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Volumn , Issue 9, 2000, Pages 2117-2125

Rhodium and iridium complexes derived from trans-[MCl(CO)(PPh3)2] (M = Rh, Ir) and pyridine-2-thiolate or 4,6-dimethylpyrimidine-2-thiolate ligands: S-monodentate coordination versus S,N-chelation and S,N-bridging; reactivity of trans-[Ir('Spy')(CO)(PPh3)2] and trans-[Ir('SpymMe2')(CO)(PPh3)2] towards acid

Author keywords

Bridging ligands; Chelates; Iridium; Rhodium; S ligands

Indexed keywords

ATOMS; CHELATION; CRYSTAL STRUCTURE; INDIUM COMPOUNDS; IRIDIUM; LIGANDS; PYRIDINE; RHODIUM; RHODIUM COMPOUNDS; SALTS; SINGLE CRYSTALS; X RAY DIFFRACTION;

EID: 0343278997     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/1099-0682(200009)2000:9<2117::aid-ejic2117>3.0.co;2-v     Document Type: Article
Times cited : (17)

References (47)
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    • M. A. Ciriano, F. Viguri, L. A. Oro, A. Tiripicchio, M. Tiripicchio-Camellini, Angew. Chem. 1987, 99, 452-453; Angew. Chem. Int. Ed. Engl. 1987, 26, 444-445.
    • (1987) Angew. Chem. Int. Ed. Engl. , vol.26 , pp. 444-445
  • 31
    • 85163239143 scopus 로고    scopus 로고
    • H atom position generated by the HFIX 83 option of SHELX-97, see ref.[29]
    • H atom position generated by the HFIX 83 option of SHELX-97, see ref.[29]
  • 32
    • 85163239109 scopus 로고    scopus 로고
    • note
    • 3)2] with an O-H⋯O-bridged hydrogen bis(trifluoroacetate) anion was taken as the basis for the final stages of refinement.
  • 33
    • 85163238241 scopus 로고    scopus 로고
    • note
    • 1H NMR data reported by others (ref.[20b,21-23]) according to which the hydride resonance of the isomeric form having the hydride ligands trans to the more electronegative atom. e.g. N, appears at lower frequencies than that in which the M-H bond is trans to a less electronegative donor atom such as sulfur.
  • 45
    • 0000604488 scopus 로고
    • A. Altomare, G. Cascarona, C. Giacovazzo, A. Guagliardi, M. C. Burla, G. Polidori, M. Camalli, SIR-92 - Program Package for Solving Crystal Structures by Direct Methods, Bari, Perugia and Rome, 1992; J. Appl. Crystallogr. 1994, 27, 435-436.
    • (1994) J. Appl. Crystallogr. , vol.27 , pp. 435-436


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.