sediments. Am. J. Sci., 264, 1 -30.
6. BERNER , R.A. (1975): The role of magnesium in crystal growth of calcite and aragonite from seawater. Geochim. Cosmochim. Acta., 39, 489 -504.
7. BERNER, R.A. (1978): Equilibrium, kinetics and the precipitation of magnesian calcite from seawater. Am. J. Sci., 278, 1435-1477.
8. BLAEDEL, W.J. and V.W. MELOCHE (1957): Elementary quantitative analysis: Theory and practice. Evanston Illinois, Row Peterson.
9. BUSENBERG, E. and L.N. PLUMMER(1989): Thermodynamics of magnesian calcite solid-solutions at 25°C and 1 atm total pressure. Geochim. Cosmochim. Acta, 53, 1189-1208.
10. CHAVE, K.E. (1952): A solid solution between calcite and dolomite. J. Geol., 60, 190-192.
11. CHAVE, K.E. (1954a): Aspect of the biochemistry of magnesium. Calcareous and marine organism. J. Geol., 62, 266-283.
12. CHAVE, K.E.(1954b): Aspect of the biochemistry of magnesium. Calcareous sediments and rocks. J. Geol., 62, 587-599.
13. CHAVE, K.E. (1982): Summary of background information on Mg-calcite. In Some aspects of the role of the shallow ocean in global carbon dioxide uptake, GARRELS, R. M. and F.T. MACKENZIE (Eds), U.S.D.O.E. Conf. 8003115, Nat'l Tech Inform. Service Springfield Virginia. pA4-A9.
14. CHAVE, K.E., K.S. DEFFEYS, P.K. WEYL, R.M. GARRELS and M.E. THOMSON (1962): Obervations on the solubility of skeletal carbonate in aqueous solutions. Science, 137, 33-34.
15. CLOUD, P.E. (1962): Behavior of calcium carbonate in seawater. Geochim. Cosmochim. Acta, 26, 876-887.
16. CULBERSON, C., R.M. PYTKOWICZ and J.E. HAWLEY (1970): Seawater alkalinity determination by pH method. J. Mar. Res., 28, 15-21.
17. DYRSSEN, D. and L.G. SILLEN (1967): Alkalinity and total carbonate in seawater. A plea for p-T independent data. Tellus, 19, 113-121.
18. GARRELS, R.M. and C.L. CHRIST (1965): Solution, minerals and equilibrium. Harper and Row, New York.
19. GRAN , G. (1952): Determination of equivalence point in potentiometric titration part II. Analyst, 77, 661-671.
20. HALL, A. and J. KENNY (1967): Aragonite of fossils. Proc. Roy Soc, Ser. B, 168, 377-412.
21. INGLE, S.E., C.H. CULBERSON, J.E. HAWLEY and R.M. PYTKOWICZ (1973): The solubility of calcite in seawater at atomospheric pressure and 35 ‰ salinity. Mar. Chem., 1, 295-307.
22. JACKSON, T.A. and J.L. BISCHOFF (1971): The influence of amino acids on kinetics of crystallization of aragonite to calcite. J. Geol., 79, 493-497.
23. JOHNSON, K.S. (1979): Ph. D. Thesis, Oregon State University, Corvallis.
24. 2+ in aqueous solutions at 25°C. Am. J. Sci., 278, 1428-1447.
25. KESTER , D.R., J.W. DUEDALL, D.N. CONNERS and R.M. PYTKOWICZ (1967): Preparation of artificial seawater. Limnol. Oceanogr., 12, 176-179.
26. KITANO , Y., K. PARK and E.W. HOOD (1962): Pure aragonite synthesis. J. Geophys. Res., 67, 4873.
27. KOCH , B. and A. DISTECHE (1984): Pressure effect on magnesian calcite coating calcite and synthesis magnesian calcite seed added to seawater in a closed system. Geochim. Cosmochim. Acta., 48, 583-589.
28. KONIGSBERGER, E. and H. GAMSJAGER (1990): Solid-solution phase equilibria in aqueous solution III. A new application of an old chemical potentiometer. Mar. Chem., 30, 317-327.
29. KRAUSKOPF, K. (1967): Introduction to geochemistry. McGraw-Hill. New York. 721pp.
30. LAND, L.S.(1967): Diagenesis of skeletal carbonate. J. Sed. Petrology, 37, 914-930.
31. 3 in Labrador Sea. J. Fish. Res. Bd. Canada, 21, 1475-1480.
32. MACKENZIE, F.T. and J.D. PIGOTT (1982): Tectonic controls of Phanerozoic sedimentary rock cycling. J. Geol. Soc. London, 138, 183-196.
33. MACKENZIE, F.T., W.D. BISCHOFF, F.C. BISCHOP, M. LOIJENS, J. SCHOONMAKER and R. WOLLAST(1982): Magnesium calcite: Low-temperature occurrence, solubility, and solid solution behavior. In Carbonate Mineralogy and Chemistry Reviews in Mineralogy 11. REEDER, R.J. (ed), P.H. Ribbe series p.97-144.
34. MEHRBACH , C., C.H. CULBERSON, J.E. HAWLEY and R.M. PYTKOWICZ(1973): Measurements of apparent dissociation constants of carbonic acid in seawater at atomospheric pressure. Limnol. Oceanogr. 18, 897-907.
35. MOLLER . P. and P.P. PAREKH (1975): Influence of magnesium on ion activity prodct of calcite and carbonate dissolved in seawater: a new approach. Mar. Chem., 3, 63-70.
36. MORES, J.W., A. MUCCI, L.M. WALTER and M.S. KAMINSKY (1979): Magnesium interaction with surface of calcite in seawater. Science, 205, 904 -905.
37. (T)=0.697m at 25°C and one atomosphere total pressure. Geochim. Cosmochim. Acta, 48, 815-822.
38. MUCCI, A., J.W. MORES and M.S. KAMINSKY (1985): Auger spectroscopy analysis of magnesium calcite overgrowths precipitated from seawater and solution of similar composition. Am. J. Sci. 285, 289-305.
39. PIGOTT, J. D. and L.S. LAND (1986): Interstitial water chemistry of Jamaica Reef sediment: Sulfate reduction and submarine cementation. Mar. Chem., 19, 355-378.
40. PLATH, D.C., K.S. JOHNSON and R.M. PYTKOWICZ (1982); The solubility of aragonite in seawater at 25 °C and 32.62‰ salinity. Mar. Chem., 10, 3-7.
41. PLUMMER, L.N. and F.T. MACKENZIE (1974): Predicting mineral solubility from rate data: Application to the dissolution of magnesian calcite. Am. J. Sci, 274, 61-83.
42. PYTKOWICZ, R.M. (1965): Rates of inorganic calcium carbonate nucleation. J. Geol., 3, 196-216.
43. PYTKOWICZ, R.M. and M. COLE (1979): Equilibrium and kinetics problems in mixed electrolyte solutions. In Thermodynamics of aqueous systems with industrial applications NEWMAN , S.A., (ed), ACS Symposium Ser. 133, 643-652.
44. PYTKOWICZ, R.M., E. ATLAS and C.H. CULBERSON (1977): Some concentrations of chemical equilibrium in the oceans. Oceanogr. Mar. Biol. Ann. Rev., 15, 11-45.
45. ROBIE, R.A. and D.R. WALBAUM (1968): Thermodynamic properties of minerals and related substances at 298.15 °K and one atomosphere. Geol. Survey Bull. Washington. 1259.
46. RUSHDI, A. (1992): Mineralogy and morphology of calcium carbonate as a function of magnesium concentration in artificial seawater. J.K.A.U. Mar. Sci., 3, 13-24.
47. RUSHDI , A. (1993): Kinetics of calcite overgrowth as a function of magnesium concentration and supersaturation in artificial seawater. J.K.A.U. Mar. Sci., 4, 39-54.
48. RUSHDI, A. and C.T.A. CHEN (1995): Variation of the apparent dissociatin constants of carbonic acids with magnesium and calcium concentrations in seawater. Terrestrial, Atomospheric and Oceanic Sciences (TAO), 6, 347-361.
49. RUSHDI, A., R.M. PYTKOWICZ, E. SUESS and C.T.A. CHEN (1992): The effect of magnesium-to-calcium ratios in artifical seawater at different ionic products, upon the induction time and the mineralogy of calcium carbonate: A laboratory study. Geolgische Randschau, 82, 571-578.
50. SCHMALZ, R.F. (1967): Kinetics and diagenesis of carbonate sediments. J. Sediment Petrol., 37, 60-67.
51. SCHMALZ, R.F. and K.E. CHAVE (1965): Calcium carbonate: Factors affecting saturation in ocean waters off Bermuda. Science, 139, 1206.
52. SCHOONMAKER, J.E. (1981): Magnesian calcite-seawater reaction: Solbility and recrysallization behavior. Ph. D. Thesis. Northwestern University.
53. SILLIMAN, B. (1846): On the chemical composition of calcareous corals. Am. J. Sci., 1, 189-199.
54. SILLIMAN, B. (1846); On the chemical composition of calcareous corals. Am. J. S ù., 1, 189-199.
55. SUESS, E. (1970): Interaction of organic compounds with calcium carbonate I . Association phenomena and geochemical implications. Geochim. Cosmochim. Acta, 34, 157-168.
56. SUESS, E. (1973): Interaction of organic compounds with calcium carbonate II. Organo-carbonate assosication in recent sediments. Geochim. Cosmochim. Acta, 37, 2435-2447.
57. THORSTENSON, D.C. and L.N. PLUMMER (1977): Equilibrium criteria for two component solid reacting with fixed composition in an aqueous phase example: The magnesian calcite. Am. J. Sci., 277, 1203-1223.
58. WALTER , L.M. and J.W. MORES (1984): The dissolution kinetics of shallow marine carbonates in seawater A laboratory study. Geochim. Cosmochim. Acta, 49, 1503-1513.
59. WESTALL, J. (1979): MICROQL. A chemical equilibrium program in basic. Chemistry Department. Oregon State University. Corvallis. 41pp.
60. WEYL , P.K. (1961): The carbonate saturatometer, J. Geol., 69, 32-44.
61. WEYL, P.K. (1967): The solution behavior of carbonate materials in seawater. Int'l Conf. Tropical Oceanogr. University of Miami, Miami Florida, 178-228.
62. 2 in Oceans. ANDERSON , N.R. and A. MALAHOFF (Eds.), Plenum Press, New York. 479-492pp.
63. WOLLAST, R. and R.M. PYTKOWICZ (1978): Carbonate equilibrium and phase rule. Geochem J., 12, 199 -200.
64. WOLLAST, R., R.M. GARRELS and F.T. MACKENZIE(1980): Calcite-seawater reaction in ocean surface waters. Am. J. Sci., 280, 831-848.