Decomposition of methyl ethyl ketone peroxide and mixtures with sulfuric acid

Journal of Loss Prevention in the Process Industries

Volumn 17, Issue 1, 2004, Pages 23-28

  Li, Xinrui ^a   Koseki, Hiroshi ^a   Iwata, Yusaku ^a   Mok, Yun Soo ^b  

^a National Res Fustitute of Fire and Disaster   (Japan)

^b Pukyong National University   (South Korea)

Author keywords

Acid decomposition; Heat flux calorimeter; Methyl ethyl ketone peroxide; Modified closed pressure vessel tests; Redox decomposition; Thermal decomposition

Indexed keywords

CALORIMETERS; DECOMPOSITION; EXPLOSIONS; PEROXIDES; PRESSURE MEASUREMENT; PRESSURE VESSELS; PYROLYSIS; REDOX REACTIONS; SULFURIC ACID; THERMAL EFFECTS;

PRESSURE VESSEL TESTS;

KETONES;

DECOMPOSITION;

EID: 0344925003     PISSN: 09504230     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jlp.2003.08.003     Document Type: Article

References (12)

1. Bretherick L. (1987). Handbook of reactive chemical hazards, 3rd ed., London: Butterworth.
2. Fukuyama I. Case studies on accidents of organic peroxides Explosion 2 2 1981 119-127
3. Haba M. The change and analysis of the fire accidents caused by organic peroxides Journal of Japan Society for Safety Engineering 14 3 2002 190-198
4. Hiatt R. Organic peroxides II 1971 Wiley-Interscience Chichester
5. Nicholas A.M. Golubovic A. Studies in organic peroxide. XXV. Preparation, separation and identification of peroxide derived from methyl ethyl ketone and hydrogen peroxide Journal of the American Chemical Society 81 1959 5824
6. Nippon Oil - Fats Co., Ltd (1996). Organic peroxide, 4th ed.. Tokyo.
7. Sun J. Li Y. Hasegawa K. A study of self-accelerating decomposition temperature (SADT) using reaction calorimetry Journal of Loss Prevention in the Process Industries 14 5 2001 331-336
8. Peng J., - Hasegawa K. (1995). On the measurement of violence in the heating decomposition of self-reactive substances. In 8th International Symposium on Loss Prevention and Safety Promotion in the Process Industries, vol. I, pp. 287-301.
9. Ujikawa N., Takamura M., - Kojima T. (1998). Evaluation of curing agent using DSC. In Proceedings of the International Composite EXPO.
10. United Nations (1995). Recommendations on the transport of dangerous goods, manual of tests and criteria of UN, 2nd ed.
11. Watanabe M. Matsunaga T. Wada Y. Tamura M. Yoshida T. Pressure profiles of thermal decomposition of organic peroxides in pressure vessel Kogyo Kayaku Japan 516 1990 355-365
12. Yoshida T. Safety of reactive chemicals 1987 Elsevier Amsterdam