Mechanism of the Metathesis between Carbon Tetrachloride and (η1-Allyl)iron Complexes. A Radical Chain Reaction of Overall Five-Thirds Order

Organometallics

Volumn 7, Issue 10, 1988, Pages 2146-2149

  Lee, Mei Tsu ^a   Waterman, Paul S ^a   Magnuson, Roy H ^a   Meirowitz, Randy E ^a   Prock, Alfred ^a   Giering, Warren P ^a  

^a BOSTON UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0343463623     PISSN: 02767333     EISSN: 15206041     Source Type: Journal    
DOI: 10.1021/om00100a010     Document Type: Article

References (14)

1. (a) Baldwin, J. E.; Adlington, R. M.; Birch, D. J.; Crawford, J. A.; Sweeney, J. B. J. Chem. Soc., Chem. Commun. 1986, 1339–40. (b) Baldwin, J. E.; Adlington, R. M.; Basak, A. J. Chem. Soc., Chem. Commun. 1984, 1284. (c) Grignon, J.; Pereyre, M. J. Organomet. Chem. 1973, 61, C33. Grignon, J.; Servens, C.; Pereyre, M. J. Organomet. Chem. 1975, 96, 225. (c) Kosugi, M.; Kurino, M.; Takayama, K.; Migita, T. J. Organomet. Chem. 1973,56, C11. (d) Keck, G. E.; Yates, J. B. J. Am. Chem. Soc. 1982, 104, 5829. (e) Keck, G. E.; Enholm, E. J.; Kachensky, D. E. Tetrahedron Lett. 1984,1867. (f) Keck, G. E.; Yates, J. B. J. Organomet. Chem. 1983, 248, C21.
2. (a) Dodd, D.; Johnson, M. D. J. Am. Chem. Soc. 1974,96, 2279. (b) Bury, A.; Cooksey, C. J.; Furiabiki, T.; Gupta, B. D.; Johnson, M. D. J. Chem. Soc., Perkin Trans. 2 1979,1050-57. (c) Gupta, B. D.; Funabiki, T.; Johnson, M. D. J. Am. Chem. Soc. 1976, 98, 6687. (d) Crease, A. E.; Gupta, B. D.; Johnson, M. D.; Bialkowska, K. N.; Duong, V.; Gaudemer, A. J. Chem. Soc., Perkins Trans. 2 1979, 2611–16. (e) Crease, A. E.; Gupta, B. D.; Johnson, M. D.; Moorhouse, S. J. Chem. Soc., Dalton Trans. 1978,1821-1825. (f) Bury, A.; Johnson, M. D.; Stewart, M. J. J. Chem. Soc., Chem. Commun. 1980, 622–23. (g) Ashcroft, M. R.; Bury, A.; Cooksey, C. J.; Davies, A. G.; Gupta, B. D.; Johnson, M. D.; Morris, H. J. Organomet. Chem. 1980, 195, 89–104. (h) Verber, M.; V.-Duong, K. N.; Gaudemer, A.; Johnson, M. D. J. Organomet. Chem. 1981, 209, 393–399.
3. Waterman, P. S.; Giering, W. P. J. Organomet. Chem. 1978, 155, C47-C50.
4. Draper, N. R.; Smith, H. Applied Regression Analysis; Wiley: New York, 1981.
5. (a) Walling, C. Tetrahedron 1985, 41, 3887–90. (b) Husyer, E. S. Free Radical Chain Reactions; Wiley-Interscience: New York, 1970.
6. Swern, D. Organic Peroxides, Wiley-Interscience: New York, 1970.
7. Terabe, S.; Kuruma, K.; Konaka, R. J. Chem. Soc., Perkins Trans. 2 1973, 1252–57.
8. (a) Howard, J. A.; Ingold, K. U. J. Am. Chem. Soc. 1966,88, 4725. (b) J. Am. Chem. Soc. 1966, 88, 4726.
9. (a) Schumacher, H. J.; Sprenger, G. Z. Phys. Chem., Abt. 1929, A180, 281. (b) Z. Phys. Chem., Abt. 1929, B2, 267.
10. 1-allybiron complexes. (a) Rosenblum, M.; Waterman, P. S. J. Organomet. Chem. 1981, 206, 197–209. (b) Fabian, B. D.; Labinger, J. A. J. Am. Chem. Soc. 1979, 101, 2239–2240.
11. Rosenblum, M. Acc. Chem. Res. 1974, 7, 122.
12. Cowdrey, W. A.; Hughes, E. D.; Ingold, C. K. J. Chem. Soc. 1937, 1208.
13. (a) Whitesides, G. M.; Lewis, D. W. J. Am. Chem. Soc. 1971, 93, 5913–14. (b) Kime, K. A.; Sievers, R. E. Aldrichim. Acta 1977, 10, 54–62.
14. Smith, L. J.; Tayler, F. L. J. Am. Chem. Soc. 1934, 56, 2370–72.