메뉴 건너뛰기




Volumn 104, Issue 45, 2000, Pages 10578-10587

C-C bond scission in ethane hydrogenolysis

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION ENERGY; BINDING ENERGY; CARBON; CHEMICAL BONDS; CRYSTAL ORIENTATION; HYDROGENATION; SURFACE CHEMISTRY;

EID: 0343773890     PISSN: 10895647     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp001082g     Document Type: Article
Times cited : (57)

References (98)
  • 29
    • 36849112289 scopus 로고
    • Tracy, J. C. J. Chem. Phys. 1972, 56, 2748. The value used in this paper corresponds to coverages of 0.1-0.5 ML. The value obtained by extrapolating to zero coverage is unexpectedly high (about 16 kcal/mol). A general trend is that the value at a very low coverage is very high due to reasons that are not yet clear (surface reconstruction, defect sites, and stepped sites are often considered as possible reasons). Then, the coverage remains virtually constant up to ∼1/3 ML.
    • (1972) J. Chem. Phys. , vol.56 , pp. 2748
    • Tracy, J.C.1
  • 98
    • 0342675435 scopus 로고    scopus 로고
    • note
    • Estimating the activities of metal surfaces from their activities in C-C bond scission steps may appear incorrect because different surfaces might prefer different intermediates as scission precursors and because C-C bond scission is not necessarily a rate-determining step.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.