Structures of rare earth homodinuclear macrocyclic complexes with the polyamine polycarboxylic ligand 1,4,7,10,14,17,20,23-octaazacyclohexacosane- 1,4,7,10,14,17,20,23-octaacetic acid (H8OHEC) in the crystal and in solution

European Journal of Inorganic Chemistry

Volumn , Issue 10, 1999, Pages 1735-1743

  Schumann, Herbert ^a   Böttger, Ulrike A ^a   Weisshoff, Hardy ^b   Ziemer, Burkhard ^b   Zschunke, Adolf ^b,c  

^a TECHNISCHE UNIVERSITÄT BERLIN   (Germany)

^b HUMBOLDT UNIVERSITY   (Germany)

^c BAM FEDERAL INSTITUTE FOR MATERIALS RESEARCH AND TESTING   (Germany)

Author keywords

Crystal structure; Homodinuclear lanthanide complexes; Lanthanides; Macrocyclic ligands; Polyamine polycarboxylic acid; Solution structure

Indexed keywords

ACTIVATION ANALYSIS; ACTIVATION ENERGY; ATOMS; CONFORMATIONS; COPPER COMPOUNDS; CRYSTAL STRUCTURE; ISOMERS; LIGANDS; MOLECULES; RARE EARTHS; RATE CONSTANTS; SOLID SOLUTIONS; TEMPERATURE;

CRYSTALS STRUCTURES; HOMODINUCLEAR LANTHANIDE COMPLEX; LANTHANIDES COMPLEXES; LIGAND SYSTEM; MACRO-CYCLIC LIGANDS; POLYAMINE POLYCARBOXYLIC ACID; POLYAMINES; POLYCARBOXYLIC ACIDS; RARE-EARTHS; SOLUTION STRUCTURES;

RARE EARTH ELEMENTS;

1,4,7,10,14,17,20,23 OCTAAZACYCLOHEXACOSANE 1,4,7,10 14,17,20,23 OCTAACETIC ACID; ACETIC ACID DERIVATIVE; AMINE; COPPER COMPLEX; LANTHANIDE; METAL COMPLEX; UNCLASSIFIED DRUG;

AQUEOUS SOLUTION; ARTICLE; CHEMICAL REACTION KINETICS; CHEMICAL STRUCTURE; COMPLEX FORMATION; CRYSTAL STRUCTURE; ISOMER; LIGAND BINDING; MOLECULAR MODEL; REACTION ANALYSIS; SOLID STATE; STRUCTURE ANALYSIS; TEMPERATURE SENSITIVITY;

EID: 0344199963     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/(sici)1099-0682(199910)1999:10<1735::aid-ejic1735>3.0.co;2-3     Document Type: Article

References (49)

1. V. Alexander, Chem. Rev. 1995, 95, 273-342.
2. [2a] J. P. L. Cox, K. J. Jankowski, R. Kataky, D. Parker, N. R. A. Beeley, B. A. Boyce, M. A. W. Eaton, K. Millar, A. T. Millican, A. Harrison, C. Walker, J. Chem. Soc., Chem. Commun. 1989, 797-798.
3. [2b] D. Parker, Crown Compounds Toward Future Applications (Ed.: S.R. Cooper), VCH Publishers, Inc., New York, 1992, Chapter 4.
4. [3a] R. B. Lauffer, Chem. Rev. 1987, 87, 901-927.
5. [3b] R. G. Choppin, K. M. Schaab, Inorg. Chim. Acta 1996, 252, 299-310.
6. [4a] M.-R. Spirlet, J. Rebizant, J. F. Desreux, M.-F. Loncin, Inorg. Chem. 1984, 23, 359-363.
7. [4b] J. P. Dubost, J. M. Legar, M. H. Langlois, D. Meyer, M. C. R. Schaefer, Acad. Sci. Paris Ser. 2 1991, 312, 349.
8. [4c] C. A. Chang, L. C. Francesconi, M. F. Malley, K. Kumar, J. Z. Gougoutas, M. F. Tweedle, Inorg. Chem. 1993, 32, 3501-3508.
9. [4d] D. Parker, K. Pulukkody, F. C. Smith, A. Batsanov, J. A. K. Howard, J. Chem. Soc. Dalton Trans. 1994, 689-693.
10. [4e] S. Aime, A. Barge, M. Botta, M. Fasano, J. D. Ayala, G. Bombieri, Inorg. Chim. Acta 1996, 246, 423-429.
11. [4f] S. Aime, A. Barge, F. Benetello, G. Bombieri, M. Botta, F. Uggeri, Inorg. Chem. 1997, 36, 4287-4289.
12. [4g] M.-R. Spirlet, J. Rebizant, M. F. Loncin, J. F. Desreux, Inorg. Chem. 1984, 23, 4278-4283.
13. [5a] S. Aime, P. L. Anelli, M. Botta, F. Fedeli, M. Grandi, P. Paoli, F. Uggeri, Inorg. Chem. 1992, 31, 2422-2428.
14. [5b] S. Aime, M. Botta, G. Ermondi, F. Fedeli, F. Uggeri, Inorg. Chem. 1992, 31, 1100-1103.
15. [5c] D. Dischino, E. J. Delaney, J. E. Emswiler, G. T. Gaughan, J. S. Prasad, S. K. Srivastava, M. F. Tweedle, Inorg. Chem. 1991, 30, 1265-1269.
16. [5d] S. I. Kang, R. S. Ranganathan, J. E. Emswiler, K. Kumar, J. Z. Gougoutas, M. F. Malley, M. F. Tweedle, Inorg. Chem. 1993, 32, 2912-2918.
17. [5e] K. Kumar, C. A. Chang, L. C. Francesconi, D. D. Dischino, M. F. Malley, M. F. Gougoutas, M. F. Tweedle, Inorg. Chem. 1994, 33, 3567-3575.
18. [5f] Z. Kovacs, A. D. Sherry, J. Chem. Soc., Chem. Commun. 1995, 185-186.
19. [5g] J. Huskens, D. A. Torres, Z. Kovacs, J. P. André, C. F. G. C. Geraldes, A. D. Sherry, Inorg. Chem. 1997, 36, 1495-1503.
20. [5h] J. Platzek, P. Blaszkiewicz, H. Gries, P. Luger, G. Michl, A. Müller-Fahrnow, B. Radüchel, D. Sülzle, Inorg. Chem. 1997, 36, 6086-6093.
21. [6a] J. F. Desreux, Inorg. Chem. 1980, 19, 1319-1324.
22. [6b] S. Aime, M. Botta, G. Ermondi, Inorg. Chem. 1992, 31, 4291-4299.
23. [6c] K. Roth, S. Hoeft, Chem. Ber. 1993, 126, 869-873.
24. [6d] V. Jacques, J. F. Desreux, Inorg. Chem. 1994, 33, 4048-4053.
25. [6e] S. Aime, M. Botta, M. Fasano, P. M. Marques, C. F. G. C. Geraldes, D. Pubanz, A. E. Merbach, Inorg. Chem. 1997, 36, 2059-2068 and references cited therein.
26. [6f] S. Aime, M. Botta, G. Ermondi, E. Terreno, P. L. Anelli, F. Fedeli, F. Uggeri, Inorg. Chem. 1996, 35, 2726-2736.
27. [6g] S. Aime, M. Botta, A. S. De Sousa, D. Parker, Angew. Chem. 1998, 110, 2819-2820.
28. R. Ziessel, M. Maestri, L. Pridi, V. Balzani, A. V. Dorsselaer, Inorg. Chem. 1993, 32, 1237-1241.
29. E. Toth, S. Vauthey, D. Pubanz, A. E. Merbach, Inorg. Chem. 1996, 35, 3375-3379.
30. U. A. Böttger, H. Gries, F. E. Hahn, H. Hemling, G. Kociok-Köhn, J. Pickardt, J. Platzek, B. Radüchel, B. Schiefner, H. Schumann, K. Zietzke, A. Zschunke, Chem. Ber. 1997, 130, 267-277.
31. U. A. Böttger, H. Weisshoff, A. Zschunke, H. Schumann, to be published.
32. [11a] M. Kodama, T Koike, A. B. Mahatma, E. Kimura, Inorg. Chem. 1991, 30, 1270-1273.
33. [11b] S. L. Wu, W. D. Horrocks, Jr., Inorg. Chem. 1995, 34, 3724-3732.
34. S. L. Wu, K. A. Johnson, W. D. Horrocks, Jr., Inorg. Chem. 1997, 36, 1884-1889.
35. C. Lecomte, V. Dahaoui-Gindrey, H. Chollet, C. Gros, A. K. Mishra, F. Barbette, P. Pullumbi, R. Guilard, Inorg. Chem. 1997, 36, 3827-3838.
36. U. Böttger, O. Galin, H. Schumann, M. Michman, Inorg. Chim. Acta 1995, 231, 29-34.
37. M. G. B. Drew, Coord. Chem. Rev. 1977, 24, 179-275 and references cited therein.
38. J. Dale, Isr. J. Chem. 1980, 20, 3-11.
39. [17a] P. M. Lowe, P. Caravan, S. J. Rettig, C. Orvig, Inorg. Chem., 1998, 37, 1637-1647.
40. [17b] F. Renaud, C. Piguet, G. Bernardinelli, J.-C. G. Bünzli, G. Hopfgartner, Chem. Eur. J., 1997, 3, 1646-1659.
41. J. F. Desreux, M. F. Loncin, Inorg. Chem. 1986, 25, 69-74.
42. N. Walker, D. Stuart, Acta Cryst. A39 1983, 158-166.
43. A. C. T. North, D. C. Phillips, F. S. Mathews, Acta Cryst. A24 1968, 351-359.
44. G. M. Sheldrick, Acta Cryst. A46 1990, 467-473.
45. G. M. Sheldrick, Program for Crystal Structure Refinement 1993, Universität Göttingen, Germany.
46. AURELIA manual, version 941101.3 Bruker Analytische Messtechnik GmbH, FRG, 1994.
47. T. E. J. Bull, Magn. Reson. 1988, 80, 470.
48. DNMR-SIM, version 1.00, G. Haegele, R. Fuhler, Institut für Anorganische und Strukturchemie I, Universität Düsseldorf, FRG, 1996. This program is available on the Internet: ftp:// ftp.uni-duesseldorf.de/pub/msdos/chemie.
49. WIN-DAISY, version 4.0 Bruker-Franzen Analytik GmbH, FRG, 1997.