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Volumn 122, Issue 8, 2000, Pages 1812-1813

Dry thienylation of the silicon (111)-(7 x 7) surface [6]

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL BINDING; CHEMICAL REACTION; CHEMICAL STRUCTURE; ENERGY TRANSFER; LETTER; REACTION ANALYSIS;

EID: 0343621492     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja993386q     Document Type: Letter
Times cited : (58)

References (30)
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    • Jursic, B. S.; Dzravkovski, Z.; Whittenburg, S. L. J. Phys. Org. Chem. 1995, 8, 753; Jursic, B. S. J. Mol. Struct. (THEOCHEM) 1998, 454, 105; Kotsuki, H.; Kitagawa, S.; Nishizawa, H.; Tokoroyama, T. J. Org. Chem. 1978, 43, 1471.
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    • Jursic, B. S.; Dzravkovski, Z.; Whittenburg, S. L. J. Phys. Org. Chem. 1995, 8, 753; Jursic, B. S. J. Mol. Struct. (THEOCHEM) 1998, 454, 105; Kotsuki, H.; Kitagawa, S.; Nishizawa, H.; Tokoroyama, T. J. Org. Chem. 1978, 43, 1471.
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    • note
    • The spacing between adjacent rest atom and adatom is 4.45 Å, which is quite comparable to the dimension of thiophene (∼2.47 Å). Considering the formation of C-Si bond (∼1.8-2.1 Å), a bridged geometry is reasonable.
  • 26
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    • note
    • Our TDS results show three desorption peaks for thiophene adsorbed on Si(111)-(7 × 7) at 110 K. The multilayer thiophene and the first physisorbed state of thiophene desorb at 137 and 159 K, respectively. The stronger binding state of chemisorbed thiophene desorbs at 414 K.
  • 28
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    • note
    • -1 are assigned to C=C stretching, C-H in-plane bending; C-C stretching, C-S-C stretching, C-H out-of-plane bending, and C-Si stretching modes, respectively.
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