Synthesis of agarofuran antifeedants. Part 6: Enantioselective synthesis of a key decalinic intermediate

Tetrahedron Asymmetry

Volumn 14, Issue 9, 2003, Pages 1153-1159

  Boyer, François Didier ^a   Prangé, Thierry ^b   Ducrot, Paul Henri ^a  

^a CEMAGREF   (France)

^b CSSB Chimie Struct Biomoleculaire   (France)

Author keywords

[No Author keywords available]

Indexed keywords

2 CYCLOHEXENONE; AGAROFURAN DERIVATIVE; LEWIS ACID;

ARTICLE; CATALYSIS; CHIRALITY; ENANTIOSELECTIVITY; PRIORITY JOURNAL; SYNTHESIS;

EID: 0344088297     PISSN: 09574166     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0957-4166(03)00132-0     Document Type: Article

References (13)

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7. Boyer, F.-D.; Descoins, C. L.; Vo Thanh, G.; Descoins, C.; Prangé, T.; Ducrot, P.-H. Eur. J. Org. Chem. 2003, accepted;
8. Boyer, F.-D.; Descoins, C.; Ducrot, P.-H. Eur. J. Org. Chem. 2003, accepted.
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13. 2 data). The two independent molecules in the X-ray structure of 13 giving the configurations of the chiral centres with respect to the (S,S)-diphenyl ketal moiety at C(9). They both differ in ring conformations and orientation of the carboxymethyl at C(5). X-Ray data for compound 13 are available from the Cambridge Crystallographic Data Centre, 12, Union Road, CB2 1EZ Cambridge, UK as a cif file with ref. CCDC 196010. It is also available from authors (T.P.) upon request at prange@lure.u-psud.fr.