Oxidative addition of py(dmgH)2Co-Na+ to a ribofuranosyl bromide: An unusual reaction with the cobaloxime ligand

Organometallics

Volumn 15, Issue 11, 1996, Pages 2585-2587

  Slade, Rachel M ^a   Branchaud, Bruce P ^a  

^a UNIVERSITY OF OREGON   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0343463848     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om950795w     Document Type: Article

References (14)

1. 12; Dolphin, D., Ed.; Wiley: New York, 1982; Vol. 1, pp 245-294.
2. Gerli, A.; Sabat, M.; Marzilli, L. J. Am. Chem. Soc. 1992, 114, 6711-6718 and references cited therein.
3. Daikh, B. E.; Finke, R. G. J. Am. Chem. Soc. 1991, 113, 4160-4172.
4. 2py, instead of its in situ formation as described in this reference.
5. 2py was prepared as described by: Schrauzer, G. N. In Inorganic Synthesis; Jolly, W. L., Ed.; McGraw-Hill: New York, 1968; Vol. 11, pp 61-70.
6. 13C, IR, MS, and high-resolution MS.
7. 2py and glycosyl halides has also been accomplished under aqueous conditions, buffered to minimize glycosyl halide solvolysis: Ghosez, A.; Gobel, T.; Giese, B. Chem. Ber. 1988, 121, 1807-1811.
8. (a) Branchaud, B. P.; Detlefsen, W. D. Tetrahedron Lett. 1991, 32, 6273-6276.
9. (b) Branchaud, B. P.; Slade, R. M.; Janisse, S. K. Tetrahedron Lett. 1993, 34, 7885-7888.
10. 9-Na 584.1771, found 584.1758.
11. (a) Thatcher, G. R. J., Ed. The Anomeric Effect and Associated Stereoelectronic Effects; American Chemical Society: Washington, DC, 1993.
12. (b) Juaristi, E.; Cuevas, G. Tetrahedron 1992, 48, 5019.
13. (c) Deslongchamps, P. Stereoelectronic Effects in Organic Chemistry; Pergamon Press: Oxford, U.K., 1983.
14. Cosse-Barbi, A.; Watson, D. G.; Dubois, J. E. Tetrahedron Lett. 1989, 30, 163-166.