Hydrolysis and condensation rates of tetramethyl orthosilicate in alcohol solutions of hydrated metal salts as determined by means of FT-IR spectroscopy

Colloids and Surfaces A: Physicochemical and Engineering Aspects

Volumn 123-124, Issue , 1997, Pages 329-337

  Öye, Gisle ^a   Libnau, Fred Olav ^a   Sjöblom, Johan ^a   Friberg, Stig E ^b  

^a UNIVERSITY OF BERGEN   (Norway)

^b CLARKSON UNIVERSITY   (United States)

Author keywords

Condensation; FT IR spectroscopy; Hydration water; Hydrolysis; Rate constants; Tetramethyl orthosilicate

Indexed keywords

COMPOSITION EFFECTS; CONDENSATION REACTIONS; DISSOCIATION; ETHANOL; FOURIER TRANSFORM INFRARED SPECTROSCOPY; HYDROLYSIS; METHANOL; NITRATES; REACTION KINETICS; REGRESSION ANALYSIS; SALTS; SOLVENTS;

HYDRATED METAL SALTS; TETRAMETHYL ORTHOSILICATE;

SILICATES;

ALCOHOL; CALCIUM NITRATE TETRAHYDRATE; METHANOL; NICKEL NITRATE HEXAHYDRATE; NITRIC ACID DERIVATIVE; SILICATE; UNCLASSIFIED DRUG; WATER;

ARTICLE; DISSOCIATION; HYDRATION; HYDROLYSIS; INFRARED SPECTROSCOPY; PRIORITY JOURNAL; TITRIMETRY;

EID: 0343907710     PISSN: 09277757     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0927-7757(96)03938-6     Document Type: Article

References (17)

1. C.J. Brinker and G.W. Scherer, Sol-Gel Science. The Physics and Chemistry of Sol-Gel Processing, Academic Press, New York, 1990.
2. R. Aelion, A. Loebel and F. Eirich, J. Am. Chem. Soc., 72 (1950) 5705.
3. R.A. Assink and B.D. Kay, J. Non-Crystalline Solids, 107 (1988) 35.
4. J.C. Pouxviel and J.P. Boilot, J. Non-Crystalline Solids, 94 (1987) 374.
5. S.E. Friberg, J. Yang, A. Amran, J. Sjöblom and G. Farrington, J. Phys. Chem., 98 (1994) 13528.
6. J. Sanchez and A. McCormick, J. Phys. Chem., 96 (1992) 8973.
7. R.A. Assink and B.D. Kay, J. Non-Crystalline Solids, 99 (1988) 359.
8. M.H. Selle, F. Fredriksen, J. Sjöblom, A. Christy and S.E. Friberg, Acta Chem. Scand., 50 (1996) 12.
9. J. Sjöblom, T. Skodvin, M.H. Selle and J.O. Saeten, J. Phys. Chem., 96 (1992) 8578.
10. A. Amran, S.E. Friberg and J. Sjöblom, J. Dispersion Sci. Technol., 15 (1994) 621.
11. I.I.S. Ignatyev, A.N. Lazarev, T.F. Tenisheva and B.F. Shchegolev, J. Mol. Struct., 244 (1991) 193.
12. A.C. Hess, P.F. McMillan and M. O'Keeffe, J. Phys. Chem., 92 (1988) 1785.
13. F. Orgaz et al., J. Non-Crystalline Solids, 82 (1986) 378.
14. A. Chmel, E.K. Mazurina and V.S. Shashkin, J. Non-Crystalline Solids, 122 (1990) 285.
15. J. Sjöblom, S.E. Friberg and A. Amran, J. Dispersion Sci. Technol., 16 (1995) 31.
16. F. Fredriksen, Hydrolyse og kondensasjon i systemer med silisiumalkoksid og hydratisert kalsium- og nikkelnitrat i alkoholer, Universitetet i Bergen, 1995.
17. B. Gestblom, S.C. Mehrotra and J. Sjöblom, J. Solution Chem., 15 (1986) 55.