Corrosion of Borosilicate Sealing Glasses for Molten Carbonate Fuel Cells

Journal of the American Ceramic Society

Volumn 86, Issue 11, 2003, Pages 1918-1926

  Pascual, Maria J ^a   Pascual, Luis ^a   Valle, Francisco J ^a   Durán, Alicia ^a   Berjoan, Rene ^b  

^a INSTITUTO DE CERÁMICA Y VIDRIO   (Spain)

^b IMP UPR CNRS 8521   (France)

Author keywords

[No Author keywords available]

Indexed keywords

CARBONATES; CORROSION RESISTANCE; DIFFUSION; FUEL CELLS; REACTION KINETICS; SCANNING ELECTRON MICROSCOPY; SEALANTS; THERMAL EXPANSION; X RAY DIFFRACTION ANALYSIS; X RAY PHOTOELECTRON SPECTROSCOPY;

ARRHENIUS LAW;

BOROSILICATE GLASS;

EID: 0344012232     PISSN: 00027820     EISSN: None     Source Type: Journal    
DOI: 10.1111/j.1151-2916.2003.tb03582.x     Document Type: Article

References (34)

1. M. J. Pascual, L. Pascual, and A. Duran, "Vidrios y Vitrocerámicos para Soldadura: Aplioaciones Tradicionales y Nuevasdemandas," Bol. Soc, Esp, Ceram. Vidr., 36 [4] 383-98 (1997).
2. (a)C. Kroger and E. Fingas, "Action of Quartz and Alkali Silicates on Alkali Carbonates," Z. Anor. Allg. Chem., 213 [1] 12-57 (1933);
3. (b)Ceram. Abs., 14 [1] 21 (1935);
4. (c)Chem. Abs., 27 [19] 4751 (1933).
5. J. T. Howarth, W. Maskill, and W. E. S. Turner, "Rate of Reaction between Silica and Sodium Carbonate at Different Temperatures and Processes of Vitrification," J. Soc. Class. Technol., 1725-49T (1933).
6. G. R. Pole and N. W. Taylor, "Kinetics of Solid-Phase Reaction of Certain Carbonates with Mullite, Silica, and Alumina," J. Am. Ceram. Soc., 18 [11] 325-37 (1935).
7. J. Wilhelm, "Reactions in Solid State at High Temperatures, I: Reaction Rates of Endothermic Reactions," Z. Anor. Allg. Chem., 163. 1-30 (1927).
8. J. W. Wilburn, S. A. Metcalfe, and R. S. Warburton, "Differential Thermal Analysis, Differential Thermogravimetric Analysis, and High Temperature Microscopy of Reactions between the Major Components of a Sheet Glass Batch," Glass Technol., 6 [4] 107-14 (1965).
9. M. Cable and D. Martlew, "Dissolution of Silica in Melts of the Sodium Carbonate-Sodium Metasilicate System," Glass Technol., 25 [3] 139-44 (1984).
10. M. Cable and D. Martlew, "The Dissolution of Silica in Melts Containing Sodium Carbonate, Sodium Sulphate, and Silica," Glass Technol., 28 [5] 203-207 (1987).
11. D. R. Patel, "Corrosion of Vitreous Silica by a Sodium Carbonate Melt with a Little Sodium Nitrate"; M. Sc. Tech. Diss. University of Sheffield, Sheffield, UK, 1977.
12. 3Melts," Glastech. Ber., 61 [2] 31-35 (1988).
13. L. C. Klein and C. J. Brinker, "Crystallization in Mixed-Alkali Silicate and Borosilicate Glasses in Contact with Molten Sodium"; pp. 287-300 in Advances in Ceramics, Vol. 4. Nucleation and Crystallization in Glasses. Edited by J. H. Simmons, D. R. Uhlman, and G. H. Beall. American Ceramic Society, Columbus, OH, 1982.
14. C. J. Brinker and L. C. Klein, "Behavior of Silicate and Borosilicate Glasses in Contact with Metallic Sodium, I: Sodium Silicate Glasses," Phys. Chem. Glasses, 21 [4] 141-45 (1980).
15. C. J. Brinker and L. C. Klein, "Behavior of Silicate and Borosilicate Glasses in Contact with Metallic Sodium, II: Borosilicate Glasses," Phys. Chem. Glasses, 22 [2] 23-28 (1981).
16. D. S. Fox and N. S. Jacobson, "Molten-Salt Corrosion of Silicon Nitride. I: Sodium Carbonate," J. Am. Ceram. Soc., 71 [2] 128-138 (1988).
17. J. H. Scofield, "Hartree Slater Subshell Photoionization Cross Sections at 1254 and 1487 eV," J. Electron. Spectrosc. Relat. Phenom. 8, 129 (1976).
18. P. W. J. M. Boumans and A. Tresenius, "Inductively Coupled Plasma-Atomic Emission Speotroscopy: Its Present and Future Position in Analytical Chemistry," Anal. Chem. 299, 341 (1979).
19. H. Bennett and R. A. Reed. Chemical Methods of Silicate Analysis. Academic Press, London, 1976.
20. G. Marietta. "Cation Dependence of the Chemical Modifications Induced by Low Energy Particle Bombardment on Inorganic Salts: An XPS Study," Nucl. Instrum. Meth. Phys. Res. B32, 204 (1988).
21. 2, R = Li, K, Na," Phys. Chem. Glasses, 43 [1] 25-31 (2002).
22. B. C. Bunker and G. W. Arnold, "Phosphate Glass Dissolution in Aqueous Solutions," J. Non-Cryst. Solids., 64, 291-316 (1984).
23. (a)B. Serin and R. T. Ellickson, "Determination of Diffusion Coefficients," J. Chem. Phys., 9, 742-47 (1941);
24. (b)Chem. Abs., 35 [22] 77-82 (1941).
25. D. E. Clark and K. Zoitos, "Nuclear Waste Glasses: Corrosion Behavior and Field Test"; pp. 218-39 in Corrosion of Glass, Ceramics and Ceramic Superconductors: Principles, Testing, Characterization and Applications. Material Science and Process Technology Series, Noyes Publications, New Jersey, 1992.
26. G. Gibson and R. Ward, "Reaction in Solid State, II: Reaction between Sodium Carbonate and Quartz," J. Am. Ceram. Soc., 26 [7] 239-46 (1943).
27. M. P. Romero, and A. La Iglesia, "Obtencion del Metasilioato de Litio. I. Puesta a punto de un Método Experimental de Síntesis," Publicaciones División Elementes Combustibles JEN, R-101/85 Madrid, Spain, (1985).
28. M. P. Romero and A. La Iglesia, "Obtención del Metasilicato de Litio, II: Estudio de la Cinética del Proceso." Publicaoiones Division Elementos Combustibles JEN, R-106/85 (1985).
29. A. La Iglesia, "Materiales Ceramicos Fertiles en Fusion Termonuclear, I: Síntesis Qqy Sinterización del Onosilicato de Litio," Bol. Soc. Esp. Ceram. Vid., 28 [3] 179-86 (1989).
30. 2 with K = Li, K, Na: Influence on Thermal Properties," Glass Sci. Technol. 75 [6] 280-89 (2002).
31. T. M. El-Shamy, R. W. Douglas, "Kinetics of the Reaction of Water with Glass," Glass Technol., 13, 77, 1972.
32. T. M. El-Shamy, J. Lewins, R. W. Douglas, "The Dependence on the pH of the Decomposition of Glasses by Aqueous Solutions," Glass Technol., 13, 81, 1972.
33. G. G. Wicks and R. M. Wallace, Leachabiliry of Waste Glass Systems: Physical and Mathematical Models, DP-MS-82-18, Savannah River Laboratory, Aiken, SC, 1982.
34. R. M. Wallace and G. G. Wicks; pp. 23 in Scientific Basic for Nuclear Waste Management VI, vol. 15. Edited by D. C. Brookins. Elsevier, Amsterdam, 1983.