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Volumn 27, Issue 4, 2003, Pages 675-679

Zircona-phosphazine complexes: Synthesis and X-ray determination

Author keywords

[No Author keywords available]

Indexed keywords

AMPHOLYTE; METAL COMPLEX; PHOSPHORUS DERIVATIVE; ZIRCONIUM DERIVATIVE;

EID: 0344080413     PISSN: 11440546     EISSN: None     Source Type: Journal    
DOI: 10.1039/b210773m     Document Type: Article
Times cited : (13)

References (48)
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    • For C-bonded diazoalkane transition metal compounds: Pd complexes: S. I. Murahashi, Y. Kitani, T. Hosokawa, K. Miki and N. Kasai, J. Chem. Soc., Chem. Commun., 1979, 450 ; Os complexes: M. A. Gallo, T. C. Jones, C. E. F. Rickard and W. R. Roper, J. Chem. Soc., Chem. Commun., 1979, 450 ; Rh complexes: E. Deydier, M.-J. Menu, M. Dartiguenave, Y. Dartiguenave, M. Simard, A. L. Beauchamp, J. C. Brewer and H. B. Gray, Organometallics, 1996, 15, 1166; M.-J. Menu, J. Desrosiers, M. Dartiguenave, Y. Dartiguenave and G. Bertrand, Organometallics, 1987, 6, 1822 ; Ni complexes: M.-J. Menu, H. König, M. Dartiguenave, Y. Dartiguenave and H. F. Klein, J. Am. Chem. Soc., 1990, 112, 5351.
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    • eds. E. W. Abel, F. G. A. Stone and G. Wilkinson, Pergamon, New York
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    • ed. A. W. Johnson, Wiley, New York
    • (d) For a review, see: Ylides and Imines of Phosphorus, ed. A. W. Johnson, Wiley, New York, 1993, p. 453.
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    • ed. A. W. Johnson, Wiley, New York
    • Note that N-metal substituted iminophosphoranes generally show P-N bond lengths slightly under 1.60 Å, see: Ylides and Imines of Phosphorus, ed. A. W. Johnson, Wiley, New York, 1993, pp. 444-449; F. Baier, Z. Fei, H. Gornitzka, A. Murso, S. Neufeld, M. Pfeiffer, I. Rüdenauer, A. Steiner, T. Stey and D. Stalke, J. Organomet. Chem., 2002, 661, 111-127.
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    • note
    • Zr-N distances of 2.45-2.50 Å suggest dative interactions in Zr(IV) complexes. Moreover, the mean Zr-N bond distances in amido and ketimide complexes determined from the Cambridge Structural Database are 2.15 and 2.04 Å, respectively.
  • 47
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    • WINGX - 1.63 integrated system of windows programs for the soluton refinement analysis of single crystal X-ray diffraction data
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