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Volumn 19, Issue 8, 2003, Pages 3190-3197

Solvolysis of benzoyl halides in AOT/isooctane/water microemulsions. Influence of the leaving group

Author keywords

[No Author keywords available]

Indexed keywords

INTERFACES (MATERIALS); MICROEMULSIONS; RATE CONSTANTS; SURFACE ACTIVE AGENTS;

EID: 0344089255     PISSN: 07437463     EISSN: None     Source Type: Journal    
DOI: 10.1021/la026753b     Document Type: Article
Times cited : (38)

References (39)
  • 21
    • 0345235967 scopus 로고    scopus 로고
    • note
    • i from bulk water to microemulsions with high water content (W = 50) and low water content (W = 2). For BzF, we observe a 43-fold decrease in the solvolysis rate constant on going from bulk water to W = 50 and a 2.5-fold decrease on going from W = 50 to W = 2.
  • 24
    • 0344373195 scopus 로고    scopus 로고
    • note
    • BzF with W would be the most pronounced of the three substrates studied.
  • 39
    • 0345667831 scopus 로고    scopus 로고
    • note
    • T(30) polarity parameter determined in AOT/hexane/water microemulsions. The existence of such a correlation from W = 50 to W = 2 is a good test of the existence of a dissociative mechanism of solvolysis of substituted benzoyl halides.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.