Raman spectroscopic investigation of speciation in MgSO4(aq)

Physical Chemistry Chemical Physics

Volumn 5, Issue 23, 2003, Pages 5253-5261

  Rudolph, W W ^a,c   Irmer, G ^b   Hefter, G T ^c  

^a DRESDEN UNIVERSITY OF TECHNOLOGY   (Germany)

^b Inst Theor Physik TU B   (Germany)

^c MURDOCH UNIVERSITY   (Australia)

Author keywords

[No Author keywords available]

Indexed keywords

AMMONIUM SULFATE; MAGNESIUM CHLORIDE; MAGNESIUM PERCHLORATE; MAGNESIUM SULFATE;

AQUEOUS SOLUTION; ARTICLE; CHEMICAL BOND; MATHEMATICAL ANALYSIS; MEASUREMENT; QUANTITATIVE ANALYSIS; RAMAN SPECTROMETRY; TEMPERATURE; THERMODYNAMICS;

EID: 0344197002     PISSN: 14639076     EISSN: None     Source Type: Journal    
DOI: 10.1039/b308951g     Document Type: Article

References (46)

1. Handbook of Metal-Ligand Interactions, ed. G. Berthon, Dekker, New York, 1995.
2. F. H. Fisher, Science (Washington, D. C.), 1967, 157, 823.
3. F. H. Fisher, Geochim. Cosmochim. Acta, 1972, 36, 99.
4. J. P. Riley and G. Skirrow, Chemical Oceanography, Academic Press, London, 1975.
5. Chemistry of Marine Water and Sediments, ed. A. Gianguzza, E. Pelizetti and S. Sammartano, Springer, Berlin, 2002.
6. Y.-H. Zhang and C. K. Chan, J. Phys. Chem. A, 2002, 106, 285.
7. A. R. Davis and B. G. Oliver, J. Phys. Chem., 1973, 77, 1315.
8. R. M. Chatterjee, W. A. Adams and A. R. Davis, J. Phys. Chem., 1973, 78, 246.
9. F. P. Daly, C. Brown and D. R. Kester, J. Phys. Chem., 1973, 76, 3664.
10. F. Rull, Ch. Balarew, J. L. Alvarez, F. Sobron and A. Rodriguez, J. Raman Spectrosc., 1994, 25, 933.
11. C. C. Pye and W. W. Rudolph, J. Phys. Chem. A, 1998, 102, 9933.
12. R. Buchner, T. Chen and G. Hefter, J. Phys. Chem., 2003, accepted for publication.
13. M. Eigen and K. Tamm, Z. Elektrochem., 1962, 66, 93.
14. M. Eigen and K. Tamm, Z. Elektrochem., 1962, 66, 107.
15. G. Atkinson and S. Petrucci, J. Phys. Chem., 1966, 70, 3122.
16. W. W. Rudolph, M. H. Brooker and C. C. Pye, J. Phys. Chem., 1995, 99, 3793.
17. 17 W. W. Rudolph, Z. Phys. Chem., 1996, 194, 73 ; W. W. Rudolph, C. C. Pye and G. Irmer, J. Raman Spectrosc., 2002, 33, 177.
18. W. W. Rudolph, Z. Phys. Chem., 1996, 194, 73 ; W. W. Rudolph, C. C. Pye and G. Irmer, J. Raman Spectrosc., 2002, 33, 177.
19. G. Schwarzenbach and H. Flaschka, Complexometric Titrations, 2nd edn., Methuen, London, 1969.
20. W. W. Rudolph and G. Irmer, J. Solution Chem., 1994, 23, 663; W. W. Rudolph, M. H. Brooker and P. R. Tremaine, Z. Phys. Chem., 1999, 209, 181.
21. W. W. Rudolph and G. Irmer, J. Solution Chem., 1994, 23, 663; W. W. Rudolph, M. H. Brooker and P. R. Tremaine, Z. Phys. Chem., 1999, 209, 181.
22. C. C. Pye and W. W. Rudolph, J. Phys. Chem. A, 2001, 105, 905.
23. W. W. Rudolph and S. Schoenherr, Z. Phys. Chem. (Leipzig), 1989, 270, 1121.
24. -1.
25. I. Nakagawa and T. Shimanouchi, Spectrochim. Acta, 1964, 20, 429; K. Fujita and M. Kimura, J. Raman Spectrosc., 1981, 11, 108.
26. I. Nakagawa and T. Shimanouchi, Spectrochim. Acta, 1964, 20, 429; K. Fujita and M. Kimura, J. Raman Spectrosc., 1981, 11, 108.
27. -1) slit widths then commonly available.
28. R. E. Hester and R. A. Plane, Inorg. Chem., 1964, 3, 769.
29. H. Nomura, S. Koda, Y. Miyahara, in Water and Cations in Biological Systems, ed. B. Pullman and K. Yagi, Japan Scientific Society, Tokyo, 1980, p. 31.
30. F. Rull and F. Sobron, J. Raman Spectrosc., 1994, 25, 693.
31. F. Rull and H. Ohtaki, Spectrochim Acta A, 1997, 53, 643.
32. J. M. Alia, in Handbook of Raman Spectroscopy, ed. I. R. Lewis and H. G. M. Edwards, Marcel Dekker, New York, 2001.
33. J. E. Griffiths, in Vibrational Spectra and Structure, vol. 6, ed. J. R. Durig, Elsevier, Amsterdam, 1977.
34. R. Buchner, S. G. Capewell, G. T. Hefter and P. M. May, J. Phys. Chem. B, 1999, 103, 1185.
35. S. C. B. Myneni, Rev. Mineral. Geochem., 2000, 40, 113.
36. F. Malatesta, Quim. Anal., 1996, 15, S9.
37. B. E. Conway, in Modern Aspects of Electrochemistry, ed. B. E. Conway and R. E. White, Kluwer Academic/Plenum, New York, 2002, vol. 35, p. 295ff.
38. See, for example, J. A. Rard, J. Chem. Thermodyn., 1997, 29, 533.
39. L. G. Hepler and H. P. Hopkins, Rev. Inorg. Chem., 1979, 1, 333.
40. See, for example, M. H. Brooker, Raman Spectroscopic Measurements of Ion Hydration, in The Chemical Physics of Ion Hydration, ed. R. R. Dogonadze, E. Kálmán, A. A. Kornyshev and J. Ulstrup, Elsevier, Amsterdam, 1986, Part B, ch. 4.
41. D. W. James and R. L. Frost, Aust. J. Chem., 1982, 35, 1793.
42. D. W. James, M. T. Carrick and R. L. Frost, J. Raman Spectrosc., 1982, 13, 115.
43. Y.-H. Zhang and C. K. Chan, J. Phys. Chem. A, 2000, 104, 9191.
44. iso profile, as in the present study, has the advantage that the scattering contribution of the water is partially removed.
45. V. Tomišic and V. Simeon, Phys. Chem. Chem. Phys., 2000, 2, 1943.
46. H. F. Shurvell, and J. T. Bulmer, in Vibrational Spectra and Structure, ed. J. R. Durig, Elsevier, Amsterdam, 1977, vol. 6, ch. 2. Phys. Chem. Chem. Phys., 2003, 5, 5262-5270