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Total energy calculations using the DFT-slab approach with GGA-PW91 functional were performed. The program used was CASTEP.19 The Ir{111} and Pt{111} surfaces were modeled by a four-layer slab with top layer relaxed; the Ir{211} and Pt{211} surfaces were modeled by 12-layer slabs with the top three layers relaxed. The other calculation parameters are identical to those described in ref 15.
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