Mild, fast, and stereoselective epoxide opening by ketone enolate anions. Application to synthesis of the norlignan curculigine

Journal of Organic Chemistry

Volumn 68, Issue 8, 2003, Pages 3049-3054

  Posner, Gary H ^a   Maxwell, John P ^b   Kahraman, Mehmet ^a  

^a JOHNS HOPKINS UNIVERSITY   (United States)

^b VERTEX PHARMACEUTICALS   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

HYDROCARBONS; KINETIC THEORY; NEGATIVE IONS; STEREOCHEMISTRY; SYNTHESIS (CHEMICAL);

DIASTEREOSELECTIVITY;

KETONES;

2 CYCLOHEPTENONE; 2 CYCLOHEXANONE; ALKANONE; ANION; CURCULIGINE; CYCLOALKANONE DERIVATIVE; CYCLOHEXANE OXIDE; CYCLOHEXENE DERIVATIVE; CYCLOPENTENE DERIVATIVE; EPOXIDE; GAMMA HYDROXYKETONE; KETONE DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL BINDING; CHEMICAL INTERACTION; CHEMICAL REACTION; CHEMICAL STRUCTURE; DIASTEREOISOMER; KINETICS; PROTON TRANSPORT; STEREOCHEMISTRY;

CATALYSIS; CHEMISTRY, ORGANIC; EPOXY COMPOUNDS; INDICATORS AND REAGENTS; KETONES; KINETICS; LIGNANS; MOLECULAR STRUCTURE; NUCLEAR MAGNETIC RESONANCE, BIOMOLECULAR; STEREOISOMERISM;

EID: 0344519742     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo020744q     Document Type: Article

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