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note
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We note that under these pH conditions the carboxyl groups are largely protonated. However, flocculation tests confirmed that both nanoparticle dispersions were stable in the deposition solution for several hours.
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note
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This procedure has also been used successfully with glass, quartz, and gold substrates.
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note
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Negatively charged 60 nm aldehdye/sulfate-modified polystyrene nanoparticles were also tested and yielded similar results.
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Control studies that attempted to create multiple layers of the same polymeric nanoparticle yielded only single-particle layers, indicating that the deposition mechanism is initiated by an electrostatic attraction and not a hydrophobic interaction.
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The light source was a 200 W, medium-pressure mercury lamp (Oriel). The beam was collimated, reflected off an air-cooled, dichroic mirror (200-260 nm), and focused by a fused-silica lens.
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0348054189
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A MultiMode NanoScope IIIa SFM (Digital Instruments) equipped with a recently calibrated 150 μm tube scanner was operated in tapping mode under ambient conditions for all measurements.
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0347423719
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Optical and fluorescent microscopy images were acquired using an Olympus BX50WI epi fluorescence microscope equipped with a DC-330 3CCD color camera (Dage-MTI) and a mercury light source. All fluorescence images were collected using a 51004v2 filter set (excitation BP: 475-492.5 nm, 545-565 nm; emission BP: 503-533 nm, 582-622 nm (Chroma Technology Corp.)).
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Immersion studies in 0.1 M NaOH were carried out on a gold substrate because NaOH is a known silicon etchant.
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m) is 240-250°C.
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Brandrup, J., Immergut, E. H., Grulk, E. A., Eds.; John Wiley & Sons: New York
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