Formation of hybrid organic/inorganic composite membranes via partial pyrolysis of poly(dimethyl siloxane)

Chemical Engineering Science

Volumn 53, Issue 9, 1998, Pages 1699-1711

  Shanan Moore Stevens, N ^a   Rezac, Mary E ^a  

^a Georgia Institute of Technology   (United States)

Author keywords

Composites; Gas separations; Oxidation; Partial pyrolysis; Silicone rubber

Indexed keywords

GAS TRANSPORT; HYBRID ORGANIC COMPOSITE MEMBRANE; INORGANIC COMPOSITE MEMBRANE; OXIDATION; POLY DIMETHYL SILOXANE; PYROLYSIS; THERMOSTABILITY;

CHEMICAL RESISTANCE; COMPOSITE MATERIALS; OXIDATION; POROSITY; POROUS MATERIALS; PYROLYSIS; SILICONES; STRENGTH OF MATERIALS; THERMAL EFFECTS; THERMODYNAMIC STABILITY;

HYBRID ORGANIC/INORGANIC COMPOSITE MEMBRANES; POLYDIMETHYL SILOXANE;

POLYMERIC MEMBRANES;

EID: 0344835840     PISSN: 00092509     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0009-2509(98)00013-X     Document Type: Article

References (47)

1. Armor J. N. Challenges in membrane catalysis. Chemtechnol. 22:1992;557-563.
2. Brandrup J., Immergut E. H. Polymer Handbook. 2:1975;III-165 Wiley, New York.
3. Collins J. P., Schwartz R. W., Sehgal R., Ward T. L., Brinker C. J., Hagen G. P., Udovich C. A. Catalytic dehydrogenationof propane in hydrogen permselective membrane reactors. Ind. Engng Chem. Res. 35:1996;4398-4405.
4. Costello L. M., Koros W. J. Temperature dependence of gas sorption and transport properties in polymers. measurement and applications Ind. Engng Chem. 31:1992;2708-2714.
5. Croson D. J. Appl. Polym. Sci. Appl. Polym. Sympo. #32. Bodnarp M. J:1977;421-443 Wiley, New York.
6. David C. Thermal degradation of polymers. Comprehensive Chemical Kinetics. Vol. 14, Degradation of Polymers:1975;104-107 Elsevier, New York.
7. DeLollis N. J. Cagle C. V. Handbook of Adhesive Bonding. 1973;2.1-2.16 McGraw-Hill, New York.
8. 2 films. Chem. Engng Sci. 44:1989;1829-1835.
9. GE Plastics Information Sheet, 1991.
10. Grassie N., Macfarlane I. G. The thermal degradation of polysiloxanes - I. Poly(Dimethylsiloxane). Eur. Polym. J. 14:1978;875-884.
11. Grosgogeat E. J., Fried J. R., Jenkins R. G., Hwang S.-T. A method for the determination of pore size distribution of molecular sieve materials and its application to the characterization of partially pyrolyzed polysilastyrene, porous glass composite membranes. J. Membrane Sci. 57:1991;237-255.
12. Henis J. M. S., Tripodi M. K. Composite hollow fiber membranes for gas separation. the resistance model approach J. Membrane Sci. 8:1981;233-246.
13. Horkay F., Zrinyi M., Geissler E., Hecht A. M., Pruvost P. Effect of neutral silica particles on the macroscopic swelling and elastic properties of poly(dimethyl siloxane) networks. Polymer. 32:1991;835-839.
14. Huang H. H., Orler B., Wilkes G. L. Structure-property behavior of new hybrid materials incorporating oligomeric species into sol-gel glasses. 3. Effect of acid content, tetraethoxysilane, and molecular weight of poly(dimethyl siloxane). Macromolecules. 20:1987;1322-1330.
15. Hwang S.-T., Kammermeyer K. Surface diffusion in microporous media. Can. J. Chem. Engng. 44:1966;82-89.
16. Hwang, S.-T. and Kammermeyer, K. (1975) Membranes in Separations, pp. 32, 55-67. Wiley, New York.
17. Ilias S., Govind R. Development of high temperature membranes for membrane reactors. an Overview Membrane Reactor Technol. AIChE Symp. Ser. 85:1989;18-25.
18. Ishida H., Dunkers J. The effect of fumed silica upon the reaction of iron octoate and polysiloxanes. J. Appl. Polym. Sci. 44:1992;1331.
19. Itaya K., Sugawara S., Arai K., Saito S. Properties of porous anodic aluminum oxide films as membranes. J. Chem. Engng Japan. 17:1984;514-520.
20. 2 mixture. Sep. Sci. Technol. 22:1987;973-982.
21. Lee, K.-H. and Khang, S.-J. (1987) High temperature membrane. US Patent 4,640,901.
22. Lee K.-H., Khang S.-J. A new silicon-based material formed by pyrolysis of silicon rubber and its properties as a membrane. Chem. Engng Commun. 44:1986;121-132.
23. Li D., Hwang S.-T. Preparation and characterization of silicon based inorganic membrane for gas separation. J. Membrane Sci. 59:1991;331-352.
24. Li Z. Y., Maeda H., Kusakabe K., Morooka S., Anzai H., Akiyama A. Preparation of palladium-silver alloy membranes for hydrogen separation by the spray pyrolysis method. J. Membrane Sci. 78:1993;247-254.
25. Mark J. E., Jiang C. Y., Tang M. Y. Simultaneous curing and filling of elastomers. Macromolecules. 17:1984;2613-2616.
26. Mulder, M. (1991) Basic Principles of Membrane Technology, pp. 66, 160. Kluwer, Boston.
27. 2-membranes on porous sintered metal substrates starting form silicone solutions. Key Engng Mater. 61 62:1991;411-414.
28. Nielsen J. M. Oxidative stabilization of dimethyl silicone fluids with iron between 70 and 370°C. J. Polym. Sci. Symp. No. 40 40:1973;189-190.
29. Nielsen, J. M. (1968) Oxidative stability of silicone fluids. Adv. Chem. Ser. (Amer. Chem. Soc.) No. 85 85, 96, 102.
30. Norton F. J. Permeation of gases through solids. J. Appl. Phys. 25:1957;34-39.
31. Pye D. G., Hoehn H. H., Pana M. Measurement of gas permeability of polymers. II. Apparatus for determination of permeabilities of mixed gases and vapors. J. Appl. Polym. Sci. 20:1976;287-301.
32. Rabek J. F. Oxidative degradation of polymers. Comprehensive Chemical Kinetics. Vol. 14, Degradation of Polymers:1975;456-457 Elsevier, New York.
33. Rao M. B., Sircar S. Nanoporous carbon membranes for separation of gas mixtures by selective surface flow. J. Membrane Sci. 85:1993;253-264.
34. Rao, M. B., Sircar, S. and Golden, T. (1992) Gas separation by adsorbent membranes. US Patent 5,104,425.
35. Rao, M. B., Sircar, S. and Golden, T. (1996) Composite porous carbonaceous membranes. US Patent 5,507,860.
36. Rodriguez F. Principles of Polymer Systems. 3:1989;321 Hemisphere, New York.
37. Saracco G., Versteeg G. F., Van Swaaij W. P. M. Current hurdles to the success of high-temperature membrane reactors. J. Membrane Sci. 95:1994;105-123.
38. Shah V. M., Hardy B. J., Stern S. A. Solubility of carbon dioxide, methane and propane in silicone polymers. effect of side chains J. Polym. Sci. Part B. Polym. Phys. 24:1986;2033-2047.
39. Shelekhin A. B., Grosgogeat E. J., Hwang S.-T. Gas separation properties of a new polymer/inorganic composite membrane. J. Membrane Sci. 66:1991;129-141.
40. Shindo Y., Hakuta T., Yoshitome H., Inoue H. Gas diffusion in microporous media in Knudsen's regime. J. Chem. Engng Japan. 16:1983;120-126.
41. Shindo Y., Obata K., Hakuta T., Yoshitome H., Todo N., Kato J. Permeation of hydrogen through a porous vycor glass membrane. Hydrogen Energy Prog. 1:1980;325-333.
42. Uemiya S., Matsuda T., Kikuchi E. Hydrogen permeable palladium-silver alloy membrane supported on porous ceramics. J. Membrane Sci. 56:1991;315-325.
43. Uemiya S., Sato N., Ando H., Kude Y, Matsuda T., Kikuchi E. Separation of hydrogen through palladium thin film supported on a porous glass tube. J. Membrane Sci. 56:1991;303-313.
44. Vieth W. R., Sladek K. J. A model for diffusion in a glassy polymer. J. Colloid Sci. 20:1965;1014-1033.
45. Ward I. M. Mechanical Properties of Solid Polymers. 1983;133-139 Wiley, New York.
46. Way J. D., Roberts D. L. Hollow fiber inorganic membranes for gas separations. Sep. Sci. Technol. 27:1992;219-229.
47. Wu J. C. S., Flowers D. F., Liu P. K. T. High-temperature separation of binary gas mixtures using microporous ceramic membranes. J. Membrane Sci. 77:1993;85-98.