Molecular lattice fragment of LiI. Crystal structure and ab initio calculations of [LiI(NEt3)]4

Inorganic Chemistry

Volumn 39, Issue 7, 2000, Pages 1534-1537

  Doriat, C ^a   Koppe R ^a   Baum, E ^a   Stosser G ^a   Kohnlein H ^a   Schnockel H ^a  

^a UNIVERSITY OF KARLSRUHE   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

LITHIUM DERIVATIVE;

ARTICLE; CALCULATION; CHEMICAL ANALYSIS; CHEMICAL REACTION; CHEMICAL STRUCTURE; CRYSTAL STRUCTURE; ENERGY TRANSFER; STRUCTURE ANALYSIS; X RAY CRYSTALLOGRAPHY;

EID: 0343278980     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic9903432     Document Type: Article

References (31)

1. Ecker, A.; Weckert, E.; Schnöckel, H. Nature 1997, 387, 379-381.
2. Barr, D.; Clegg, W.; Mulvey, R. E.; Snaith, R. Chem. Commun. 1984, 79-80.
3. Neumann, F.; Hampel, F.; v. R. Schleyer, P. Inorg. Chem. 1995, 34, 6553-6555.
4. Snaith, R.; Wright, D. S. In Lithium Chemistry: A Theoretical and Experimental Overview, Sapse, A.-M., Schleyer, P. v. R., Eds.; Wiley: New York, 1995; p 227.
5. Sapse, A. M.; Yain, C. C.; Raghavachav, K. In Lithium Chemistry: A Theoretical and Experimentel Overview; Sapse, A.-M., Schleyer, P. v. R., Eds.; Wiley: New York, 1995; p 45. Mulvey, R. C. Chem. Soc. Rev. 1998, 27, 339-346.
6. Sapse, A. M.; Yain, C. C.; Raghavachav, K. In Lithium Chemistry: A Theoretical and Experimentel Overview; Sapse, A.-M., Schleyer, P. v. R., Eds.; Wiley: New York, 1995; p 45. Mulvey, R. C. Chem. Soc. Rev. 1998, 27, 339-346.
7. Weiss, E.; Hencken, G. J. Organomet. Chem. 1970, 21, 265-268.
8. Wannagat, U.; Niederprüm, H. Chem. Ber 1961, 94, 1540-1545.
9. Doriat, C. U.; Friesen, M.; Baum, E.; Ecker, A.; Schnöckel, H. Angew. Chem 1997, 109, 2057-2058; Angew. Chem., Int. Ed. Engl. 1997, 36, 1969-1970.
10. Doriat, C. U.; Friesen, M.; Baum, E.; Ecker, A.; Schnöckel, H. Angew. Chem 1997, 109, 2057-2058; Angew. Chem., Int. Ed. Engl. 1997, 36, 1969-1970.
11. Ecker, A.; Schnöckel, H. Z. Anorg. Allg. Chem. 1996, 622, 149-152.
12. Sheldrick, G. M. Acta Crystallogr. A 1990, 46, 467-473.
13. Sheldrick, G. M. SHELXL-93. Program for the Refinement of Crystal Structures; University of Göttingen: Göttingen, Germany, 1993.
14. Ahlrichs, R.; Bär, M.; Häser, M.; Horn, H.; Kölmel, C. Chem. Phys. Lett. 1989, 162, 165-171.
15. Treutler, O.; Öhm, H.; Häser, M.; Ahlrichs, R. Chem. Phys. Lett. 1995, 240, 283-299.
16. Schäfer, A.; Horn, H.; Ahlrichs, R. J. Chem. Phys. 1992, 97, 2751-2754.
17. Bergner, A.; Dolg, M.; Kuechle, W.; Stoll, H.; Preuss, H. Mol. Phys. 1993, 80, 1431.
18. Üffing, C.; Köppe, R.; Schnöckel, H. Organometallics 1998, 17, 3512-3515.
19. Heinzmann, R.; Ahlrichs, R. Theor. Chim. Acta 1976, 42, 33-40.
20. Erhardt, C.; Ahlrichs, R. Theor. Chim. Acta 1985, 68, 231-245.
21. 23 are much larger than errors due to the neglect of zero-point energies and thermal corrections to the enthalpy.
22. Robinson, E. A.; Heard, G. L.; Gillespie, R. J. J. Mol. Struct. 1999, 485, 305-320.
23. 2 the SEN is reduced to about 0.6.
24. Köster, H.; Thoennes, D.; Weiss, E. J. Organomet. Chem. 1978, 160, 1-5.
25. Hoffmann, D.; Dorigo, A.; Schleyer, P. v. R.; Reif, H.; Stalke, D.; Sheldrick, G. M.; Weiss, E.; Geissler, M. Inorg. Chem. 1995, 34, 262-269.
26. rd ed.; American Chemical Society: Midland, MI, 1985.
27. 3 solutions, entropy influences should not loom large.
28. Jolly, W. J.; Hallada, C. J. In Nonaqueous solvent systems; Waddington, T. C., Ed.; Academic Press: London, 1965; p 26.
29. Weast, R. C. CRC Handbook of Chemistry and Physics, 51st ed.; The Chemical Rubber Co.: Cleveland, OH, 1970; Section D, p 78.
30. Huber, K. P.; Herzberg, G. Molecular Spectra and Molecular Structure IV. Constants of Diatomic Molecules; Van Nostrand Reinhold: New York, 1979.
31. Wells, A. F. Structural Inorganic Chemistry, 5th ed; Clarendon Press: Oxford, U.K., 1984; p 444.