Electrophilic addition of the carbene ligand in [Fe(CO)2(η5-C5H5) {=CMe(OMe)}]+ to the reductively activated benzene ligand in [Mn(CO)3(η4-C6H6)]-]

Organometallics

Volumn 22, Issue 22, 2003, Pages 4361-4363

  Shao, Li ^a   Geib, Steven J ^a   Cooper, N John ^a  

^a UNIVERSITY OF PITTSBURGH   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATED BENZENE LIGAND; ADDUCT; CARBENE LIGAND; ELECTROPHILIC ADDITION; IRON CARBENE CATION;

ADDITION REACTIONS; BENZENE; CHEMICAL BONDS; MANGANESE COMPOUNDS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PARAFFINS; POSITIVE IONS; POTASSIUM COMPOUNDS; REDUCTION; SOLUTIONS; X RAY DIFFRACTION ANALYSIS;

IRON COMPOUNDS;

EID: 0344924992     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om030363i     Document Type: Article

References (12)

1. (a) Zaragoza Dörwald, F. Metal Carbenes in Organic Synthesis; Wiley-VCH: New York, 1999.
2. (b) Brookhart, M.; Studabaker, W. B. Chem. Rev. 1987, 87, 411.
3. (c) Taber, D. F. In Comprehensive Organic Chemistry; Trost, B. M., Fleming, I., Eds.; Pergamon Press: Oxford, U.K., 1991; Vol. 3, p 1045.
4. (a) Kerber, R. C. In Comprehensive Organometallic Chemistry II; Wilkinson, G., Stone, F. G., Abel, E. W., Eds., Pergamon: New York, 1995; Vol. 7, p 101.
5. (b) Pearson, A. J. In Comprehensive Organometallic Chemistry II; Wilkinson, G., Stone, F. G., Abel, E. W., Eds.; Pergamon: New York, 1995, Vol. 7, p 939.
6. (c) Ruck-Braun, K.; Mikulas, M.; Amrhein, P. Synthesis 1999, 727.
7. Lee, S.; Geib, S. J.; Cooper, N. J. J. Am. Chem. Soc. 1995, 117, 9572.
8. Shao, L.; Geib, S. J.; Badger, P. D.; Cooper, N. J. Organometallics 2003, 11, 2811.
9. Brookhart, M.; Tucker, J. R.; Husk, G. R. J. Am. Chem. Soc. 1983, 105, 258.
10. 3).
11. Shao, L.; Geib, S. J.; Badger, P. D.; Cooper, N. J. Organometallics 2003, 22, 3977.
12. 2), 95.9 (CH), 86.1 (CH), 80.2 (CH), 61.1 (CH), 50.2 (CH).